TheZND detonation model is a one-dimensional model for the process ofdetonation of anexplosive. It was proposed duringWorld War II independently byYakov Zeldovich,[1]John von Neumann,[2] andWerner Döring,[3] hence the name.
This model admits finite-rate chemical reactions and thus the process of detonation consists of the following stages. First, aninfinitesimally thin shock wave compresses the explosive to a high pressure called thevon Neumann spike. At the von Neumann spike point the explosive still remains unreacted. The spike marks the onset of the zone of exothermic chemical reaction, which finishes at theChapman–Jouguet condition. After that, the detonation products expand backward.
In the reference frame in which the shock is stationary, the flow following the shock issubsonic. Because of this, energy release behind the shock is able to be transported acoustically to the shock for its support. For a self-propagating detonation, the shock relaxes to a speed given by the Chapman–Jouguet condition, which induces the material at the end of the reaction zone to have a locally sonic speed in the reference frame in which the shock is stationary. In effect, all of the chemical energy is harnessed to propagate the shock wave forward.
However, in the 1960s, experiments revealed that gas-phase detonations were most often characterized by unsteady, three-dimensional structures, which can only in an averaged sense be predicted by one-dimensional steady theories. Indeed, such waves are quenched as their structure is destroyed.[4][5] The Wood–Kirkwood detonation theory can correct for some of these limitations.[6]
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