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Article

Terahertz Metamaterial Modulator Based on Phase Change Material VO2

1
Industries Training Centre, Shenzhen Polytechnic (SZPT), Shenzhen 518055, China
2
College of Electronic Science, National University of Defense Technology, Changsha 410073, China
3
College of Electrical and Information Engineering, Hunan University, Changsha 410082, China
4
Hunan Provincial Key Laboratory of Flexible Electronic Materials Genome Engineering, Changsha University of Science and Technology, Changsha 410004, China
*
Author to whom correspondence should be addressed.
Symmetry2021,13(11), 2230;https://doi.org/10.3390/sym13112230
Submission received: 8 October 2021 /Revised: 29 October 2021 /Accepted: 10 November 2021 /Published: 22 November 2021

Abstract

:
In this paper, a new type of terahertz (THz) metamaterial (MM) modulator has been presented with bifunctional properties based on vanadium dioxide (VO2). The design consists of a VO2 resonator, polyimide substrate, frequency selective surface (FSS) layer, and VO2 film. Based on the metal-insulator transition (MIT) of VO2, this structure integrated with VO2 material can achieve the dynamic modulation on both transmission and reflection waves at 2.5 THz by varying the electrical conductivity value of VO2. Meanwhile, it also exhibits adjustable absorption performance across the whole band from 0.5–7 THz. At the lower conductivity (σ = 25 S/m), this structure can act as a bandpass FSS, and, at the high conductivity (σ = 2 × 105 S/m), it behaves like a wideband absorber covering 2.52–6.06 THz with absorptionA > 0.9, which realizes asymmetric transmission. The surface electric field distributions are illustrated to provide some insight into the physical mechanism of dynamic modulation. From the simulated results, it can be observed that this design has the capability of controlling tunable manipulation on both transmission/reflection responses at a wide frequency band. This proposed design may pave a novel pathway towards thermal imaging, terahertz detection, active modulators, etc.

    1. Introduction

    In the past decade, metamaterial (MM), a kind of artificially periodic or non-periodic structure, has demonstrated outstanding electromagnetic (EM) functionalities that are not realized in natural materials such as water, soil, wood, and so on. Owing to its extraordinary EM characteristics, MM usually offers spatial potential to the asymmetric transmission in manipulating the amplitude, phase, or polarization of the incident EM waves [1,2,3,4,5], which enables them to be extensively studied; plentiful applications have been proposed in different regions including the polarization converter [6,7,8], the antenna [9,10,11,12,13], absorber [14,15,16], etc., which has greatly promoted the development of functional devices.
    Currently, to control and manipulate the transmission/reflection response [17,18,19], a variety of active structures based on metamaterials, such as the tunable frequency selective surface (FSS) [20,21], switchable absorber [22,23,24], and coding metasurface [25,26], have been designed to implement the dynamic modulation performance. However, though the concept and design of active devices that are incorporated with active components (PIN diodes and varactor diodes) [27] make it possible to achieve the dynamic manipulation on the EM waves [28,29], it is not suitable for the application in the terahertz (THz) field due to the high cost and complicated manufacturing processes. At the same time, it is difficult to realize the rapid switching of absorbing, transmitting, and reflecting states in the THz regime.
    To solve these problems, phase-change materials (PCM), for instance, graphene [30,31], liquid crystal [32], and vanadium dioxide (VO2) [33], have attracted extensive attention due to their unique electromagnetic and optical performances that can be directly controlled by adopting external excitations, making them a potential new way to manipulate THz waves. Among them, VO2 is more preferable to implement a dynamic modulation response in THz frequencies for its electrical and optical characteristics near room temperature. VO2 can achieve an ultrafast [34] and brutal reversible metal–insulator transition (MIT) from insulator to metal provoked by thermal [35], electrical [36], or optical [37] stimuli. Although the active modulation can be faster and more efficient if excited by the electrical or optical method as compared to thermal excitation, electrical stimuli need a complex biasing network and then, the fabrication difficulty would increase significantly in the THz regime. Meanwhile, the external laser source is required for applying the optical method, making the operating system bulky and the cost high. Thus, thermal excitation is an ideal choice for modulating the property of VO2. There is a dramatic variation in the electrical and optical performance during the phase transition (4–5 order of magnitude change on the electrical conductivityσVO2), so VO2 is a promising candidate in tunable MM devices at THz frequencies to achieve excellent modulation characteristics. Therefore, VO2 is of crucial importance and can be employed in THz devices to tailor various performances. Indeed, a lot of research fields have been focused on VO2-based tunable devices to obtain adjustable and switchable functions, such as reconfigurable THz filters [38,39,40], polarization converters [41,42,43], tunable THz absorbers [44,45,46], and so on. However, to the best of our knowledge, few works have been presented to achieve multiple functionalities that can be dynamically adjusted in THz devices.
    In this manuscript, a novel VO2-based THz MM modulator is proposed. By introducing the phase change material VO2, this design can be capable of dynamically controlling the transmission/reflection response of the incident waves. WhenσVO2 gradually changes from 25 to 2 × 105 S/m with the external temperature increasing, the transmittance would slowly decrease from 0.89 to approximately 0 around 2.5 THz, and absorption behavior performs dynamic modulation across 0.5–7 THz. In the case of insulating state (σVO2 = 25 S/m), this structure can be used as a bandpass FSS, while whenσVO2 = 2 × 105 S/m, it acts as a wideband absorber over the frequency band of 2.52–6.06 THz, covering 82.5% fractional bandwidth with absorptivity of more than 0.9. The electric field distribution of this design on both top and FSS layers is provided to investigate the physical mechanism for the different states. It can be believed that this proposed design would have great potential in the applications of thermal imaging, remote sensing, and wireless communication systems, etc., due to its excellent characteristics.

    2. Metamaterials (MM) Structure and Design

    The three-dimensional (3D) view of the proposed unit cell geometry with a 2-dimensional (2D) array is shown in detail inFigure 1. This design is a four-layer periodic structure, which, from top to bottom, is composed of a tunable resonator designed with circle and cross geometries, polyimide substrate, bandpass FSS layer, and the ground plate. Among them, the resonator and ground plate are both symmetrical patterns and made of vanadium dioxide (VO2) material with thicknesses oft1 = 0.2 μm andt2 = 0.5 μm, respectively. The dielectric constant of polyimide substrate is 3.5 with a tangent loss oftanδ=0.0027 and a thickness (h) of 9 μm. The gold is selected as a metal model for the bandpass FSS structure with a thickness (t2) of 0.2 μm, and a conductivity (σ) of 4.561 × 107 S/m.
    During the insulator-to-metal transition of VO2, the conductivity value (σVO2) can be dynamically adjusted, and its electrical characteristics will also be modulated accordingly. When the external temperature is lower (<300 K), VO2 is in the insulating state as the insulator; as the external temperature is over 340 K [47], it would be in a metallic state like metal. According to the Bruggeman effective-medium theory, the complex dielectric properties of VO2 can be described as follows:
    εeff=14{εi(23V)+εm(3V1)+[εi(23V)+εm(3V1)]+8εiεm}
    whereεi andεm are the dielectric permittivities of the insulating and metallic states of VO2, respectively. Additionally,V represents the volume fraction of the metallic region. When the external temperature changes, VO2 can transform between the insulating and metallic states.εm can be calculated by using the Drude model:
    εm(ω)=εiωp2ω(ω+i/τ)
    Here,ε=12 is the dielectric permittivity at high frequency;τ = 5.75 × 1013 rad/s represents the collision frequency; andωp=σ/εoτ denotes the plasma frequency.V can be defined as:
    V=Vmax(111+exp[(TTo)/ΔT])
    whereTo is the critical temperature of phase transition;ΔT denotes the temperature difference of the external thermal excitation between the heating and cooling processes; andVmax describes the maximum limit volume distribution in the metallic state during the phase transition (≈0.95). Thus, based on the Equations (1)–(3), the effective conductivity of VO2 material under different temperature cases can be expressed as:
    σeff(ω)=iεoω(εeff(ω)1)
    Figure 2 illustrates the experimental results of the conductivity of VO2 for different temperature states. From the results, it is worth noting the conductivity of VO2 can change from 25 S/m at 300 K to 2.5 × 105 S/m at 370 K during the phase transition. When the temperature is above 350 K, the conductivity is over 2 × 105 S/m. Therefore, in simulation, the conductivity (σvo2) of VO2 is assumed in the range from 25 to 2 × 105 S/m.

    3. Results and Discussion

    The numerical simulations of this design are carried out by using the commercial software CST Microwave Studio. The periodic boundary conditions are adopted along thex- andy-directions to model the infinite array. Floquet ports are used to excite the incident plane waves. Meanwhile, the absorbanceA(ω) can be calculated byA(ω)=1R(ω)T(ω), whereR(ω)=|S11(ω)|2 andT(ω)=|S21(ω)|2 represent reflectance and transmittance, respectively.
    The simulated frequency responses under different conductivity values are described inFigure 3. InFigure 3a, there is a transmission peak appearing at the frequency of 2.5 THz; the transmission coefficient gradually decreases as the conductivity of VO2 (σvo2) increases, and whenσvo2 is above 2 × 103 S/m, the transmission peak almost disappears. Then, as the valueσvo2 progressively goes from 25 to 2 × 105 S/m, the transmission coefficient would slowly decrease from 0.9 to nearly 0, the amplitude modulation depth of transmission is approximately 200% at 2.5 THz, and so do the reflection results accordingly, as shown inFigure 3b,c; this obviously demonstrates that this design can achieve dynamically tunable absorption property under normal incidence across the whole frequency band of 0.5–7 THz by changing the conductivity of VO2. There is a wide absorption bandwidth in the frequency band ranging from 2.52 to 6.06 THz with the fractional bandwidth of 82.5%, as the absorptance is more than 0.9 whenσvo2 = 2 × 105 S/m. However, in the insulating state (σvo2 = 25 S/m), VO2 behaves like the insulator and the incident EM waves can transit with low insertion loss, so then this design can act as a bandpass FSS. When it is in the metallic state (σvo2 = 2 × 105 S/m), VO2 can be regarded as metal; the majority of incident EM waves would be reflected by the bottom VO2 film, and then absorbed by the top VO2 resonator due to ohmic loss to realize the wide absorption performance. The above results clearly indicate that this design achieves the adjustable and switchable functions by controlling the characteristics of phase transition of VO2 material.
    In an attempt to achieve a better physical insight on the working operation of this design, the electric field distributions at both top and FSS layers are investigated and shown in detail inFigure 4 at three different frequencies, in which the color refers to the intensities of the electric field.
    At the frequency of 2.5 THz, fromFigure 4a, the electric field is mainly distributed on the upper and lower edges of the loop-shaped aperture of the FSS layer to form the resonance and the incident waves can be allowed to pass through the structure. There exists a small part of the electric field on the top resonator, which is the reason for insertion loss at the passband. Thus, the design can produce an EM transparent window at 2.5 THz with an insertion loss asσvo2 = 25 S/m. InFigure 4b, it can be seen that the electric field is mainly focused on the four arms of the top resonator at 3.1 THz. For the frequency of 5.3 THz, an amount of the electric field is concentrated on both left and right sides of the circle of the top layer, as illustrated inFigure 4c. The electric field distributions indicate that the absorption mainly comes from the ohmic dissipation of the top VO2 resonator whenσvo2 = 2 × 105 S/m for these two frequencies.
    As a result, the proposed configuration incorporated with VO2 material generates a highly effective modulation performance on the transmission/reflection response. It demonstrates that the transmission/reflection modulation located at 2.5 THz and the tunable absorption property is implemented simultaneously by applying phase-change material VO2.
    Figure 5 depicts the oblique incidence properties for two different conductivity states in both cases of TE and TM polarizations. From the above results, it is seen that this design maintains relatively robust angular stability at the passband of 2.5 THz over the incident angle (θ, the angle between the incident wave vectork and thez-axis), ranging from 0° to 45° for both TE and TM waves inFigure 5a,b withσvo2 = 25 S/m. However, some harmonics are appearing at the higher frequencies for both cases, asθ is greater than 15°, which is attributed to the mutual coupling between adjacent units.Figure 5c,d describes the absorption responses against the incident angle (θ) asσvo2 = 2 × 105 S/m. In TE mode, the absorption gradually deteriorates whenθ goes up to 45° at the lower absorption band with the absorptance > 0.8, as plotted inFigure 5c. It can be ascribed to the fact that the parallelE-field component gradually decreases with increasingθ. On the contrary, the absorption performance almost remains stable even thoughθ reaches up to 45° for the TM mode because the parallelE-field component stays nearly unchanged. From the above results, for the TM mode, the design has good angular stability on absorption performance as compared with that in the TE mode whenθ increases up to 45°, as detailed inFigure 5d.

    4. Conclusions

    In conclusion, a tunable THz MM modulator with bifunctional properties integrated with VO2 has been presented in the article. By utilizing the phase transition performance of VO2 from the insulator to metal, the proposed design can realize the dynamic manipulation of the incident THz waves. Compared to the previous works, this design has high modulation characteristics for the transmission/reflection and absorption responses. With the conductivityσVO2 changing from 25 to 2 × 105 S/m, the design provides high modulation depth on the transmission/reflection at the frequency of 2.5 THz, and achieves the tunable absorption performance over the whole frequency band of 0.5–7 THz. At the lower conductivity (σVO2 = 25 S/m), this design can be used as the bandpass FSS, while also acting as a wider absorber across the operating frequency band ranging from 2.52–6.06 THz with the absorption of over 0.9 and fractional bandwidth of 82.5% asσVO2 = 2 × 105 S/m. In addition, it still possesses the polarization-insensitivity performance for structural symmetry. The design demonstrates attractive advantages, which paves a new way towards the THz modulator with asymmetric transmission property, and may be extensively applied to biological imaging, thermal scanning, THz camouflage, etc.

    Author Contributions

    This study was conducted through the contributions of all authors. Conceptualization, investigation, validation, writing—original draft preparation, D.Y. and Y.D.; software, writing—review and editing, G.L. and M.L.; visualization, supervision, L.-A.B. All authors have read and agreed to the published version of the manuscript.

    Funding

    This work was supported by the Young Creative Talents Project of Guangdong Provincial Department of Education under Grant No. 2020KQNCX203.

    Conflicts of Interest

    The authors declare no conflict of interest.

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    Symmetry 13 02230 g001 550
    Figure 1. Unit cell of the proposed design. (a) 3D view; (b) 2D array. The parameters are (μm):p = 25,l1 = 8.5,l2 = 16,l3 = 10,w1 =w2 = 2,w3 = 1,r = 4,h = 9,t1 =t2 = 0.2,t3 = 0.5.
    Figure 1. Unit cell of the proposed design. (a) 3D view; (b) 2D array. The parameters are (μm):p = 25,l1 = 8.5,l2 = 16,l3 = 10,w1 =w2 = 2,w3 = 1,r = 4,h = 9,t1 =t2 = 0.2,t3 = 0.5.
    Symmetry 13 02230 g001
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    Figure 2. The measured conductivity of VO2 under different temperature cases.
    Figure 2. The measured conductivity of VO2 under different temperature cases.
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    Figure 3. The simulated results of this design for different conductivity states: (a) transmission; (b) reflection; (c) absorption.
    Figure 3. The simulated results of this design for different conductivity states: (a) transmission; (b) reflection; (c) absorption.
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    Symmetry 13 02230 g004 550
    Figure 4. The electric field distributions on the top and FSS layers at (a) 2.5 THz, (b) 3.1 THz, and (c) 5.3 THz, respectively.
    Figure 4. The electric field distributions on the top and FSS layers at (a) 2.5 THz, (b) 3.1 THz, and (c) 5.3 THz, respectively.
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    Figure 5. The transmission/reflection and absorption performances under different incident angles under (a,c) TE and (b,d) TM modes for different conductivity states.
    Figure 5. The transmission/reflection and absorption performances under different incident angles under (a,c) TE and (b,d) TM modes for different conductivity states.
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    Dong, Y.; Yu, D.; Li, G.; Lin, M.; Bian, L.-A. Terahertz Metamaterial Modulator Based on Phase Change Material VO2.Symmetry2021,13, 2230. https://doi.org/10.3390/sym13112230

    AMA Style

    Dong Y, Yu D, Li G, Lin M, Bian L-A. Terahertz Metamaterial Modulator Based on Phase Change Material VO2.Symmetry. 2021; 13(11):2230. https://doi.org/10.3390/sym13112230

    Chicago/Turabian Style

    Dong, Yanfei, Dingwang Yu, Gaosheng Li, Mingtuan Lin, and Li-An Bian. 2021. "Terahertz Metamaterial Modulator Based on Phase Change Material VO2"Symmetry 13, no. 11: 2230. https://doi.org/10.3390/sym13112230

    APA Style

    Dong, Y., Yu, D., Li, G., Lin, M., & Bian, L.-A. (2021). Terahertz Metamaterial Modulator Based on Phase Change Material VO2.Symmetry,13(11), 2230. https://doi.org/10.3390/sym13112230

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