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Calcium stearate

From Wikipedia, the free encyclopedia
Calcium stearate
Names
Preferred IUPAC name
Calcium di(octadecanoate)
Other names
E470
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard100.014.976Edit this at Wikidata
UNII
  • InChI=1S/2C18H36O2.Ca/c2*1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18(19)20;/h2*2-17H2,1H3,(H,19,20);/q;;+2/p-2 checkY
    Key: CJZGTCYPCWQAJB-UHFFFAOYSA-L checkY
  • InChI=1/2C18H36O2.Ca/c2*1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18(19)20;/h2*2-17H2,1H3,(H,19,20);/q;;+2/p-2
    Key: CJZGTCYPCWQAJB-NUQVWONBAL
  • [Ca+2].[O-]C(=O)CCCCCCCCCCCCCCCCC.[O-]C(=O)CCCCCCCCCCCCCCCCC
Properties
C36H70CaO4
Molar mass607.030 g·mol−1
Appearancewhite to yellowish-white powder
Density1.08 g/cm3
Melting point155 °C (311 °F; 428 K)
0.004 g/100 mL (15 °C)
Solubilitysoluble in hotpyridine
slightly soluble inoil
insoluble inalcohol,ether
Hazards
NFPA 704 (fire diamond)
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Chemical compound

Calcium stearate is acarboxylate salt ofcalcium, classified as a calciumsoap. The salt is a component of somelubricants,surfactants, as well as many foodstuffs. It is a white waxy powder.[1]

Production and occurrence

[edit]

Calcium stearate is produced by heatingstearic acid andcalcium oxide:

2 C17H35COOH + CaO → (C17H35COO)2Ca + H2O

It is also the main component ofsoap scum, a white solid that forms when soap is mixed withhard water. Unlike soaps containing sodium and potassium, calcium stearate is insoluble in water and does not lather well.[2]Commercially it is sold as a 50% dispersion in water or as a spray dried powder. As afood additive it is known by the genericE number E470.

Applications

[edit]

Calcium stearate is a waxy material with low solubility in water, unlike traditional sodium and potassium soaps. It is also easy and cheap to produce, and exhibits low toxicity. These attributes are the basis of many of its applications. Related applications exist for the magnesium stearate.[1]

  • Calcium stearate is used as a flow agent and surface conditioner in some candies such asSmarties,jawbreakers andSprees.
  • It is a waterproofing agent for fabrics.
  • A lubricant in pencils and crayons.
  • A lubricant in thedry drawing method of wire production
  • The concrete industry uses calcium stearate forefflorescence control of cementitious products used in the production of concrete masonry units i.e.paver and block, as well aswaterproofing.[3]
  • In paper production, calcium stearate is used as a lubricant to provide good gloss, preventing dusting and fold cracking in paper and paperboard making.[4]
  • In plastics, it can act as an acid scavenger or neutralizer at concentrations up to 1000ppm, a lubricant and a release agent. It may be used inplastic colorant concentrates to improve pigment wetting. In rigid PVC, it can accelerate fusion, improve flow, and reduce die swell.
  • Applications in the personal care andpharmaceutical industry include tablet mold release, anti-tack agent, and gelling agent.
  • Calcium stearate is a component in some types ofdefoamers.
  • Anticaking agent for drugs etc.[5]

References

[edit]
  1. ^abNora A, Szczepanek A, Koenen G (2001). "Metallic Soaps".Ullmann's Encyclopedia of Industrial Chemistry.doi:10.1002/14356007.a16_361.ISBN 3527306730.
  2. ^Weingärtner H, Franck EU, Wiegand G, Dahmen N, Schwedt G, Frimmel FH, Gordalla BC, Johannsen K, Summers RS, Höll W, Jekel M, Gimbel R, Rautenbach R, Glaze WH (2000). "Water".Ullmann's Encyclopedia of Industrial Chemistry.doi:10.1002/14356007.a28_001.ISBN 3527306730.
  3. ^Preventing Efflorescence, Portland Cement Association
  4. ^US 5527383, Flynn, Gregory J.; Krasniewski, John M. & Wilson Jr., Joseph, "Lubricant additives for paper coating compositions", published 1996-06-18, assigned toHenkel Corp. 
  5. ^Lück E, von Rymon Lipinski GW (2000). "Foods, 3. Food Additives".Ullmann's Encyclopedia of Industrial Chemistry.doi:10.1002/14356007.a11_561.ISBN 3527306730.
Hydrogen & halogens
Chalcogens
Pnictogens
Group 13 & 14
Trans metals
Organics
Salts and covalent derivatives of thestearate ion
HCH3(CH2)16CO2He
LiCH3(CH2)16CO2Be(CH3(CH2)16CO2)2B(CH3(CH2)16CO2)3CNH4CH3(CH2)16CO2,-O-FNe
NaCH3(CH2)16CO2Mg(CH3(CH2)16CO2)2Al(CH3(CH2)16CO2)3Si(CH3(CH2)16CO2)4P(CH3(CH2)16CO2)3SClAr
KCH3(CH2)16CO2Ca(CH3(CH2)16CO2)2Sc(CH3(CH2)16CO2)3TiVCr(CH3(CH2)16CO2)2MnFe(CH3(CH2)16CO2)2
Fe(CH3(CH2)16CO2)3
Co(CH3(CH2)16CO2)2Ni(CH3(CH2)16CO2)2Cu(CH3(CH2)16CO2)2Zn(CH3(CH2)16CO2)2Ga(CH3(CH2)16CO2)3GeAs(CH3(CH2)16CO2)3SeBrKr
RbCH3(CH2)16CO2Sr(CH3(CH2)16CO2)2Y(CH3(CH2)16CO2)3Zr(CH3(CH2)16CO2)3NbMoTcRuRhPd(CH3(CH2)16CO2)2AgCH3(CH2)16CO2Cd(CH3(CH2)16CO2)2In(CH3(CH2)16CO2)3SnSb(CH3(CH2)16CO2)3TeIXe
CsCH3(CH2)16CO2Ba(CH3(CH2)16CO2)2*Lu(CH3(CH2)16CO2)3HfTaWReOsIrPtAuCH3(CH2)16CO2Hg2(CH3(CH2)16CO2)2,
Hg(CH3(CH2)16CO2)2
TlCH3(CH2)16CO2Pb(CH3(CH2)16CO2)2Bi(CH3(CH2)16CO2)3PoAtRn
FrRa**LrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg
 
*La(CH3(CH2)16CO2)3Ce(CH3(CH2)16CO2)3PrNdPmSm(CH3(CH2)16CO2)3Eu(CH3(CH2)16CO2)3Gd(CH3(CH2)16CO2)3TbDy(CH3(CH2)16CO2)3Ho(CH3(CH2)16CO2)3ErTmYb(CH3(CH2)16CO2)3
**Ac(CH3(CH2)16CO2)3Th(CH3(CH2)16CO2)4PaUO2(CH3(CH2)16CO2)2NpPuAmCmBkCfEsFmMdNo
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