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Wyllieite

A valid IMA mineral species
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(Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO4)3
Colour:
deep bluish-green to deep oily-green, gray-green, to greenish-black
Lustre:
Vitreous, Sub-Metallic
Hardness:
4 - 4½
Specific Gravity:
3.61 (Calculated)
Crystal System:
Monoclinic
Member of:
Wyllieite Group >Alluaudite Supergroup
Name:
Named by Paul B. Moore and Jun Ito in 1973 in honor of Peter John Wyllie (8 February 1930, London, England - ), Professor of Geology, University of Chicago (1965-1983) and the California Institute of Technology (1984-1999), for his work on granite melts in dry and aqueous conditions. He received the Roebling Medal in 2001.

The original wyllieite from the Victory Pegmatite, Custer, South Dakota, USA (Moore and Ito, 1973) was redefined by Moore and Ito (1979) as ferrowyllieite-MnNaNa, but their new wyllieite, designated by them as wyllieite-□NaCa, was not formally described except for a published chemical analysis and the implicit assertion that their material otherwise conformed to the wyllieite group (Min Mag 43:227, 1979).

The mineralrosemaryite is named for his wife.
Type Locality:
ⓘOld Mike mine (Great Northern; Old Mike M.S.2212), Custer, Custer Mining District, Custer County, South Dakota, USA
Wyllieite Group.Ferrowyllieite-Wyllieite Series, and theRosemaryite-Wyllieite Series.


Unique Identifiers
IMA Formula:
NaNaMn(Fe2+Al)(PO4)3
Approval year:
1972
First published:
1973
Type description reference:
Moore, Paul B., Ito, Jun (1973) Wyllieite, Na2Fe2+2Al(PO4)3: a New Species.The Mineralogical Record, 4 (3) 131-136

Classification of Wyllieite
Dana 7th ed.:
38.2.8.2
Dana 8th ed.:
38.2.4.2

38 : ANHYDROUS NORMAL PHOSPHATES, ARSENATES, AND VANADATES
2 : (AB)5(XO4)3
Hey's CIM Ref.:
19.14.4

19 : Phosphates
14 : Phosphates of Fe and other metals

Mineral Symbols
Transparency:
Translucent
Colour:
Deep bluish-green to deep oily-green, gray-green, to greenish-black
Streak:
Dirty olive green
Hardness:
4 - 4½ onMohs scale
Tenacity:
Very brittle
Cleavage:
Perfect
{010} perfect, {101} distinct
Density:
3.61 g/cm3 (Calculated)

Optical Data of Wyllieite
Surface Relief:
High
Dispersion:
r > v weak
Comments:
Thick plates show pleochroism, X smoky blue-gray, Y smoky
bluish-green, Z green. Abs Z>Y>X.

Chemistry of Wyllieite

Crystallography of Wyllieite
General Appearance of Type Material:
Masses and crude crystals to 10 cm. Likely previously misidentified as triphylite-lithiophilite.
Place of Conservation of Type Material:
National Museum of Natural History, Washington, D.C., USA, 162557.
Geological Setting of Type Material:
Zoned, complex granite pegmatites
Associated Minerals at Type Locality:
Arrojadite-(KFe)GraftoniteSarcopsideScorzalite
Reference:
Moore, Paul B., Ito, Jun (1973) Wyllieite, Na2Fe2+2Al(PO4)3: a New Species.The Mineralogical Record, 4 (3) 131-136

Synonyms of Wyllieite

Other Language Names for Wyllieite

Relationship of Wyllieite to other Species
Other Members of Wyllieite Group:
FerroqingheiiteNaNaFe2+(MgAl)(PO4)3Mon. 2/m :P21/m
Ferrorosemaryite◻NaFe2+Fe3+Al(PO4)3Mon. 2/m
Ferrowyllieite(Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO4)3Mon. 2/m :P21/b
Fupingqiuite(Na,Mn2+,◻)2Mn2+2Fe3+(PO4)3Mon.
MagnesioqingheiiteNa2Mg(MgAl)(PO4)3Mon. 2/m
QingheiiteNaNaMn2+(MgAl)(PO4)3Mon. 2/m :P21/b
Rosemaryite(Na,Ca,Mn)(Mn,Fe2+)(Fe3+,Mg)Al(PO4)3Mon. 2/m :P21/b
Forms a series with:
FerrowyllieiteFerrowyllieite-Wyllieite Series
RosemaryiteRosemaryite-Wyllieite Series

Common AssociatesMon. 2/m :P21/m8.AC.MagnesioqingheiiteNa2Mg(MgAl)(PO4)3Mon. 2/m8.AC.ManganobadaloviteNaNaMn(MgFe3+)(AsO4)3Mon. 2/m :B2/b8.AC.Changesite–(Y)(Ca8Y)◻Fe2+(PO4)7Trig. 3m :R3c8.AC.CrocobeloniteCaFe3+2O(PO4)2Orth.mmm(2/m2/m2/m) :Pnma8.AC.WopmayiteCa6Na3◻Mn(PO4)3(PO3OH)4Trig. 3m :R3c8.AC.BeershevaiteCaFe3+3(PO4)3OMon. 2/m :P21/m8.AC.Epiebnerite(NH4)Zn(PO4)Mon. 2 :P218.AC.Ebnerite(NH4)Zn(PO4)Hex. 6 :P638.AC.XDyrnaesite-(La)Na8Ce4+(La,REE)2(PO4)6Orth.mmm(2/m2/m2/m) :Pnma8.AC.EdtolliteK2NaCu5Fe3+O2(AsO4)4Tric.1 :P18.AC.AngarfiteNaFe3+5(PO4)4(OH)4 · 4H2OOrth. 222 :C22218.AC.KabaloviteFe2+3Fe3+4(PO4)6Tric.1 :P18.AC.Nazarchukite Ca2NiFe3+2(PO4)4Orth.mmm(2/m2/m2/m) :Pbca8.AC.CalciohatertiteNaNaCa(CaFe3+)(AsO4)3Mon. 2/m :B2/b8.AC.AlumoedtolliteK2NaCu5AlO2(AsO4)4Tric. 1 :P18.AC.02GrigorieviteCu3Fe3+2Al2(VO4)6Tric.1 :P18.AC.02KoksharoviteCaMg2Fe3+4(VO4)6Tric.1 :P18.AC.02ZiminaiteFe3+6 (VO4)6Tric.1 :P18.AC.05HatertiteNa2(Ca,Na)(Fe3+,Cu)2(AsO4)3Mon. 2/m :B2/b8.AC.05ErikapohliteCu3(Zn,Cu,Mg)4Ca2(AsO4)6 · 2H2OMon. 2/m :B2/m8.AC.05Unnamed (Na-Mg Arsenate Hydroxyarsenate)NaMg3(AsO4)(AsO3OH)2Mon. 2/m :B2/b8.AC.05Unnamed (Na-Zn-H Arsenate Hydroxyarsenate)Na(Na0.6Zn0.4)Zn2(H0.6AsO4)(AsO3OH)2Mon. 2/m :B2/b8.AC.05CalciojohilleriteNaCaMg3(AsO4)3Mon. 2/m :B2/b8.AC.05Magnesiohatertite(Na,Ca)2Ca(Mg,Fe3+)2(AsO4)3Mon. 2/m :B2/b8.AC.05 vaAlluaudite-Na[]◻4Na4Mn2+4Fe3+8(PO4)12Mon. 2/m :B2/b8.AC.05 vaAlluaudite-Ca[]◻4Ca4Mn2+4Fe3+8(PO4)12Mon. 2/m :B2/b8.AC.05 vaFerroalluaudite-NaNaNa4Na4Fe2+4Fe3+8(PO4)12Mon. 2/m :B2/m8.AC.05Hagendorfite-NaNaNaNaFe2+(Mn2+,Mn3+)(PO4)3 (?)Mon. 2/m :B2/b8.AC.05O'DanieliteNa(Zn,Mg)3(AsO4)(AsO3OH)2Mon. 2/m :B2/b8.AC.05HowardevansiteNaCuFe2(VO4)3Tric.1 :P18.AC.05KhrenoviteNa3Fe3+2(AsO4)3Mon. 2/m :B2/b8.AC.05ZincobradaczekiteNaZn2Cu2(AsO4)3Mon. 2/m :B2/b8.AC.05ParaberzeliiteNaCa2Mg2(AsO4)3Mon. 2/m :B2/b8.AC.05BadaloviteNa2Mg2Fe(AsO4)3Mon. 2/m :B2/b8.AC.05MagnesiocanutiteNaMnMg2[AsO4]2[AsO2(OH)2]Mon. 2/m :B2/b8.AC.05ManganohatertiteNaNaCa(MnFe3+)(AsO4)3Mon. 2/m :B2/b8.AC.05CamanchacaiteNaCaMg2[AsO4][AsO3(OH)]2Mon. 2/m :B2/b8.AC.07ZhanghuifeniteNa3Mn4Mg2Al(PO4)6Mon. 2/m8.AC.07FerrobobfergusoniteNa2Fe2+5Fe3+Al(PO4)6Mon.8.AC.10HagendorfiteNaCaMn2+Fe2+2(PO4)3Mon. 2/m :B2/b8.AC.10FerrohagendorfiteNaCaFe2+Fe2+2(PO4)3Mon.8.AC.10JohilleriteNa(Mg,Zn)3Cu(AsO4)3Mon. 2/m :B2/b8.AC.10VaruliteNaCaMn2+Mn2+2(PO4)3Mon. 2/m :B2/b8.AC.10NickenichiteNa0.8Ca0.4Cu0.4(Mg,Fe)3(AsO4)3Mon. 2/m :B2/b8.AC.10ArseniopleiteNaCaMnMn2(AsO4)3Mon. 2/m8.AC.10GroatiteNaCaMn2(PO4)[PO3(OH)]2Mon. 2/m :B2/b8.AC.10Alluaudite(Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3Mon. 2/m :B2/b8.AC.10BradaczekiteNaCu4(AsO4)3Mon. 2/m :B2/b8.AC.10Caryinite(Na,Pb)(Ca,Na)CaMn2+2(AsO4)3Mon. 2/m8.AC.10Ferroalluaudite(Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3Mon. 2/m :B2/b8.AC.10Maghagendorfite(Na,◻)MgMn2+(Fe2+,Fe3+)2(PO4)3Mon. 2/m8.AC.15Ferrowyllieite(Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO4)3Mon. 2/m :P21/b8.AC.15QingheiiteNaNaMn2+(MgAl)(PO4)3Mon. 2/m :P21/b8.AC.15Rosemaryite(Na,Ca,Mn)(Mn,Fe2+)(Fe3+,Mg)Al(PO4)3Mon. 2/m :P21/b8.AC.15FerroqingheiiteNaNaFe2+(MgAl)(PO4)3Mon. 2/m :P21/m8.AC.15Ferrorosemaryite◻NaFe2+Fe3+Al(PO4)3Mon. 2/m8.AC.15BobfergusoniteNa2Mn5FeAl(PO4)6Mon. 2/m :P2/b8.AC.17CzochralskiiteNa4Ca3Mg(PO4)4Orth.mmm(2/m2/m2/m) :Pnma8.AC.18ManitobaiteNa16Mn2+25Al8(PO4)30Mon.m :Pb8.AC.20MarićiteNaFe2+(PO4)Orth.mmm(2/m2/m2/m) :Pmna8.AC.25Schäferite(NaCa2)Mg2(VO4)3Iso.m3m(4/m32/m) :Ia3d8.AC.25Berzeliite(NaCa2)Mg2(AsO4)3Iso.m3m(4/m32/m) :Ia3d8.AC.25MatyhiteCa18(Ca,◻)2Fe2+2(PO4)14Trig. 3m :R3c8.AC.25Hedegaardite(Ca,Na)9(Ca,Na)Mg(PO4)6(PO3OH)Trig. 3m :R3c8.AC.25Manganberzeliite(NaCa2)Mn2+2(AsO4)3Iso.m3m(4/m32/m) :Ia3d8.AC.25Palenzonaite(NaCa2)Mn2+2(VO4)3Iso.m3m(4/m32/m) :Ia3d8.AC.30BrianiteNa2CaMg(PO4)2Mon. 2/m :P21/b8.AC.35Vitusite-(Ce)Na3(Ce,La,Nd)(PO4)2Orth.mm2 :Pca218.AC.40Bario-olgite(Ba,Sr)(Na,Sr,REE)2Na(PO4)2 ·Trig. 3 :P38.AC.40Olgite(Sr,Ba)(Na,Sr,REE)2Na(PO4)2Trig.3m(32/m) :P3m18.AC.45TuiteCa3(PO4)2Trig.3m(32/m) :R3m8.AC.45FerromerrilliteCa9NaFe2+(PO4)7Trig. 3m :R3c8.AC.45StrontiowhitlockiteSr9Mg(PO4)6(PO3OH)Trig. 3m :R3c8.AC.45MerrilliteCa9NaMg(PO4)7Trig. 3m :R3m8.AC.45WhitlockiteCa9Mg(PO4)6(PO3OH)Trig. 3m :R3c8.AC.47IwateiteNa2BaMn(PO4)2Trig.3 :P38.AC.47OzerovaiteNa2KAl3(AsO4)4Orth.mmm(2/m2/m2/m) :Cmca8.AC.47YurmariniteNa7(Fe3+,Mg,Cu)4(AsO4)6Trig.3m(32/m) :R3c8.AC.47PansneriteK3Na3(Fe3+,Al)6(AsO4)8Orth.mmm(2/m2/m2/m)8.AC.47AnatolyiteNa6(Ca,Na)(Mg,Fe3+)3Al(AsO4)6Trig.3m(32/m) :R3c8.AC.50FillowiteNa3CaMn2+11(PO4)9Trig.3 :R38.AC.50GalileiiteNa3Fe2+Fe2+11(PO4)9Trig.3 :R38.AC.50JohnsomervilleiteNa3CaFe11(PO4)9Trig.3 :R38.AC.50XenophylliteNa4Fe2+7(PO4)6Tric.1 :P18.AC.50UdinaiteNaMg4(VO4)3Tet.42m :I42d8.AC.50ArsenudinaiteNaMg4(AsO4)3Tet.42m :I42d8.AC.50ChladniiteNa3CaMg11(PO4)9Trig.3 :R38.AC.52Lasnierite(Ca,Sr)(Mg,Fe2+)2Al(P[O,F]4)3Orth.mmm(2/m2/m2/m) :Pbcn8.AC.55PharmazinciteKZnAsO4Hex. 6 :P638.AC.57ZubkovaiteCa3Cu3(AsO4)4Mon. 2 :B28.AC.60KosnariteKZr2(PO4)3Trig.3m(32/m) :R3c8.AC.65Panethite(Na,Ca)2(Mg,Fe2+)2(PO4)2Mon. 2/m :P21/b8.AC.70StanfielditeCa4Mg5(PO4)6Mon.8.AC.75RonneburgiteK2MnV4O12Mon. 2/m8.AC.80TillmannsiteAg3Hg[(V,As)O4]Tet. 4 :I48.AC.85FilatoviteK(Al,Zn)2(As,Si)2O8Mon. 2/m

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    • References for WyllieiteⓘDifunta Correa pegmatiteFernando Colombo et al. (2018)Tait et al. (2004)Roda-Robles et al. (2012)
    Brazil
     
    Cassedanne (1983)
    Europe
     
    Keller et al. (1997)
    France
     
    Berbain et al. (2012)Berbain et al. (2012)
    Germany
     
    Thomas et al. (2000)
    Poland
     
    Łodziński M. & Sitarz M. 2008: Chemical and Spectroscopic Characterization of Some Phosphates Accessory Minerals from Pegmatites of the Sowie Mts (Owles Mts)Pieczka et al. (2017)
    Portugal
     
    Dias P et al. (2014)
    Rwanda
     
    Fransolet (1995)
    Spain
     
    Merino et al. (2019)Encarnación Roda-Robles (2007)+1 other referenceBareche (2005)& locality references+1 other reference
    Sweden
     
    Grensman (1989)+1 other referenceEk et al. (1990)
    USA
     
    London et al. (1982)Campbell et al. (1986)[MinRec 4:111Forrest CuretonYedlin (1973)
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