.jpg)
Water chlorination is the process of addingchlorine or chlorine compounds such assodium hypochlorite towater. This method is used to kill bacteria, viruses and other microbes in water. In particular, chlorination is used to prevent the spread ofwaterborne diseases such ascholera,dysentery, andtyphoid.[1][2][3]
In a paper published in 1894, it was formally proposed to add chlorine to water to render it "germ-free". Two other authorities endorsed this proposal and published it in many other papers in 1895.[4] Early attempts at implementing water chlorination at a water treatment plant were made in 1893 inHamburg, Germany. In 1897 the town ofMaidstone, England was the first to have its entire water supply treated with chlorine.[5]
Permanent water chlorination began in 1905, when a faultyslow sand filter and a contaminated water supply caused a serious typhoid fever epidemic inLincoln, England.[6] Alexander Cruickshank Houston used chlorination of the water to stop the epidemic. His installation fed a concentrated solution of so-called "chlorinated lime" (a mixture ofcalcium hypochlorite,calcium hydroxide andcalcium chloride) to the water being treated. This was not simply modern calcium chloride, but contained chlorine gas dissolved in lime-water (dilute calcium hydroxide) to form calcium hypochlorite (chlorinated lime). The chlorination of the water supply helped stop the epidemic and as a precaution, the chlorination was continued until 1911 when a new water supply was commissioned.[7]
The first continuous use of chlorine in theUnited States fordisinfection took place in 1908 at Boonton Reservoir (on theRockaway River), which served as the supply forJersey City, New Jersey.[8] Chlorination was achieved by controlled additions of dilute solutions of chloride of lime (calcium hypochlorite) at doses of 0.2 to 0.35 ppm. The treatment process was conceived byJohn L. Leal, and the chlorination plant was designed byGeorge Warren Fuller.[9] Over the next few years, chlorine disinfection using chloride of lime (calcium hypochlorite) was rapidly implemented in drinking water systems around the world.[10]
The technique of purification of drinking water by use of compressed liquefied chlorine gas was developed by a British officer in theIndian Medical Service, Vincent B. Nesfield, in 1903. According to his own account, "It occurred to me that chlorine gas might be found satisfactory ... if suitable means could be found for using it.... The next important question was how to render the gas portable. This might be accomplished in two ways: by liquefying it, and storing it in lead-lined iron vessels, having a jet with a very fine capillary canal, and fitted with a tap or a screw cap. The tap is turned on, and the cylinder placed in the amount of water required. The chlorine bubbles out, and in ten to fifteen minutes the water is absolutely safe. This method would be of use on a large scale, as for service water carts."[11]
MajorCarl Rogers Darnall, Professor of Chemistry at theArmy Medical School, gave the first practical demonstration of this in 1910.[12] This work became the basis for present day systems of municipal waterpurification. Shortly after Darnall's demonstration, MajorWilliam J. L. Lyster of theArmy Medical Department used a solution ofcalcium hypochlorite in a linen bag to treat water.[citation needed]
For many decades, Lyster's method remained the standard for U.S. ground forces in the field and in camps, implemented in the form of the familiar Lyster Bag (also spelled Lister Bag). The canvas "bag, water, sterilizing" was a common component of field kitchens, issued one per 100 persons, of a standard 36-gallon capacity that hung from an often-improvised tripod in the field. In use from World War I through the Vietnam War, it has been replaced byreverse osmosis systems that producepotable water by pressure straining local water through microscopic-level filters: the Reverse Osmosis Water Purification Unit (1980) and the Tactical Water Purification System (2007) for large-scale production, and the Light Water Purifier unit for smaller-scale needs that includes ultrafiltration technology to produce potable water from any source and uses automated backwash cycles every 15 minutes to simplify cleaning operations.[citation needed]
Chlorine gas was first used on a continuing basis to disinfect the water supply at the Belmont filter plant,Philadelphia,Pennsylvania by using a machine invented by Charles Frederick Wallace[citation needed] who dubbed it the Chlorinator. It was manufactured by the Wallace & Tiernan company beginning in 1913.[13] By 1941, disinfection of U.S. drinking water by chlorine gas had largely replaced the use of chloride of lime.[14][15]
As ahalogen,chlorine is a highly efficient disinfectant, and is added to public water supplies to kill disease-causing pathogens, such asbacteria,viruses, andprotozoans, that commonly grow in water supply reservoirs, on the walls of water mains and in storage tanks.[16] The microscopic agents of many diseases such ascholera,typhoid fever, anddysentery killed countless people annually before disinfection methods were employed routinely.[16]
By far most chlorine ismanufactured from table salt (NaCl) by electrolysis in thechlor-alkali process. The resulting gas at atmospheric pressures is liquified at high pressure. The liquefied gas is transported and used as such.[citation needed]
As a strongoxidizing agent, chlorine kills via the oxidation of organic molecules.[16] Chlorine and the hydrolysis producthypochlorous acid are not charged and therefore easily penetrate the negatively charged surface of pathogens. It is able to disintegrate the lipids that compose the cell wall and react with intracellularenzymes andproteins, making them nonfunctional.Microorganisms then either die or are no longer able to multiply.[17]
When dissolved in water, chlorine converts to an equilibrium mixture of chlorine,hypochlorous acid (HOCl), andhydrochloric acid (HCl):
In acidic solution, the major species areCl
2 and HOCl, whereas in alkaline solution, effectively only ClO− (hypochlorite ion) is present. Very small concentrations ofClO2−,ClO3−,ClO4− are also found.[18]
Shock chlorination is a process used in many swimming pools,water wells,springs, and other water sources to reduce thebacterial andalgal residue in the water. Shock chlorination is performed by mixing a large amount ofhypochlorite into the water. The hypochlorite can be in the form of a powder or a liquid such as chlorine bleach (solution ofsodium hypochlorite or calcium hypochlorite in water). Water that is being shock chlorinated should not be swum in or drunk until the sodium hypochlorite count in the water goes down to threeparts per million (ppm) or until the calcium hypochlorite count goes down to 0.2 to 0.35 ppm.[citation needed]
As an alternative to shock chlorination, some swimming pools are chlorinated by use of a chlorine-generating filter thatelectrolyzes commonsalt. Pools chlorinated by this method generally have lower levels of chlorine than directly chlorinated pools. Such pools are called saltwater pools.[citation needed]
Disinfection by chlorination can be problematic in some circumstances. Chlorine can react with naturally occurringorganic compounds found in the water supply to produce compounds known asdisinfection by-products (DBPs). The most common DBPs aretrihalomethanes (THMs) andhaloacetic acids (HAAs). Trihalomethanes are the primary disinfection by-products created from chlorination. In high doses, bromoform mainly slows down regular brain activity, which is manifested by symptoms such as sleepiness or sedation. Chronic exposure to both bromoform and dibromochloromethane can cause liver and kidney cancer, as well as heart disease, unconsciousness, or death in high doses.[19] Due to the potentialcarcinogenicity of these compounds, drinking water regulations across thedeveloped world require regular monitoring of the concentration of these compounds in the distribution systems of municipal water systems. TheWorld Health Organization has stated that "the risks to health from these by-products are extremely small in comparison with the risks associated with inadequate disinfection".[2]
There are also other concerns regarding chlorine, including its volatile nature which causes it to disappear too quickly from the water system, andorganoleptic concerns such as taste and odor.[citation needed]
Adechlorinator is a chemical additive that removeschlorine orchloramine from water. Where tap water is chlorinated, it should be dechlorinated before use in anaquarium, since chlorine can harm aquatic life in the same way it killsmicro-organisms. Chlorine will kill fish[20] and cause damage to an aquarium'sbiological filter.[21] Chemicals that serve this function arereducing agents which reduce chlorine species tochloride, which is harmless to life.
Some compounds employed in commercial dechlorinators aresodium thiosulfate, sodium hydroxymethanesulfonate, and sodium hydroxymethane sulfinic acid.[22]
