| Åkermanite | Ca2Mg[Si2O7] | Tet.42m :P421m |
| Alumoåkermanite | (CaNa)Al[Si2O7] | Tet.42m :P421m |
| Bennesherite | Ba2Fe2+[Si2O7] | Tet.42m :P421m |
| Ferri-gehlenite | Ca2Fe3+[AlSiO7] | |
| Ferroåkermanite | Ca2Fe[Si2O7] | Tet.42m :P421m |
| Gugiaite | Ca2Be[Si2O7] | Tet.42m :P42m |
| Hardystonite | Ca2Zn[Si2O7] | Tet.42m :P421m |
| Hydroxylgugiaite | (Ca,◻)2(Si,Be)[(Be,Si)2O5.5(OH)1.5] | Tet.42m :P421m |
| Okayamalite | Ca2B[BSiO7] | Tet.42m :P421m |