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Octatetraynyl radical

From Wikipedia, the free encyclopedia
Organic radical (HC≡CC≡CC≡CC≡C•)
Octatetraynyl radical
Skeletal formula of the octatetraynyl radical with the explicit hydrogen added
Skeletal formula of the octatetraynyl radical with the explicit hydrogen added
Names
Preferred IUPAC name
Octa-1,3,5,7-tetrayn-1-yl
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/C8H/c1-3-5-7-8-6-4-2/h1H checkY
    Key: GTEOCQSGHJLKQX-UHFFFAOYSA-N checkY
  • anion: InChI=1S/C8H/c1-3-5-7-8-6-4-2/h1H/q-1
    Key: JPYHXIJMECKQLV-UHFFFAOYSA-N
  • [C]#CC#CC#CC#C
  • anion: [C-]#CC#CC#CC#C
Properties
C8H
Molar mass97.096 g·mol−1
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Chemical compound

Octatetraynyl radical (C8H) is anorganicfree radical with eightcarbon atoms linked in alinear chain with alternatingsingle bonds andtriple bonds (H−C≡C−C≡C−C≡C−C≡C•).

In 2007 negatively charged octatetraynyl was detected in Galactic molecular sourceTMC-1, making it the second type ofanion to be found in theinterstellar medium (afterhexatriynyl radical) and the largest such molecule detected to date.[1][2]

References

[edit]
  1. ^Remijan, Anthony J.; J. M. Hollis; F. J. Lovas; M. A. Cordiner; T. J. Millar; A. J. Markwick-Kemper; P. R. Jewell (July 20, 2007)."Detection of C8H and Comparison with C8H toward IRC +10 216".The Astrophysical Journal.664 (1):L47 –L50.Bibcode:2007ApJ...664L..47R.doi:10.1086/520704.
  2. ^Brünken, S.; H. Gupta; C. A. Gottlieb; M. C. McCarthy; P. Thaddeus (July 20, 2007). "Detection of the Carbon Chain Negative Ion C8H in TMC-1".The Astrophysical Journal.664 (1):L43 –L46.Bibcode:2007ApJ...664L..43B.doi:10.1086/520703.S2CID 120912943.
Molecules
Diatomic








Triatomic
Four
atoms
Five
atoms
Six
atoms
Seven
atoms
Eight
atoms
Nine
atoms
Ten
atoms
or more
Deuterated
molecules
Unconfirmed
Related
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