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Americium(III) oxide

From Wikipedia, the free encyclopedia
Americium(III) oxide
Names
Other names
Americium sesquioxide
Identifiers
3D model (JSmol)
  • InChI=1S/2Am.3O/q2*+3;3*-2
    Key: HPWBMQLLXMZFDK-UHFFFAOYSA-N
  • [O-2].[O-2].[O-2].[Am+3].[Am+3]
Properties
Am2O3
Molar mass534 g·mol−1
Density11.77
Melting point2,205 °C (4,001 °F; 2,478 K)
Structure
Trigonal,hP5
P3m1, No. 164
a = 381.7 pm,c = 597.1 pm[1]
Related compounds
Othercations
Curium(III) oxide
Related compounds
Americium dioxideAmericium(II) oxide
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Americium(III) oxide oramericium sesquioxide is anoxide of the elementamericium. It has the empirical formulaAm2O3. Since allisotopes of americium are only artificially produced, americium (III) oxide has no natural occurrence. The colour depends on the crystal structure, of which there are more than one. It is soluble in acids.[2]

Formation

[edit]

Americium(III) oxide can be made by heatingamericium dioxide in hydrogen at 600°C.[3]

2 AmO2 + H2 → Am2O3 + H2O

Forms

[edit]

The hexagonal form is coloured tan, and the cubic form is coloured red-brown the same aspersimmon.[3] The cubic form converts to the hexagonal form on heating to 800°C.[3] The cubic form isnon-stoichiometric with variable oxygen composition. It darkens with increasing oxygen.[3]

References

[edit]
  1. ^Christine Guéneau; Alain Chartier; Paul Fossati; Laurent Van Brutzel; Philippe Martin (2020). "Thermodynamic and Thermophysical Properties of the Actinide Oxides".Comprehensive Nuclear Materials 2nd Ed.7:111–154.doi:10.1016/B978-0-12-803581-8.11786-2.ISBN 9780081028667.S2CID 261051636.
  2. ^Lide, David R. (1995).CRC Handbook of Chemistry and Physics: A Ready-reference Book of Chemical and Physical Data. CRC Press. p. 4-38.ISBN 978-0-8493-0595-5.
  3. ^abcdChikalla, T.D.; Eyring, L. (January 1968). "Phase relationships in the americium-oxygen system".Journal of Inorganic and Nuclear Chemistry.30 (1):133–145.doi:10.1016/0022-1902(68)80072-7.
Am(II)
Am(III)
Am(IV)
Am(VI)
AmF6(predicted)
Mixed oxidation states
+1 oxidation state
+2 oxidation state
+3 oxidation state
+4 oxidation state
+5 oxidation state
+6 oxidation state
+7 oxidation state
+8 oxidation state
Related
Oxides are sorted byoxidation state.Category:Oxides
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