Movatterモバイル変換


[0]ホーム

URL:


Jump to content
WikipediaThe Free Encyclopedia
Search

Zinc molybdate

From Wikipedia, the free encyclopedia
Zinc molybdate[1]
Identifiers
ECHA InfoCard100.033.965Edit this at Wikidata
EC Number
  • 237-377-8
UNII
Properties
ZnMoO4
Molar mass225.33 g/mol
Appearancewhitetetragonal crystals
Density4.32 g/cm3[2]
Melting point900 °C (1,650 °F; 1,170 K)
insoluble
Structure
tetragonal
Hazards
GHS labelling:[3]
GHS07: Exclamation mark
Warning
H315,H319,H335
NFPA 704 (fire diamond)
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Chemical compound

Zinc molybdate is aninorganic compound with the formulaZnMoO4. It is used as a whitepigment, which is also acorrosion inhibitor. A related pigment is sodium zinc molybdate, Na2Zn(MoO4)2.[4] The material has also been investigated as an electrode material.[5]

In terms of its structure, the Mo(VI) centers are tetrahedral and the Zn(II) centers are octahedral.[2]

Safety

[edit]

The LD50 (oral, rats) is 11,500 mg/kg.[4] While highlysolublemolybdates like e.g.sodium molybdate are toxic in higher doses, zinc molybdate is essentially non-toxic because of its insolubility in water. Molybdates possess a lower toxicity than chromates or lead salts and are therefore seen as an alternative to these salts for corrosion inhibition.

References

[edit]
  1. ^Lide, David R. (1998),Handbook of Chemistry and Physics (87 ed.), Boca Raton, FL: CRC Press, pp. 4–95,ISBN 978-0-8493-0594-8
  2. ^abAit Ahsaine, H.; Zbair, M.; Ezahri, M.; Benlhachemi, A.; Arab, M.; Bakiz, B.; Guinneton, F.; Gavarri, J. R. (2015)."Rietveld Refinements, Impedance Spectroscopy and Phase Transition of the Polycrystalline ZnMoO4 Ceramics"(PDF).Ceramics International.41 (10):15193–15201.doi:10.1016/j.ceramint.2015.08.094.S2CID 93070036.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  3. ^"C&L Inventory".echa.europa.eu.
  4. ^abG. Etzrodt (2012). "Pigments, Inorganic 5. Anticorrosive Pigments".Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH.doi:10.1002/14356007.n20_n04.ISBN 978-3-527-30673-2.
  5. ^Hu, Xianluo; Zhang, Wei; Liu, Xiaoxiao; Mei, Yueni; Huang, Yunhui (2015). "Nanostructured Mo-based electrode materials for electrochemical Energy Storage".Chemical Society Reviews.44 (8):2376–404.doi:10.1039/C4CS00350K.PMID 25688809.S2CID 205906132.

External links

[edit]
Zinc(I)
Organozinc(I) compounds
Zinc(II)
Organozinc(II) compounds
Molybdates
Chloromolybdates
Dimolybdates
Related


Stub icon

Thisinorganiccompound–related article is astub. You can help Wikipedia byexpanding it.

Retrieved from "https://en.wikipedia.org/w/index.php?title=Zinc_molybdate&oldid=1226512795"
Categories:
Hidden categories:

[8]ページ先頭

©2009-2025 Movatter.jp