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Aluminosilicate

From Wikipedia, the free encyclopedia
Mineral with elements Al, Si and O
This article is about a class of minerals. For related neutral compounds composed solely of aluminium, silicon and oxygen, seeAluminium silicate.

Aluminosilicate refers to materials containinganionic Si-O-Al linkages.[citation needed] Commonly, the associate cations are sodium (Na+), potassium (K+) and protons (H+). Such materials occur asminerals, coal combustion products[1] and as synthetic materials, often in the form ofzeolites. Both synthetic and natural aluminosilicates are of technical significance as structural materials, catalysts, andreagents.

Important representatives

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The aluminosilicate framework of LTA-type zeolite (left) and FAU-type zeolite (right). Vertices = Al or Si, oxygen atoms are not shown.

Feldspar is a commontectosilicate aluminosilicate mineral made of potassium, sodium, and calcium cations surrounded by a negatively charged network of silicon, aluminium and oxygen atoms.

Many aluminosilicates are synthesized by reactions of silicates, aluminates, and other compounds. They have the general formula(MAlO2)(SiO2)x(H2O)y where M+ is usually H+ and Na+. The Si/Al ratio is variable, which provides a means to tune the properties.[2] Many of these materials are porous and exhibit properties of industrial value.[3] Naturally occurringmicroporous, hydrous aluminosilicate minerals are also referred to aszeolites.

See also

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References

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  1. ^"Brindle & McCarthy (2006) Chemical Constraints on Fly Ash Glass Compositions".pubs.acs.org.doi:10.1021/ef0603028.
  2. ^Greenwood, Norman N.; Earnshaw, Alan (1997).Chemistry of the Elements (2nd ed.).Butterworth-Heinemann.doi:10.1016/C2009-0-30414-6.ISBN 978-0-08-037941-8.
  3. ^"Fact.MR – Aluminosilicate Market - Global Market Report (2024 to 2034)".www.factmr.com. Retrieved2023-12-30.
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