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Fluorinert

From Wikipedia, the free encyclopedia
Brand of electronics coolant liquids

Fluorinert is the trademarked brand name for the line of electronics coolant liquids sold commercially by3M. Asperfluorinated compounds (PFCs), all Fluorinert variants have an extremely highglobal warming potential (GWP),[1] so should be used with caution (see below). It is anelectrically insulating, stablefluorocarbon-based fluid, which is used in various cooling applications. It is mainly used for cooling electronics. Different molecular formulations are available with a variety ofboiling points, allowing it to be used in "single-phase" applications, where it remains a liquid, or for "two-phase" applications, where the liquid boils to remove additional heat byevaporative cooling. An example of one of the compounds 3M uses is FC-72 (perfluorohexane, C6F14). Perfluorohexane is used for low-temperatureheat-transfer applications due to its 56 °C (133 °F) boiling point. Another example isFC-75, perfluoro(2-butyl-tetrahydrofurane). There are 3M fluids that can handle up to 215 °C (419 °F), such as FC-70 (perfluorotripentylamine).[2]

Fluorinert is used in situations where air cannot carry away enough heat, or where airflow is so restricted that some sort of forced pumping is required.

Toxicity

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Fluorinert may be harmful if inhaled, and care should be taken to avoid contact with eyes and skin. However, according to the documentation from the manufacturer, no health effects are expected from ingestion of Fluorinert.[3]Usage of fluorinated oils should be limited to closed systems and reduced volumes, since they have a very highglobal-warming potential and a longatmospheric lifetime.[4]

The Fluorinert-filled "fountain" of a Cray-2

Although Fluorinert was intended to be inert, theLawrence Livermore National Laboratory discovered that the liquid cooling system of theirCray-2 supercomputers decomposed during extended service, producing some highly toxicperfluoroisobutene.[5] Catalytic scrubbers were installed to remove this contaminant.

The science-fiction filmThe Abyss (1989) depicted an experimentalliquid-breathing system, in which the use of highly oxygenated Fluorinert enabled a diver to descend to great depths. While several rats were shown actually breathing Fluorinert, scenes depicting actorEd Harris using the fluid-breathing apparatus were simulated.[6]

Global warming potential

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Fluorinertperfluorotributylamine absorbs infra-red (IR) wavelengths readily and has a long atmospheric lifetime. As such, it has a very highglobal warming potential (GWP) of ~9,000,[1] and it should be used in closed systems only and carefully managed to minimize emissions.

Alternatives

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Due to Fluorinert's high global warming potential, alternative low global warming potential agents were found and sold under the brand names Novec Engineered Fluids. There are two types of chemical compounds under Novec branding for similar industrial applications:

  • Segregated Hydrofluoroether (HFE) compounds including Novec 7000, 7100, 7200, 7300, 7500, and 7700 has lower global warming potential (GWP) of ~300.[7]
  • Fluoroketones (FK) compounds includingNovec 649 and 774 has very low global warming potential (GWP) of 1. Novec 649 has similar thermo-physical properties to FC-72 making it a good drop-in replacement for low temperature heat transfer.[8]

See also

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References

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  1. ^abEnvironmental Protection Agency, Office of Air and Radiation."Report EPA-430-R-06-90: Uses and Emissions of Liquid PFC Heat Transfer Fluids from the Electronics Sector"(PDF).WWW.EPA.GOV. p. 3.Archived(PDF) from the original on 2017-07-27. Retrieved2018-02-03.
  2. ^"3M Manufacturing and Industry: 3M Fluorinert Electronic Liquids". Archived fromthe original on 2010-03-28. Retrieved2006-01-10.
  3. ^"Material safety data sheet FC-40 fluorinert brand electronic liquid 03/25/09".Archived from the original on 2009-08-21. Retrieved2009-05-19. 090519 multimedia.3m.com
  4. ^"Fluorinert FC70 Product Information"(PDF).Archived(PDF) from the original on 2011-07-07. Retrieved2011-02-03.
  5. ^Kwan, J. Kelly, R, Miller G. Presentation at the American Industrial Hygiene Conference, Salt Lake City, UT, May 1991
  6. ^Aljean Harmetz (August 6, 1989)."FILM; 'The Abyss': A Foray Into Deep Waters".The New York Times. Archived fromthe original on 2022-01-25.
  7. ^"3M Novec fluids as alternative to perfluorocarbons for detector cooling at CERN"(PDF). CERN.Archived(PDF) from the original on January 19, 2022. RetrievedApril 8, 2021.
  8. ^"3M Novec 649 as a replacement of C6F14 in liquid cooling systems"(PDF). CERN.Archived(PDF) from the original on April 10, 2021. RetrievedApril 8, 2021.

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