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For a compact$3$-manifold$M$ with arbitrary (possibly empty) boundary, we give a parameterization of the set of conjugacy classes of boundary-unipotent representations of${\pi }_1\left(M\right)$ into$SL(n,\mathbb{C})$. Our parameterization uses Ptolemy coordinates, which are inspired by coordinates on higher Teichmüller spaces due to Fock and Goncharov. We show that a boundary-unipotent representation determines an element in Neumann’s extended Bloch group$\hat{\mathcal{B}}\left(\mathbb{C}\right)$, and we use this to obtain an efficient formula for the Cheeger–Chern–Simons invariant, and, in particular, for the volume. Computations for the census manifolds show that boundary-unipotent representations are abundant, and numerical comparisons with census volumes suggest that the volume of a representation is an integral linear combination of volumes of hyperbolic$3$-manifolds. This is in agreement with a conjecture of Walter Neumann, stating that the Bloch group is generated by hyperbolic manifolds.