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Ferrowyllieite

A valid IMA mineral species
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(Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO4)3
Colour:
Greenish black, also dark bluish green, dark greenish gray, dark green, dark brown.
Lustre:
Sub-Vitreous, Resinous, Greasy
Hardness:
4
Specific Gravity:
3.601
Crystal System:
Monoclinic
Member of:
Wyllieite Group >Alluaudite Supergroup
Name:
Named by Paul (Paulus) Brian Moore and Jun Ito in 1973 in honor of Peter John Wyllie [February 8, 1930 London, UK-], American mineralogist and petrologist at University of Chicago and California Institute of Technology. Wyllieite was redefined and renamed by Moore and Ito in 1979 (Min. Mag. v. 43, p. 227 (1979) as ferrowyllieite-(MnNaNa) and a new species was re-assigned the older root name wyllieite-□NaCa, but no physical description was published of the new wyllieite although the chemistry was presented and the structure was verified.
Type Locality:
ⓘVictory Mine, Custer, Custer Mining District, Custer County, South Dakota, USA
Isostructural with:
Alluaudite Group
Wyllieite Group.Ferrowyllieite-Wyllieite Series.


Unique Identifiers
IMA Formula:
NaNaFe2+(Fe2+Al)(PO4)3
Type description reference:
Moore, Paul B., Ito, Jun (1973) Wyllieite, Na2Fe2+2Al(PO4)3: a New Species.The Mineralogical Record, 4 (3) 131-136(this material was re-named ferrowyllieite)

Classification of Ferrowyllieite
Dana 7th ed.:
38.2.8.1
Dana 8th ed.:
38.2.4.1

38 : ANHYDROUS NORMAL PHOSPHATES, ARSENATES, AND VANADATES
2 : (AB)5(XO4)3
Hey's CIM Ref.:
19.14.5

19 : Phosphates
14 : Phosphates of Fe and other metals

Mineral Symbols
Transparency:
Translucent
Colour:
Greenish black, also dark bluish green, dark greenish gray, dark green, dark brown.
Streak:
Light gray
Hardness:
4 onMohs scale
Tenacity:
Very brittle
Cleavage:
Perfect
{010} perfect; {101} poor to good
Fracture:
Irregular/Uneven
Density:
3.601 g/cm3 (Measured)    3.68 g/cm3 (Calculated)
Comment:
Range 3.60-3.68 (calculated)

Optical Data of Ferrowyllieite
Surface Relief:
High
Dispersion:
r < v strong
Pleochroism:
Strong
Comments:
X=smoky gray; Y=smoky bluish green; Z=green

Chemistry of Ferrowyllieite

Crystallography of Ferrowyllieite
General Appearance of Type Material:
Crude euhedral crystals, to 10 cm, in interlocking aggregates
Place of Conservation of Type Material:
National Museum of Natural History, Washington, D.C., USA, 126318, 137244, 162555, 162556.
Geological Setting of Type Material:
Large pods in granite pegmatite.
Associated Minerals at Type Locality:
Arrojadite-(KFe)MuscovitePlagioclaseQuartzSchorl
Reference:
Moore, Paul B., Ito, Jun (1973) Wyllieite, Na2Fe2+2Al(PO4)3: a New Species.The Mineralogical Record, 4 (3) 131-136(this material was re-named ferrowyllieite)

Other Language Names for Ferrowyllieite

Relationship of Ferrowyllieite to other Species
Other Members of Wyllieite Group:
FerroqingheiiteNaNaFe2+(MgAl)(PO4)3Mon. 2/m :P21/m
Ferrorosemaryite◻NaFe2+Fe3+Al(PO4)3Mon. 2/m
Fupingqiuite(Na,Mn2+,◻)2Mn2+2Fe3+(PO4)3Mon.
MagnesioqingheiiteNa2Mg(MgAl)(PO4)3Mon. 2/m
QingheiiteNaNaMn2+(MgAl)(PO4)3Mon. 2/m :P21/b
Rosemaryite(Na,Ca,Mn)(Mn,Fe2+)(Fe3+,Mg)Al(PO4)3Mon. 2/m :P21/b
Wyllieite(Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO4)3Mon. 2/m
Forms a series with:
WyllieiteFerrowyllieite-Wyllieite Series
RosemaryiteFerrowyllieite-Rosemaryite Series

Common AssociatesMon. 2/m :P21/m8.AC.MagnesioqingheiiteNa2Mg(MgAl)(PO4)3Mon. 2/m8.AC.ManganobadaloviteNaNaMn(MgFe3+)(AsO4)3Mon. 2/m :B2/b8.AC.Changesite–(Y)(Ca8Y)◻Fe2+(PO4)7Trig. 3m :R3c8.AC.CrocobeloniteCaFe3+2O(PO4)2Orth.mmm(2/m2/m2/m) :Pnma8.AC.WopmayiteCa6Na3◻Mn(PO4)3(PO3OH)4Trig. 3m :R3c8.AC.BeershevaiteCaFe3+3(PO4)3OMon. 2/m :P21/m8.AC.Epiebnerite(NH4)Zn(PO4)Mon. 2 :P218.AC.Ebnerite(NH4)Zn(PO4)Hex. 6 :P638.AC.XDyrnaesite-(La)Na8Ce4+(La,REE)2(PO4)6Orth.mmm(2/m2/m2/m) :Pnma8.AC.EdtolliteK2NaCu5Fe3+O2(AsO4)4Tric.1 :P18.AC.AngarfiteNaFe3+5(PO4)4(OH)4 · 4H2OOrth. 222 :C22218.AC.KabaloviteFe2+3Fe3+4(PO4)6Tric.1 :P18.AC.Nazarchukite Ca2NiFe3+2(PO4)4Orth.mmm(2/m2/m2/m) :Pbca8.AC.CalciohatertiteNaNaCa(CaFe3+)(AsO4)3Mon. 2/m :B2/b8.AC.AlumoedtolliteK2NaCu5AlO2(AsO4)4Tric. 1 :P18.AC.02GrigorieviteCu3Fe3+2Al2(VO4)6Tric.1 :P18.AC.02KoksharoviteCaMg2Fe3+4(VO4)6Tric.1 :P18.AC.02ZiminaiteFe3+6 (VO4)6Tric.1 :P18.AC.05HatertiteNa2(Ca,Na)(Fe3+,Cu)2(AsO4)3Mon. 2/m :B2/b8.AC.05ErikapohliteCu3(Zn,Cu,Mg)4Ca2(AsO4)6 · 2H2OMon. 2/m :B2/m8.AC.05Unnamed (Na-Mg Arsenate Hydroxyarsenate)NaMg3(AsO4)(AsO3OH)2Mon. 2/m :B2/b8.AC.05Unnamed (Na-Zn-H Arsenate Hydroxyarsenate)Na(Na0.6Zn0.4)Zn2(H0.6AsO4)(AsO3OH)2Mon. 2/m :B2/b8.AC.05CalciojohilleriteNaCaMg3(AsO4)3Mon. 2/m :B2/b8.AC.05Magnesiohatertite(Na,Ca)2Ca(Mg,Fe3+)2(AsO4)3Mon. 2/m :B2/b8.AC.05 vaAlluaudite-Na[]◻4Na4Mn2+4Fe3+8(PO4)12Mon. 2/m :B2/b8.AC.05 vaAlluaudite-Ca[]◻4Ca4Mn2+4Fe3+8(PO4)12Mon. 2/m :B2/b8.AC.05 vaFerroalluaudite-NaNaNa4Na4Fe2+4Fe3+8(PO4)12Mon. 2/m :B2/m8.AC.05Hagendorfite-NaNaNaNaFe2+(Mn2+,Mn3+)(PO4)3 (?)Mon. 2/m :B2/b8.AC.05O'DanieliteNa(Zn,Mg)3(AsO4)(AsO3OH)2Mon. 2/m :B2/b8.AC.05HowardevansiteNaCuFe2(VO4)3Tric.1 :P18.AC.05KhrenoviteNa3Fe3+2(AsO4)3Mon. 2/m :B2/b8.AC.05ZincobradaczekiteNaZn2Cu2(AsO4)3Mon. 2/m :B2/b8.AC.05ParaberzeliiteNaCa2Mg2(AsO4)3Mon. 2/m :B2/b8.AC.05BadaloviteNa2Mg2Fe(AsO4)3Mon. 2/m :B2/b8.AC.05MagnesiocanutiteNaMnMg2[AsO4]2[AsO2(OH)2]Mon. 2/m :B2/b8.AC.05ManganohatertiteNaNaCa(MnFe3+)(AsO4)3Mon. 2/m :B2/b8.AC.05CamanchacaiteNaCaMg2[AsO4][AsO3(OH)]2Mon. 2/m :B2/b8.AC.07ZhanghuifeniteNa3Mn4Mg2Al(PO4)6Mon. 2/m8.AC.07FerrobobfergusoniteNa2Fe2+5Fe3+Al(PO4)6Mon.8.AC.10HagendorfiteNaCaMn2+Fe2+2(PO4)3Mon. 2/m :B2/b8.AC.10FerrohagendorfiteNaCaFe2+Fe2+2(PO4)3Mon.8.AC.10JohilleriteNa(Mg,Zn)3Cu(AsO4)3Mon. 2/m :B2/b8.AC.10VaruliteNaCaMn2+Mn2+2(PO4)3Mon. 2/m :B2/b8.AC.10NickenichiteNa0.8Ca0.4Cu0.4(Mg,Fe)3(AsO4)3Mon. 2/m :B2/b8.AC.10ArseniopleiteNaCaMnMn2(AsO4)3Mon. 2/m8.AC.10GroatiteNaCaMn2(PO4)[PO3(OH)]2Mon. 2/m :B2/b8.AC.10Alluaudite(Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3Mon. 2/m :B2/b8.AC.10BradaczekiteNaCu4(AsO4)3Mon. 2/m :B2/b8.AC.10Caryinite(Na,Pb)(Ca,Na)CaMn2+2(AsO4)3Mon. 2/m8.AC.10Ferroalluaudite(Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3Mon. 2/m :B2/b8.AC.10Maghagendorfite(Na,◻)MgMn2+(Fe2+,Fe3+)2(PO4)3Mon. 2/m8.AC.15QingheiiteNaNaMn2+(MgAl)(PO4)3Mon. 2/m :P21/b8.AC.15Rosemaryite(Na,Ca,Mn)(Mn,Fe2+)(Fe3+,Mg)Al(PO4)3Mon. 2/m :P21/b8.AC.15FerroqingheiiteNaNaFe2+(MgAl)(PO4)3Mon. 2/m :P21/m8.AC.15Ferrorosemaryite◻NaFe2+Fe3+Al(PO4)3Mon. 2/m8.AC.15BobfergusoniteNa2Mn5FeAl(PO4)6Mon. 2/m :P2/b8.AC.15Wyllieite(Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO4)3Mon. 2/m8.AC.17CzochralskiiteNa4Ca3Mg(PO4)4Orth.mmm(2/m2/m2/m) :Pnma8.AC.18ManitobaiteNa16Mn2+25Al8(PO4)30Mon.m :Pb8.AC.20MarićiteNaFe2+(PO4)Orth.mmm(2/m2/m2/m) :Pmna8.AC.25Schäferite(NaCa2)Mg2(VO4)3Iso.m3m(4/m32/m) :Ia3d8.AC.25Berzeliite(NaCa2)Mg2(AsO4)3Iso.m3m(4/m32/m) :Ia3d8.AC.25MatyhiteCa18(Ca,◻)2Fe2+2(PO4)14Trig. 3m :R3c8.AC.25Hedegaardite(Ca,Na)9(Ca,Na)Mg(PO4)6(PO3OH)Trig. 3m :R3c8.AC.25Manganberzeliite(NaCa2)Mn2+2(AsO4)3Iso.m3m(4/m32/m) :Ia3d8.AC.25Palenzonaite(NaCa2)Mn2+2(VO4)3Iso.m3m(4/m32/m) :Ia3d8.AC.30BrianiteNa2CaMg(PO4)2Mon. 2/m :P21/b8.AC.35Vitusite-(Ce)Na3(Ce,La,Nd)(PO4)2Orth.mm2 :Pca218.AC.40Bario-olgite(Ba,Sr)(Na,Sr,REE)2Na(PO4)2 ·Trig. 3 :P38.AC.40Olgite(Sr,Ba)(Na,Sr,REE)2Na(PO4)2Trig.3m(32/m) :P3m18.AC.45TuiteCa3(PO4)2Trig.3m(32/m) :R3m8.AC.45FerromerrilliteCa9NaFe2+(PO4)7Trig. 3m :R3c8.AC.45StrontiowhitlockiteSr9Mg(PO4)6(PO3OH)Trig. 3m :R3c8.AC.45MerrilliteCa9NaMg(PO4)7Trig. 3m :R3m8.AC.45WhitlockiteCa9Mg(PO4)6(PO3OH)Trig. 3m :R3c8.AC.47IwateiteNa2BaMn(PO4)2Trig.3 :P38.AC.47OzerovaiteNa2KAl3(AsO4)4Orth.mmm(2/m2/m2/m) :Cmca8.AC.47YurmariniteNa7(Fe3+,Mg,Cu)4(AsO4)6Trig.3m(32/m) :R3c8.AC.47PansneriteK3Na3(Fe3+,Al)6(AsO4)8Orth.mmm(2/m2/m2/m)8.AC.47AnatolyiteNa6(Ca,Na)(Mg,Fe3+)3Al(AsO4)6Trig.3m(32/m) :R3c8.AC.50FillowiteNa3CaMn2+11(PO4)9Trig.3 :R38.AC.50GalileiiteNa3Fe2+Fe2+11(PO4)9Trig.3 :R38.AC.50JohnsomervilleiteNa3CaFe11(PO4)9Trig.3 :R38.AC.50XenophylliteNa4Fe2+7(PO4)6Tric.1 :P18.AC.50UdinaiteNaMg4(VO4)3Tet.42m :I42d8.AC.50ArsenudinaiteNaMg4(AsO4)3Tet.42m :I42d8.AC.50ChladniiteNa3CaMg11(PO4)9Trig.3 :R38.AC.52Lasnierite(Ca,Sr)(Mg,Fe2+)2Al(P[O,F]4)3Orth.mmm(2/m2/m2/m) :Pbcn8.AC.55PharmazinciteKZnAsO4Hex. 6 :P638.AC.57ZubkovaiteCa3Cu3(AsO4)4Mon. 2 :B28.AC.60KosnariteKZr2(PO4)3Trig.3m(32/m) :R3c8.AC.65Panethite(Na,Ca)2(Mg,Fe2+)2(PO4)2Mon. 2/m :P21/b8.AC.70StanfielditeCa4Mg5(PO4)6Mon.8.AC.75RonneburgiteK2MnV4O12Mon. 2/m8.AC.80TillmannsiteAg3Hg[(V,As)O4]Tet. 4 :I48.AC.85FilatoviteK(Al,Zn)2(As,Si)2O8Mon. 2/m

Fluorescence of Ferrowyllieite

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    • References for FerrowyllieiteⓘS11D-0047 cave ?SALLUN FILHO (orgs.)+2 other references
    Italy
     
    Vignola et al. (2011)+1 other reference
    Namibia
     
    Förch (1998)
    Poland
     
    Łodziński M. & Sitarz M. 2008: Chemical and Spectroscopic Characterization of Some Phosphates Accessory Minerals from Pegmatites of the Sowie Mts (Owles Mts)Pieczka et al. (2017)
    Sweden
     
    Museum Victoria collection M 43287+1 other reference
    USA
     
    Moore et al. (1979)Rocks & Min.: 57:55.
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