Pulp is a fibrouslignocellulosic material prepared by chemically, semi-chemically, or mechanically isolating thecellulosic fibers ofwood,fiber crops,waste paper, orrags. Mixed with water and other chemicals or plant-based additives, pulp is the major raw material used inpapermaking and the industrial production of otherpaper products.[1][2]
Before the widely acknowledged invention ofpapermaking byCai Lun in China around AD 105, paper-like writing materials such aspapyrus andamate were produced by ancient civilizations using plant materials which were largely unprocessed. Strips ofbark orbast material were woven together, beaten into rough sheets, dried, and polished by hand.[3][4] Pulp used in modern and traditionalpapermaking is distinguished by themaceration process which produces a finer, more regular slurry of cellulose fibers which are pulled out of solution by a screen and dried to form sheets or rolls.[5] The earliest paper produced in China consisted of bast fibers from thepaper mulberry (kozo) plant along withhemp rag and net scraps.[5][6][7] By the 6th century, the mulberry tree was domesticated by farmers in China specifically for the purpose of producing pulp to be used in the papermaking process. In addition to mulberry, pulp was also made frombamboo,hibiscus bark,blue sandalwood,straw, andcotton.[7] Papermaking using pulp made from hemp andlinen fibers from tattered clothing, fishing nets and fabric bags spread to Europe in the 13th century, with an ever-increasing use of rags being central to the manufacture and affordability ofrag paper, a factor in the development ofprinting.[1] By the 1800s, production demands on the newly industrialized papermaking and printing industries led to a shift in raw materials, most notably the use ofpulpwood and other tree products which today make up more than 95% of global pulp production.[8]
The use of wood pulp and the invention of automaticpaper machines in the late 18th- and early 19th-century contributed to paper's status as an inexpensive commodity in modern times.[1][9][10] While some of the earliest examples of paper made from wood pulp include works published byJacob Christian Schäffer in 1765 andMatthias Koops in 1800,[1][11] large-scale wood paper production began in the 1840s with unique, simultaneous developments in mechanical pulping made byFriedrich Gottlob Keller in Germany[12] and byCharles Fenerty inNova Scotia.[9] Chemical processes quickly followed, first withJ. Roth's use ofsulfurous acid to treat wood, then byBenjamin Tilghman'sU.S. patent on the use ofcalcium bisulfite, Ca(HSO3)2, to pulp wood in 1867.[2] Almost a decade later, the first commercialsulfite pulp mill was built, in Sweden. It usedmagnesium as thecounter ion and was based on work byCarl Daniel Ekman. By 1900, sulfite pulping had become the dominant means of producing wood pulp, surpassing mechanical pulping methods. The competing chemical pulping process, the sulfate, orkraft, process, was developed byCarl F. Dahl in 1879; the first kraft mill started, in Sweden, in 1890.[2] The invention of therecovery boiler, byG.H. Tomlinson in the early 1930s,[12] allowed kraft mills to recycle almost all of their pulping chemicals. This, along with the ability of the kraft process to accept a wider variety of types of wood and to produce stronger fibres,[13] made the kraft process the dominant pulping process, starting in the 1940s.[2]
Global production of wood pulp in 2006 was 175 million tons (160 million tonnes).[14] In the previous year, 63 million tons (57 million tonnes) of market pulp (not made into paper in the same facility) was sold, with Canada being the largest source at 21 percent of the total, followed by the United States at 16 percent. Thewood fiber sources required for pulping are "45% sawmill residue, 21% logs and chips, and 34% recycled paper" (Canada, 2014).[15] Chemical pulp made up 93% of market pulp.[16]
Thetimber resources used to make wood pulp are referred to aspulpwood.[17] While in theory any tree can be used for pulp-making,coniferous trees are preferred because the cellulose fibers in the pulp of these species are longer, and therefore make stronger paper.[18]Some of the most commonly used trees for paper making includesoftwoods such asspruce,pine,fir,larch andhemlock, andhardwoods such aseucalyptus,aspen andbirch.[19] There is also increasing interest ingenetically modified tree species (such as GMeucalyptus and GMpoplar) because of several major benefits these can provide, such as increased ease of breaking down lignin and increased growth rate.
Apulp mill is a manufacturing facility that converts wood chips or other plant fibre source into a thick fiberboard which can be shipped to apaper mill for further processing. Pulp can be manufactured using mechanical, semi-chemical or fully chemical methods (kraft and sulfite processes). The finished product may be eitherbleached or non-bleached, depending on the customer requirements.
Wood and other plant materials used to make pulp contain three main components (apart from water): cellulose fibers (desired for papermaking),lignin (a three-dimensional polymer that binds the cellulose fibres together) andhemicelluloses (shorter branchedcarbohydratepolymers). The aim of pulping is to break down the bulk structure of the fibre source, be it chips, stems or other plant parts, into the constituent fibres.
Chemical pulping achieves this by degrading the lignin and hemicellulose into small, water-soluble molecules which can be washed away from the cellulose fibres withoutdepolymerizing the cellulose fibres (chemically depolymerizing the cellulose weakens the fibres). The various mechanical pulping methods, such as groundwood (GW) and refiner mechanical pulping (RMP), physically tear the cellulose fibres one from another. Much of the lignin remains adhering to the fibres. Strength is impaired because the fibres may be cut. There are a number of related hybrid pulping methods that use a combination of chemical and thermal treatment to begin an abbreviated chemical pulping process, followed immediately by a mechanical treatment to separate the fibres. These hybrid methods include thermomechanical pulping, also known as TMP, and chemithermomechanical pulping, also known as CTMP. The chemical and thermal treatments reduce the amount of energy subsequently required by the mechanical treatment, and also reduce the amount of strength loss suffered by the fibres.
| Pulp category | Production [Mton] |
| Chemical | 131.2 |
| Kraft | 117.0 |
| Sulfite | 7.0 |
| Semichemical | 7.2 |
| Mechanical | 37.8 |
| Nonwood | 18.0 |
| Total virgin fibres | 187.0 |
| Recovered fibres | 147.0 |
| Total pulp | 334.0 |
Most pulp mills use goodforest management practices in harvesting trees to ensure that they have a sustainable source of raw materialscitation required. One of the major complaints about harvesting wood for pulp mills is that it reduces thebiodiversity of the harvested forest. Pulptree plantations account for 16 percent of world pulp production,old-growth forests 9 percent, and second- and third- and more generation forests account for the rest.[21]Reforestation is practiced in most areas, so trees are arenewable resource. The FSC (Forest Stewardship Council), SFI (Sustainable Forestry Initiative), PEFC (Programme for the Endorsement of Forest Certification), and other bodies certify paper made from trees harvested according to guidelines meant to ensure good forestry practices.[22]
The number of trees consumed depends on whether mechanical processes or chemical processes are used. It has been estimated that based on a mixture ofsoftwoods andhardwoods 12 metres (40 ft) tall and 15–20 centimetres (6–8 in) in diameter, it would take an average of 24 trees to produce 0.9 tonne (1 ton) of printing and writing paper, using thekraft process (chemical pulping). Mechanical pulping is about twice as efficient in using trees, since almost all of the wood is used to make fibre, therefore it takes about 12 trees to make 0.9 tonne (1 ton) of mechanical pulp ornewsprint.[23]
There are roughly two short tons in acord of wood.[24]
Wood chipping is the act and industry of chipping wood for pulp, but also for otherprocessed wood products andmulch. Only theheartwood andsapwood are useful for making pulp.Bark contains relatively few useful fibers and is removed and used as fuel to provide steam for use in the pulp mill. Most pulping processes require that the wood be chipped and screened to provide uniform sized chips.
There are a number of different processes which can be used to separate the wood fiber:
Manufacturedgrindstones with embeddedsilicon carbide oraluminum oxide can be used to grind small wood logs called "bolts" to make stone pulp (SGW). If the wood is steamed prior to grinding it is known as pressure ground wood pulp (PGW). Most modern mills use chips rather than logs and ridged metal discs called refiner plates instead of grindstones. If the chips are just ground up with the plates, the pulp is called refiner mechanical pulp (RMP) and if the chips are steamed while being refined the pulp is called thermomechanical pulp (TMP). Steam treatment significantly reduces the total energy needed to make the pulp and decreases the damage (cutting) to fibres. Mechanical pulps are used for products that require less strength, such asnewsprint andpaperboards.
Thermomechanical pulp is pulp produced by processingwood chips using heat (thus "thermo-") and a mechanical refining movement (thus "-mechanical"). It is a two-stage process where the logs are first stripped of theirbark and converted into small chips. These chips have a moisture content of around 25–30 percent. A mechanical force is applied to the wood chips in a crushing or grinding action which generates heat and water vapour and softens thelignin thus separating the individual fibres. The pulp is then screened and cleaned, any clumps of fibre are reprocessed. This process gives a high yield of fibre from thetimber (around 95 percent) and as the lignin has not been removed, the fibres are hard and rigid.[25]
Wood chips can be pre-treated withsodium carbonate,sodium hydroxide,sodium sulfate and other chemicals prior to refining with equipment similar to a mechanical mill. The conditions of the chemical treatment are much less vigorous (lower temperature, shorter time, less extremepH) than in a chemical pulping process since the goal is to make the fibers easier to refine, not to remove lignin as in a fully chemical process. Pulps made using these hybrid processes are known as chemi-thermomechanical pulps (CTMP).
Chemical pulp is produced by combining wood chips and chemicals in large vessels called digesters. There, heat and chemicals break down lignin, which bindscellulose fibres together, without seriously degrading thecellulose fibres. Chemical pulp is used for materials that need to be stronger or combined with mechanical pulps to give a product different characteristics. Thekraft process is the dominant chemical pulping method, with thesulfite process second. Historicallysoda pulping was the first successful chemical pulping method.
Recycled pulp is also calleddeinked pulp (DIP). DIP isrecycled paper which has been processed by chemicals, thus removingprinting inks and other unwanted elements and freed the paper fibres. The process is calleddeinking.
DIP is used as raw material inpapermaking. Manynewsprint,toilet paper andfacial tissue grades commonly contain 100 percent deinked pulp and in many other grades, such as lightweight coated for offset and printing and writing papers for office and home use, DIP makes up a substantial proportion of the furnish.
Organosolv pulping uses organic solvents at temperatures above 140 °C to break down lignin and hemicellulose into soluble fragments. The pulping liquor is easily recovered by distillation. The reason for using a solvent is to make thelignin more soluble in the cooking liquor. Most common used solvents aremethanol,ethanol,formic acid andacetic acid often in combination withwater.
Research is under way to develop biopulping (biological pulping), similar to chemical pulping but using certain species offungi that are able to break down the unwanted lignin, but not the cellulose fibres.[26] In the biopulping process, the fungal enzymelignin peroxidase selectively digests lignin to leave remaining cellulose fibres. This could have majorenvironmental benefits in reducing the pollution associated with chemical pulping. The pulp is bleached usingchlorine dioxide stage followed by neutralization andcalcium hypochlorite. Theoxidizing agent in either case oxidizes and destroys the dyes formed from thetannins of the wood and accentuated (reinforced) bysulfides present in it.
Steam exploded fibre is a pulping and extraction technique that has been applied to wood and other fibrous organic material.[27]
The pulp produced up to this point in the process can bebleached to produce awhite paper product. The chemicals used to bleach pulp have been a source of environmental concern, and recently the pulp industry has been using alternatives tochlorine, such aschlorine dioxide,oxygen,ozone andhydrogen peroxide.
Pulp made from non-wood plant sources orrecycled textiles is manufactured today largely as a speciality product for fine-printing and art purposes.[8] Modern machine- and hand-made art papers made with cotton, linen, hemp,abaca,kozo, and other fibers are often valued for their longer, stronger fibers and their lowerlignin content.Lignin, present in virtually all plant materials, contributes to the acidification and eventual breakdown of paper products, often characterized by the browning and embrittling of paper with a high lignin content such asnewsprint.[28][29] 100% cotton or a combination of cotton and linen pulp is widely used to produce documents intended for long-term use, such as certificates, currency, and passports.[30][31][32]
Today, some groups advocate using field crop fibre or agricultural residues instead of wood fibre as a moresustainable means of production.[citation needed]
There is enoughstraw to meet much of North America's book, magazine, catalogue and copy paper needs.[citation needed] Agricultural-based paper does not come fromtree farms. Some agricultural residue pulps take less time to cook than wood pulps. That means agricultural-based paper uses less energy, less water and fewer chemicals. Pulp made from wheat and flax straw has half the ecological footprint of pulp made from forests.[33]
Hemp paper is a possible replacement, but processing infrastructure, storage costs and the low usability percentage of the plant means it is not a ready substitute.[citation needed]
However, wood is also a renewable resource, with about 90 percent of pulp coming fromplantations or reforested areas.[21] Non-wood fibre sources account for about 5–10 percent of global pulp production, for a variety of reasons, including seasonal availability, problems with chemical recovery, brightness of the pulp etc.[16][34] In China, as of 2009, a higher proportion of non-wood pulp processing increased use of water and energy.[35]
Nonwovens are in some applications alternatives to paper made from wood pulp, likefilter paper ortea bags.
| Component | Wood | Nonwood |
|---|---|---|
| Carbohydrates | 65–80% | 50–80% |
| 40–45% | 30–45% |
| 23–35% | 20–35% |
| Lignin | 20–30% | 10–25% |
| Extractives | 2–5% | 5–15% |
| Proteins | <0.5% | 5–10% |
| Inorganics | 0.1–1% | 0.5–10% |
| <0.1% | 0.5–7% |
Market pulp is any variety of pulp that is produced in one location, dried and shipped to another location for further processing.[37] Important quality parameters for pulp not directly related to the fibres arebrightness, dirt levels, viscosity and ash content. In 2004 it accounted for about 55 millionmetric tons of market pulp.[37]
Air dry pulp is the most common form to sell pulp. This is pulp dried to about 10 percent moisture content. It is normally delivered as sheeted bales of 250 kg. The reason to leave 10 percent moisture in the pulp is that this minimizes the fibre to fibre bonding and makes it easier to disperse the pulp in water for further processing topaper.[37]
Roll pulp orreel pulp is the most common delivery form of pulp to non traditional pulp markets.Fluff pulp is normally shipped on rolls (reels). This pulp is dried to 5–6 percent moisture content. At the customer this is going to a comminution process to prepare for further processing.[37]
Some pulps are flash dried. This is done by pressing the pulp to about 50 percent moisture content and then let it fall throughsilos that are 15–17 m high. Gas fired hot air is the normal heat source. The temperature is well above thechar point ofcellulose, but large amount of moisture in thefibre wall andlumen prevents the fibres from being incinerated. It is often not dried down to 10 percent moisture (air dry). The bales are not as densely packed as air dry pulp.[37]
The major environmental impacts of producing wood pulp come from its impact on forest sources and from its waste products.
The impact of logging to provide the raw material for wood pulp is an area of intense debate. Modernlogging practices, usingforest management seek to provide a reliable, renewable source of raw materials forpulp mills. The practice ofclear cutting is a particularly sensitive issue since it is a very visible effect oflogging.Reforestation, the planting of tree seedlings on logged areas, has also been criticized for decreasingbiodiversity because reforested areas aremonocultures.Logging ofold growth forests accounts for less than 10 percent of wood pulp,[21] but is one of the most controversial issues.
The process effluents are treated in a biologicaleffluent treatment plant, which guarantees that the effluents are not toxic in the recipient.
Mechanical pulp is not a major cause for environmental concern since most of the organic material is retained in the pulp, and the chemicals used (hydrogen peroxide andsodium dithionite) produce benign byproducts (water andsodium sulfate (finally), respectively).
Chemical pulp mills, especially kraft mills, are energy self-sufficient and very nearly closed cycle with respect to inorganic chemicals.
Bleaching with chlorine produces large amounts oforganochlorine compounds, including polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans (PCDD/Fs).[38][39] Many mills have adopted alternatives to chlorinated bleaching agents thereby reducing emissions of organochlorine pollution.[40]
The kraft pulping reaction in particular releases foul-smelling compounds. The sulfide reagent that degrades lignin structure also causes some demethylation, yieldingmethanethiol,dimethyl sulfide, anddimethyl disulfide.[41] These same compounds are released during many forms of microbial decay, including the internal microbial action inCamembert cheese, although the kraft process is a chemical one and does not involve any microbial degradation. These compounds have extremely low odor thresholds and disagreeable smells.
The main applications for pulp arepaper andboard production. The furnish of pulps used depends on the quality on the finished paper. Important quality parameters arewood furnish,brightness, viscosity, extractives, dirt count and strength.
Chemical pulps are used for makingnanocellulose.[citation needed]
Speciality pulp grades have many other applications.Dissolving pulp is used in makingregenerated cellulose that is usedtextile andcellophane production. It is also used to makecellulose derivatives.Fluff pulp is used indiapers,feminine hygiene products andnonwovens.
The Fourdrinier Machine is the basis for most modernpapermaking, and it has been used in some variation since its conception. It accomplishes all the steps needed to transform pulp into a finalpaper product.
In 2009,NBSK pulp sold for $650/ton in the United States. The price had dropped due to falling demand when newspapers reduced their size, in part, as a result of the recession.[42] By 2024 this price had recovered to $1315/ton.[43]
| Lumber/ timber | |
|---|---|
| Engineered wood | |
| Fuelwood | |
| Fibers | |
| Derivatives | |
| By-products | |
| Historical | |
| See also | |
