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HomeStructure of 2,10-dibromo-3-chloro-7R,8S-epoxychamigrene
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Structure of 2,10-dibromo-3-chloro-7R,8S-epoxychamigrene

    Published/Copyright:August 25, 2010
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    De Gruyter (O)
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    Abstract

    C15H23OBr2Cl,Mr = 411.98, orthorhombic,P212121,a = 7.232(7),b = 11.923(16),c = 19.046(19) Å,V = 1642.3 Å3,Z = 4,Dx = 1.67 Mgm−3, Mo,λ = 0.71069 Å,μ = 49.7 cm−1,F(000) = 832,T = 293 K,R = 0.089 for 1263 reflexions. The two rings are joined at the spiro carbon C(6) and adopt chair [C(1) → C(6)] and half-chair [C(6) → C(11)] conformations. Extensive decomposition of the crystals occurred in the X-ray beam.

    Published Online:2010-08-25
    Published in Print:1989
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    Articles in the same Issue

    1. Structure of 2,10-dibromo-3-chloro-7R,8S-epoxychamigrene
    2. Structural determination of a lead-lithium monophosphate, LiPbPO4
    3. Reciprocal lattice scan modes in single crystal diffractometry: a reexamination for cases of mineralogical interest
    4. Experimental charge density in polythionate anions: II. X-ray study of the electron density distribution in potassium tetrathionate, K2S4O6
    5. An uncommon Cu[2+4]O6 coordination polyhedron in the crystal structure of KCu3(OH)2[(AsO4)H(AsO4)] (with a comparison to related structure types)
    6. Some aspects of information theory and phase problem: Effect of heavy atoms on information content inP[unk]
    7. The crystal structure of hexaaquacopper(II) bis(7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato)cuprate(II)
    8. Crystal and molecular structure of an isostere of purine ring system: 7-benzylamino-2-methylmercaptothiazolo [5,4-d] pyrimidine
    9. A novel form of molybdenum (V) phosphate:δ-KMo2P3O13
    10. Structure cristalline et moléculaire du camphosulfonate de l'α-(tétrahydro-4,5,6,7 thiéno (3,2-c) pyridyl-5) (chloro-2 phényl)-acétate de méthyle, C26H32NO6S2Cl. Configuration absolue
    11. Verfeinerung der Kristallstruktur von Holmquistit vom Brandrücken/Weinebene, Koralpe, Österreich
    12. Structural relationships of zeolite frameworks: “5-ring zeolites”
    13. Symmetry restrictions on minimal surfaces related by the Bonnet-transformation
    14. Crystal and molecular structure of N-p-fluorobenzoyl-l-valine
    15. Thermal decay of laser-induced long living metastable electronic states in Na2[Fe(CN)5NO] · 2H2O single crystals
    16. Crystal structures of three substituted ammonium hexachlororhenates(IV)
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    Articles in the same Issue

    1. Structure of 2,10-dibromo-3-chloro-7R,8S-epoxychamigrene
    2. Structural determination of a lead-lithium monophosphate, LiPbPO4
    3. Reciprocal lattice scan modes in single crystal diffractometry: a reexamination for cases of mineralogical interest
    4. Experimental charge density in polythionate anions: II. X-ray study of the electron density distribution in potassium tetrathionate, K2S4O6
    5. An uncommon Cu[2+4]O6 coordination polyhedron in the crystal structure of KCu3(OH)2[(AsO4)H(AsO4)] (with a comparison to related structure types)
    6. Some aspects of information theory and phase problem: Effect of heavy atoms on information content inP[unk]
    7. The crystal structure of hexaaquacopper(II) bis(7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato)cuprate(II)
    8. Crystal and molecular structure of an isostere of purine ring system: 7-benzylamino-2-methylmercaptothiazolo [5,4-d] pyrimidine
    9. A novel form of molybdenum (V) phosphate:δ-KMo2P3O13
    10. Structure cristalline et moléculaire du camphosulfonate de l'α-(tétrahydro-4,5,6,7 thiéno (3,2-c) pyridyl-5) (chloro-2 phényl)-acétate de méthyle, C26H32NO6S2Cl. Configuration absolue
    11. Verfeinerung der Kristallstruktur von Holmquistit vom Brandrücken/Weinebene, Koralpe, Österreich
    12. Structural relationships of zeolite frameworks: “5-ring zeolites”
    13. Symmetry restrictions on minimal surfaces related by the Bonnet-transformation
    14. Crystal and molecular structure of N-p-fluorobenzoyl-l-valine
    15. Thermal decay of laser-induced long living metastable electronic states in Na2[Fe(CN)5NO] · 2H2O single crystals
    16. Crystal structures of three substituted ammonium hexachlororhenates(IV)
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