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Theatomic nucleus is the small, dense region consisting ofprotons andneutrons at the center of anatom, discovered in 1911 byErnest Rutherford at the University of Manchester based on the 1909Geiger–Marsden gold foil experiment. After the discovery of the neutron in 1932, models for a nucleus composed of protons and neutrons were quickly developed byDmitri Ivanenko[1] andWerner Heisenberg.[2][3][4][5][6] An atom is composed of a positively charged nucleus, with a cloud of negatively chargedelectrons surrounding it, bound together byelectrostatic force. Almost all of themass of an atom is located in the nucleus, with a very small contribution from theelectron cloud. Protons and neutrons are bound together to form a nucleus by thenuclear force.

The diameter of the nucleus is in the range of1.70 fm (1.70×10−15 m[7]) forhydrogen (the diameter of a single proton) to about11.7 fm foruranium.[8] These dimensions are much smaller than the diameter of the atom itself (nucleus + electron cloud), by a factor of about 26,634 (uranium atomic radius is about156 pm (156×10−12 m))[9] to about 60,250 (hydrogen atomic radius is about52.92 pm).[a]
The branch of physics involved with the study and understanding of the atomic nucleus, including its composition and the forces that bind it together, is callednuclear physics.
History
editThe nucleus was discovered in 1911, as a result ofErnest Rutherford's efforts to test Thomson's "plum pudding model" of the atom.[10] The electron had already been discovered byJ. J. Thomson. Knowing that atoms are electrically neutral, J. J. Thomson postulated that there must be a positive charge as well. In his plum pudding model, Thomson suggested that an atom consisted of negative electrons randomly scattered within a sphere of positive charge. Ernest Rutherford later devised an experiment with his research partnerHans Geiger and with help ofErnest Marsden, that involved the deflection ofalpha particles (helium nuclei) directed at a thin sheet of metal foil. He reasoned that if J. J. Thomson's model were correct, the positively charged alpha particles would easily pass through the foil with very little deviation in their paths, as the foil should act as electrically neutral if the negative and positive charges are so intimately mixed as to make it appear neutral. To his surprise, many of the particles were deflected at very large angles. Because the mass of an alpha particle is about 8000 times that of an electron, it became apparent that a very strong force must be present if it could deflect the massive and fast moving alpha particles. He realized that the plum pudding model could not be accurate and that the deflections of the alpha particles could only be explained if the positive and negative charges were separated from each other and that the mass of the atom was a concentrated point of positive charge. This justified the idea of a nuclear atom with a dense center of positive charge and mass.
Etymology
editThe termnucleus is from the Latin wordnucleus, a diminutive ofnux ('nut'), meaning 'the kernel' (i.e., the 'small nut') inside a watery type of fruit (like apeach). In 1844,Michael Faraday used the term to refer to the "central point of an atom". The modern atomic meaning was proposed by Ernest Rutherford in 1912.[11] The adoption of the term "nucleus" to atomic theory, however, was not immediate. In 1916, for example,Gilbert N. Lewis stated, in his famous articleThe Atom and the Molecule, that "the atom is composed of thekernel and an outer atom orshell."[12]Similarly, the termkern meaning kernel is used for nucleus in German and Dutch.
Principles
editThe nucleus of an atom consists of neutrons and protons, which in turn are the manifestation of more elementary particles, calledquarks, that are held in association by thenuclear strong force in certain stable combinations ofhadrons, calledbaryons. The nuclear strong force extends far enough from each baryon so as to bind the neutrons and protons together against the repulsive electrical force between the positively charged protons. The nuclear strong force has a very short range, and essentially drops to zero just beyond the edge of the nucleus. The collective action of the positively charged nucleus is to hold the electrically negative charged electrons in their orbits about the nucleus. The collection of negatively charged electrons orbiting the nucleus display an affinity for certain configurations and numbers of electrons that make their orbits stable. Whichchemical element an atom represents is determined by the number ofprotons in the nucleus; the neutral atom will have an equal number of electrons orbiting that nucleus. Individual chemical elements can create more stable electron configurations by combining to share their electrons. It is that sharing of electrons to create stable electronic orbits about the nuclei that appears to us as the chemistry of our macro world.
Protons define the entire charge of a nucleus, and hence itschemical identity. Neutrons are electrically neutral, but contribute to the mass of a nucleus to nearly the same extent as the protons. Neutrons can explain the phenomenon ofisotopes (same atomic number with different atomic mass). The main role of neutrons is to reduce electrostatic repulsion inside the nucleus.
Composition and shape
editProtons and neutrons arefermions, with different values of thestrong isospinquantum number, so two protons and two neutrons can share the same spacewave function since they are not identical quantum entities. They are sometimes viewed as two different quantum states of the same particle, thenucleon.[13][14] Two fermions, such as two protons, or two neutrons, or a proton + neutron (the deuteron) can exhibitbosonic behavior when they become loosely bound in pairs, which have integer spin.
In the rare case of ahypernucleus, a thirdbaryon called ahyperon, containing one or morestrange quarks and/or other unusual quark(s), can also share the wave function. However, this type of nucleus is extremely unstable and not found on Earth except in high-energy physics experiments.
The neutron has a positively charged core of radius ≈ 0.3 fm surrounded by a compensating negative charge of radius between 0.3 fm and 2 fm. The proton has an approximately exponentially decaying positive charge distribution with a mean square radius of about 0.8 fm.[15]
The shape of the atomic nucleus can be spherical, rugby ball-shaped (prolate deformation), discus-shaped (oblate deformation), triaxial (a combination of oblate and prolate deformation) or pear-shaped.[16][17]
Forces
editNuclei are bound together by the residual strong force (nuclear force). The residual strong force is a minor residuum of thestrong interaction which binds quarks together to form protons and neutrons. This force is much weakerbetween neutrons and protons because it is mostly neutralized within them, in the same way that electromagnetic forcesbetween neutral atoms (such asvan der Waals forces that act between two inert gas atoms) are much weaker than the electromagnetic forces that hold the parts of the atoms together internally (for example, the forces that hold the electrons in an inert gas atom bound to its nucleus).
The nuclear force is highly attractive at the distance of typical nucleon separation, and this overwhelms the repulsion between protons due to the electromagnetic force, thus allowing nuclei to exist. However, the residual strong force has a limited range because it decays quickly with distance (seeYukawa potential); thus only nuclei smaller than a certain size can be completely stable. The largest known completely stable nucleus (i.e. stable to alpha,beta, andgamma decay) islead-208 which contains a total of 208 nucleons (126 neutrons and 82 protons). Nuclei larger than this maximum are unstable and tend to be increasingly short-lived with larger numbers of nucleons. However,bismuth-209 is also stable to beta decay and has the longest half-life to alpha decay of any known isotope, estimated at a billion times longer than the age of the universe.
The residual strong force is effective over a very short range (usually only a fewfemtometres (fm); roughly one or two nucleon diameters) and causes an attraction between any pair of nucleons. For example, between aproton and aneutron to form adeuteron [NP], and also between protons and protons, and neutrons and neutrons.
Halo nuclei and nuclear force range limits
editThe effective absolute limit of the range of thenuclear force (also known as residualstrong force) is represented byhalo nuclei such aslithium-11 orboron-14, in whichdineutrons, or other collections of neutrons, orbit at distances of about10 fm (roughly similar to the8 fm radius of the nucleus ofuranium-238). These nuclei are not maximally dense. Halo nuclei form at the extreme edges of thechart of the nuclides—the neutron drip line and proton drip line—and are all unstable with short half-lives, measured inmilliseconds; for example, lithium-11 has a half-life of8.8 ms.
Halos in effect represent an excited state with nucleons in an outer quantum shell which has unfilled energy levels "below" it (both in terms of radius and energy). The halo may be made of either neutrons [NN, NNN] or protons [PP, PPP]. Nuclei which have a single neutron halo include11Be and19C. A two-neutron halo is exhibited by6He,11Li,17B,19B and22C. Two-neutron halo nuclei break into three fragments, never two, and are calledBorromean nuclei because of this behavior (referring to a system of three interlocked rings in which breaking any ring frees both of the others).8He and14Be both exhibit a four-neutron halo. Nuclei which have a proton halo include8B and26P. A two-proton halo is exhibited by17Ne and27S. Proton halos are expected to be more rare and unstable than the neutron examples, because of the repulsive electromagnetic forces of the halo proton(s).
Nuclear models
editAlthough thestandard model of physics is widely believed to completely describe the composition and behavior of the nucleus, generating predictions from theory is much more difficult than for most other areas ofparticle physics. This is due to two reasons:
- In principle, the physics within a nucleus can be derived entirely fromquantum chromodynamics (QCD). In practice however, current computational and mathematical approaches for solving QCD in low-energy systems such as the nuclei are extremely limited. This is due to thephase transition that occurs between high-energyquark matter and low-energyhadronic matter, which rendersperturbative techniques unusable, making it difficult to construct an accurate QCD-derived model of theforces between nucleons. Current approaches are limited to either phenomenological models such as the Argonne v18 potential orchiral effective field theory.[18]
- Even if the nuclear force is well constrained, a significant amount of computational power is required to accurately compute the properties of nucleiab initio. Developments inmany-body theory have made this possible for many low mass and relatively stable nuclei, but further improvements in both computational power and mathematical approaches are required before heavy nuclei or highly unstable nuclei can be tackled.
Historically, experiments have been compared to relatively crude models that are necessarily imperfect. None of these models can completely explain experimental data on nuclear structure.[19]
Thenuclear radius (R) is considered to be one of the basic quantities that any model must predict. For stable nuclei (not halo nuclei or other unstable distorted nuclei) the nuclear radius is roughly proportional to the cube root of themass number (A) of the nucleus, and particularly in nuclei containing many nucleons, as they arrange in more spherical configurations:
The stable nucleus has approximately a constant density and therefore the nuclear radius R can be approximated by the following formula,
whereA = Atomicmass number (the number of protonsZ, plus the number of neutronsN) andr0 = 1.25 fm = 1.25 × 10−15 m. In this equation, the "constant"r0 varies by 0.2 fm, depending on the nucleus in question, but this is less than 20% change from a constant.[20]
In other words, packing protons and neutrons in the nucleus givesapproximately the same total size result as packing hard spheres of a constant size (like marbles) into a tight spherical or almost spherical bag (some stable nuclei are not quite spherical, but are known to beprolate).[21]
Models ofnuclear structure include:
Cluster model
editThe cluster model describes the nucleus as a molecule-like collection of proton-neutron groups (e.g.,alpha particles) with one or more valence neutrons occupying molecular orbitals.[22][23][24][25]
Liquid drop model
editEarly models of the nucleus viewed the nucleus as a rotating liquid drop. In this model, the trade-off of long-range electromagnetic forces and relatively short-range nuclear forces, together cause behavior which resembled surface tension forces in liquid drops of different sizes. This formula is successful at explaining many important phenomena of nuclei, such as their changing amounts ofbinding energy as their size and composition changes (seesemi-empirical mass formula), but it does not explain the special stability which occurs when nuclei have special "magic numbers" of protons or neutrons.
The terms in the semi-empirical mass formula, which can be used to approximate the binding energy of many nuclei, are considered as the sum of five types of energies (see below). Then the picture of a nucleus as a drop of incompressible liquid roughly accounts for the observed variation of binding energy of the nucleus:
Volume energy. When an assembly of nucleons of the same size is packed together into the smallest volume, each interior nucleon has a certain number of other nucleons in contact with it. So, this nuclear energy is proportional to the volume.
Surface energy. A nucleon at the surface of a nucleus interacts with fewer other nucleons than one in the interior of the nucleus and hence its binding energy is less. This surface energy term takes that into account and is therefore negative and is proportional to the surface area.
Coulomb energy. The electric repulsion between each pair of protons in a nucleus contributes toward decreasing its binding energy.
Asymmetry energy (also calledPauli Energy). An energy associated with thePauli exclusion principle. Were it not for the Coulomb energy, the most stable form of nuclear matter would have the same number of neutrons as protons, since unequal numbers of neutrons and protons imply filling higher energy levels for one type of particle, while leaving lower energy levels vacant for the other type.
Pairing energy. An energy which is a correction term that arises from the tendency of proton pairs and neutron pairs to occur. An even number of particles is more stable than an odd number.
Shell models and other quantum models
editA number of models for the nucleus have also been proposed in which nucleons occupy orbitals, much like theatomic orbitals inatomic physics theory. These wave models imagine nucleons to be either sizeless point particles in potential wells, or else probability waves as in the "optical model", frictionlessly orbiting at high speed in potential wells.
In the above models, the nucleons may occupy orbitals in pairs, due to being fermions, which allows explanation ofeven/oddZ andN effects well known from experiments. The exact nature and capacity of nuclear shells differs from those of electrons in atomic orbitals, primarily because the potential well in which the nucleons move (especially in larger nuclei) is quite different from the central electromagnetic potential well which binds electrons in atoms. Some resemblance to atomic orbital models may be seen in a small atomic nucleus like that ofhelium-4, in which the two protons and two neutrons separately occupy 1s orbitals analogous to the 1s orbital for the two electrons in the helium atom, and achieve unusual stability for the same reason. Nuclei with 5 nucleons are all extremely unstable and short-lived, yet,helium-3, with 3 nucleons, is very stable even with lack of a closed 1s orbital shell. Another nucleus with 3 nucleons, the tritonhydrogen-3 is unstable and will decay into helium-3 when isolated. Weak nuclear stability with 2 nucleons {NP} in the 1s orbital is found in the deuteronhydrogen-2, with only one nucleon in each of the proton and neutron potential wells. While each nucleon is a fermion, the {NP} deuteron is a boson and thus does not follow Pauli Exclusion for close packing within shells.Lithium-6 with 6 nucleons is highly stable without a closed second 1p shell orbital. For light nuclei with total nucleon numbers 1 to 6 only those with 5 do not show some evidence of stability. Observations of beta-stability of light nuclei outside closed shells indicate that nuclear stability is much more complex than simple closure of shell orbitals withmagic numbers of protons and neutrons.
For larger nuclei, the shells occupied by nucleons begin to differ significantly from electron shells, but nevertheless, present nuclear theory does predict the magic numbers of filled nuclear shells for both protons and neutrons. The closure of the stable shells predicts unusually stable configurations, analogous to the noble group of nearly-inert gases in chemistry. An example is the stability of the closed shell of 50 protons, which allowstin to have 10 stable isotopes, more than any other element. Similarly, the distance from shell-closure explains the unusual instability of isotopes which have far from stable numbers of these particles, such as the radioactive elements 43 (technetium) and 61 (promethium), each of which is preceded and followed by 17 or more stable elements.
There are however problems with the shell model when an attempt is made to account for nuclear properties well away from closed shells. This has led to complexpost hoc distortions of the shape of the potential well to fit experimental data, but the question remains whether these mathematical manipulations actually correspond to the spatial deformations in real nuclei. Problems with the shell model have led some to propose realistic two-body and three-body nuclear force effects involving nucleon clusters and then build the nucleus on this basis. Three such cluster models are the 1936Resonating Group Structure model of John Wheeler,Close-Packed Spheron Model of Linus Pauling and the2D Ising Model of MacGregor.[19]
See also
edit- Giant resonance
- List of particles
- James Rainwater,Aage Bohr andBen Roy Mottelson modelled non-spherical nuclei
- Nuclear medicine
- Radioactivity
- Interacting boson model
Notes
edit- ^26,634 derives from2 x156 pm /11.7142 fm; 60,250 derives from2 x52.92 pm /1.7166 fm
References
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External links
edit- The Nucleus – a chapter from an online textbookArchived December 14, 2010, at theWayback Machine
- The LIVEChart of Nuclides – IAEA inJava orHTML
- Article on the "nuclear shell model", giving nuclear shell filling for the various elements. Accessed September 16, 2009.
- Timeline: Subatomic Concepts, Nuclear Science & TechnologyArchived February 5, 2021, at theWayback Machine.