Chemistry of the solanidane ring system
Abstract
The reaction of acetyldemissidine and acetylsolanidine with cyanogen bromide is described and the results of the lithium aluminium hydride reduction of the bromo-cyanamides so produced are discussed. The hydrolysis of acetyldemissidine bromo-cyanamide under very mild conditions caused a retro-von Braun reaction to afford the initial alkaloid.
Please wait while we load your content... Something went wrong.Try again?Article information
- Article type
- Paper
Permissions
Chemistry of the solanidane ring system
J. A. Beisler and Y. Sato,J. Chem. Soc. C, 1971, 149DOI: 10.1039/J39710000149
To request permission to reproduce material from this article, please go to theCopyright Clearance Center request page.
If you arean author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you arethe author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to theCopyright Clearance Center request page.
Read more abouthow to correctly acknowledge RSC content.