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Arylide yellow

From Wikipedia, the free encyclopedia
Family of organic compounds used as industrial colorants
Arylide yellow
 
About these coordinates     Color coordinates
Hex triplet#E9D66B
sRGBB (r,g,b)(233, 214, 107)
HSV (h,s,v)(51°, 54%, 91%)
CIELChuv (L,C,h)(85, 71, 76°)
Source[1][2]
ISCC–NBS descriptorBrilliant greenish yellow
B: Normalized to [0–255] (byte)

Arylide yellow, also known asHansa yellow andmonoazo yellow, is a family oforganic compounds used aspigments. They are primarily used as industrial colorants includingplastics, building paints and inks. They are also used in artisticoil paints,acrylics andwatercolors. These pigments are usually semi-transparent and range from orange-yellow to yellow-greens. Related organic pigments are thediarylide pigments. Overall, these pigments have partially displaced the toxiccadmium yellow in the marketplace. Painters such asAlexander Calder andJackson Pollock are known to have employed arylide yellow in their artworks.[1]

Production

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The compound is obtained byazo coupling ofaniline andacetoacetanilide or their derivatives. The class of compounds was discovered in Germany in 1909. The initially formed diazo compoundtautomerizes to give aketohydrazone, which features extended pi-conjugation.[2]

formation of Hansa pigments by diazotization followed by tautomerization

Examples

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Members of this class include:

Artists Pigments

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Several monoazo yellows are used as artists' pigments, frequently marketed under the names 'Hansa' or Arylide.[3] These include:

  • PY1[4]
  • PY2[5]
  • PY3 Hansa Yellow Light or Lemon Yellow[6]
  • PY4[7]
  • PY5[8]
  • PY6[9]
  • PY10[10]
  • PY60[11]
  • PY65 Hansa Yellow Deep or Indian Yellow[12]
  • PY74 Hansa Yellow Medium or Primary Yellow[13]
  • PY82[14]
  • PY97 Hansa Yellow Medium or Hansa Yellow Deep[15]

See also

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References

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  1. ^Arylide Yellow, Colourlex
  2. ^K. Hunger. W. Herbst "Pigments, Organic" inUllmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2012.doi:10.1002/14356007.a20_371
  3. ^"Synthetic organic pigments - Monoazo (arylide)".Handprint. 1 August 2015.
  4. ^"PY1 Hansa Yellow G".Artist Pigments.
  5. ^"PY2 Hansa Yellow GR".Artist Pigments.
  6. ^"PY3 Hansa Yellow 10G".Artist Pigments.
  7. ^"PY4 Hansa Yellow 10G".Artist Pigments.
  8. ^"PY5 Hansagelb 5G".Artist Pigments.
  9. ^"PY6 Hansa Yellow 3G".Artist Pigments.
  10. ^"PY10 Hansa Yellow R".Artist Pigments.
  11. ^"PY60 Hansa Yellow 4R 3D—1750".Artist Pigments.
  12. ^"PY65 Hansa Yellow 3RN".Artist Pigments.
  13. ^"PY74 Arylide Yellow 5GX".Artist Pigments.
  14. ^"PY82 Hansagelb 8G".Artist Pigments.
  15. ^"PY97 Diarylide Yellow FGL".Artist Pigments.

Further reading

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A typical sample is shown for each name; a range of color-variations is commonly associated with each color-name.
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