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Actinium(III) fluoride

From Wikipedia, the free encyclopedia
Actinium fluoride
Crystal structure
Names
Other names
Actinium(III) fluoride
Actinium trifluoride
Identifiers
3D model (JSmol)
  • InChI=1S/Ac.3FH/h;3*1H/q+3;;;/p-3 checkY
  • InChI=1/Ac.3FH/h;3*1H/q+3;;;/p-3
  • F[Ac](F)F
Properties
AcF3
Molar mass284 g/mol[1]
Appearancewhite, crystalline solid
Density7.88 g/cm3[1]
Structure
Rhombohedral,hR24
P3c1, No. 165[2]
a = 0.741 nm,c = 0.755 nm
0.35902
6
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Chemical compound

Actinium(III) fluoride (AcF3) is aninorganic compound, a salt ofactinium andfluorine.

Synthesis

[edit]

Actinium fluoride can be prepared in solution or by a solid-state reaction. In the first method,actinium hydroxide is treated withhydrofluoric acid and the product precipitates:[3]

Ac(OH)3 + 3HF → AcF3↓ + 3H2O

In the solid-state reaction, actinium metal is treated withhydrogen fluoride gas at 700 °C in a platinum crucible.[4][5]

Properties

[edit]

Actinium fluoride is a white solid that reacts with ammonia at 900–1000 °C to yield an actinium oxyfluoride:

AcF3 + 2NH3 + H2O -> AcOF + 2NH4F

While lanthanum oxyfluoride is easily formed by heatinglanthanum fluoride in air, a similar treatment merely melts actinium fluoride and does not yield AcOF.[4][5]

References

[edit]
  1. ^abHaynes, William M., ed. (2011).CRC Handbook of Chemistry and Physics (92nd ed.). Boca Raton, Florida:CRC Press. p. 4.44.ISBN 1-4398-5511-0.
  2. ^Zachariasen, W. H. (1949)."Crystal chemical studies of the 5f-series of elements. XII. New compounds representing known structure types".Acta Crystallographica.2 (6):388–390.Bibcode:1949AcCry...2..388Z.doi:10.1107/S0365110X49001016.
  3. ^Haire, Richard G. (2006). "Actinium". In Morss; Edelstein, Norman M.; Fuger, Jean (eds.).The Chemistry of the Actinide and Transactinide Elements (3rd ed.). Dordrecht, The Netherlands:Springer Science+Business Media. p. 36.ISBN 1-4020-3555-1.
  4. ^abFried, Sherman; Hagemann, French; Zachariasen, W. H. (1950). "The Preparation and Identification of Some Pure Actinium Compounds".Journal of the American Chemical Society.72 (2): 771.doi:10.1021/ja01158a034.
  5. ^abMeyer, Gerd and Morss, Lester R. (1991)Synthesis of lanthanide and actinide compounds. Springer.ISBN 0-7923-1018-7. pp. 87–88
Salts and covalent derivatives of thefluoride ion
HF?HeF2
LiFBeF2BF
BF3
B2F4
+BO3
CF4
CxFy
+CO3
NF3
FN3
N2F2
NF
N2F4
NF2
?NF5
+N
+NO3
OF2
O2F2
OF
O3F2
O4F2
?OF4
F2Ne
NaFMgF2AlF
AlF3
SiF4P2F4
PF3
PF5
+PO4
S2F2
SF2
S2F4
SF3
SF4
S2F10
SF6
+SO4
ClF
ClF3
ClF5
?ArF2
?ArF4
KFCaF
CaF2
ScF3TiF2
TiF3
TiF4
VF2
VF3
VF4
VF5
CrF2
CrF3
CrF4
CrF5
?CrF6
MnF2
MnF3
MnF4
?MnF5
FeF2
FeF3
FeF4
CoF2
CoF3
CoF4
NiF2
NiF3
NiF4
CuF
CuF2
?CuF3
ZnF2GaF2
GaF3
GeF2
GeF4
AsF3
AsF5
Se2F2
SeF4
SeF6
+SeO3
BrF
BrF3
BrF5
KrF2
?KrF4
?KrF6
RbFSrF
SrF2
YF3ZrF2
ZrF3
ZrF4
NbF4
NbF5
MoF4
MoF5
MoF6
TcF4
TcF
5

TcF6
RuF3
RuF
4

RuF5
RuF6
RhF3
RhF4
RhF5
RhF6
PdF2
Pd[PdF6]
PdF4
?PdF6
Ag2F
AgF
AgF2
AgF3
CdF2InF
InF3
SnF2
SnF4
SbF3
SbF5
TeF4
?Te2F10
TeF6
+TeO3
IF
IF3
IF5
IF7
+IO3
XeF2
XeF4
XeF6
?XeF8
CsFBaF2 LuF3HfF4TaF5WF4
WF5
WF6
ReF4
ReF5
ReF6
ReF7
OsF4
OsF5
OsF6
?OsF
7

?OsF
8
IrF2
IrF3
IrF4
IrF5
IrF6
PtF2
Pt[PtF6]
PtF4
PtF5
PtF6
AuF
AuF3
Au2F10
?AuF6
AuF5•F2
Hg2F2
HgF2
?HgF4
TlF
TlF3
PbF2
PbF4
BiF3
BiF5
PoF2
PoF4
PoF6
AtF
?AtF3
?AtF5
RnF2
?RnF
4

?RnF
6
FrFRaF2 LrF3RfDbSgBhHsMtDsRgCnNhFlMcLvTsOg
LaF3CeF3
CeF4
PrF3
PrF4
NdF2
NdF3
NdF4
PmF3SmF
SmF2
SmF3
EuF2
EuF3
GdF3TbF3
TbF4
DyF2
DyF3
DyF4
HoF3ErF3TmF2
TmF3
YbF2
YbF3
AcF3ThF2
ThF3
ThF4
PaF4
PaF5
UF3
UF4
UF5
UF6
NpF3
NpF4
NpF5
NpF6
PuF3
PuF4
PuF5
PuF6
AmF2
AmF3
AmF4
?AmF6
CmF3
CmF4
 ?CmF6
BkF3
BkF
4
CfF3
CfF4
EsF3
EsF4
?EsF6
FmMdF3No
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