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Vacuum

From Wikipedia, the free encyclopedia
Space that is empty of matter
This article is about empty physical space or the absence of matter. For the appliance, seevacuum cleaner. For other uses, seeVacuum (disambiguation)."Free space" redirects here. For other uses, seeFree space (disambiguation).
Vacuum pump andbell jar for vacuum experiments, used in science education during the early 20th century, on display in the Schulhistorische Sammlung ('School Historical Museum'),Bremerhaven, Germany

Avacuum (pl.:vacuums orvacua) isspace devoid ofmatter. The word is derived from the Latin adjectivevacuus (neutervacuum) meaning "vacant" or "void". An approximation to such vacuum is a region with a gaseouspressure much less thanatmospheric pressure.[1] Physicists often discuss ideal test results that would occur in aperfect vacuum, which they sometimes simply call "vacuum" orfree space, and use the termpartial vacuum to refer to an actual imperfect vacuum as one might have in alaboratory or inspace. Inengineering and applied physics on the other hand, vacuum refers to any space in which the pressure is considerably lower than atmospheric pressure.[2] The Latin termin vacuo is used to describe an object that is surrounded by a vacuum.

Thequality of a partial vacuum refers to how closely it approaches a perfect vacuum. Other things equal, lower gaspressure means higher-quality vacuum. For example, a typicalvacuum cleaner produces enoughsuction to reduce air pressure by around 20%.[3] But higher-quality vacuums are possible.Ultra-high vacuum chambers, common in chemistry, physics, and engineering, operate below one trillionth (10−12) of atmospheric pressure (100 nPa), and can reach around 100 particles/cm3.[4]Outer space is an even higher-quality vacuum, with the equivalent of just a few hydrogen atoms per cubic meter on average in intergalactic space.[5]

Vacuum has been a frequent topic of philosophical debate since ancientGreek times, but was not studied empirically until the 17th century.Clemens Timpler (1605) philosophized about the experimental possibility of producing a vacuum in small tubes.[6]Evangelista Torricelli produced the first laboratory vacuum in 1643, and other experimental techniques were developed as a result of his theories of atmospheric pressure. A Torricellian vacuum is created by filling with mercury a tall glass container closed at one end, and then inverting it in a bowl to contain the mercury (see below).[7]

Vacuum became a valuable industrial tool in the 20th century with the introduction ofincandescent light bulbs andvacuum tubes, and a wide array of vacuum technologies has since become available. The development ofhuman spaceflight has raised interest in the impact of vacuum on human health, and on life forms in general.

Etymology

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The wordvacuum comes from Latin 'an empty space, void', noun use of neuter ofvacuus, meaning "empty", related tovacare, meaning "to be empty".

Vacuum is one of the few words in the English language that contains two consecutive instances of the vowelu.[8]

Historical understanding

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Historically, there has been much dispute over whether such a thing as a vacuum can exist. AncientGreek philosophers debated the existence of a vacuum, or void, in the context ofatomism, which positedvoid and atom as the fundamental explanatory elements of physics.Lucretius argued for the existence of vacuum in the first century BC andHero of Alexandria tried unsuccessfully to create an artificial vacuum in the first century AD.[9]

FollowingPlato, however, even the abstract concept of a featureless void faced considerable skepticism: it could not be apprehended by the senses, it could not, itself, provide additional explanatory power beyond the physical volume with which it was commensurate and, by definition, it was quite literally nothing at all, which cannot rightly be said to exist.Aristotle believed that no void could occur naturally, because the denser surrounding material continuum would immediately fill any incipient rarity that might give rise to a void. In hisPhysics, book IV, Aristotle offered numerous arguments against the void: for example, that motion through a medium which offered no impediment could continuead infinitum, there being no reason that something would come to rest anywhere in particular.

In the medievalMuslim world, the physicist andIslamic scholarAl-Farabi wrote a treatise rejecting the existence of the vacuum in the 10th century.[10] He concluded that air's volume can expand to fill available space, and therefore the concept of a perfect vacuum was incoherent.[11] According toAhmad Dallal,Abū Rayhān al-Bīrūnī states that "there is no observable evidence that rules out the possibility of vacuum".[12] Thesuctionpump was described by Arab engineerAl-Jazari in the 13th century, and later appeared in Europe from the 15th century.[13][14]

Europeanscholars such asRoger Bacon,Blasius of Parma andWalter Burley in the 13th and 14th century focused considerable attention on issues concerning theconcept of a vacuum. The commonly held view that nature abhorred a vacuum was calledhorror vacui. There was even speculation that even God could not create a vacuum if he wanted and the 1277Paris condemnations ofBishopÉtienne Tempier, which required there to be no restrictions on the powers of God, led to the conclusion that God could create a vacuum if he so wished.[15] From the 14th century onward increasingly departed from the Aristotelian perspective, scholars widely acknowledged that asupernatural void exists beyond the confines of the cosmos itself by the 17th century. This idea, influenced byStoic physics, helped to segregate natural and theological concerns.[16]

Almost two thousand years after Plato,René Descartes also proposed ageometrically based alternative theory of atomism, without the problematic nothing–everythingdichotomy of void and atom. Although Descartes agreed with the contemporary position, that a vacuum does not occur in nature, the success of hisnamesake coordinate system and more implicitly, the spatial–corporeal component of his metaphysics would come to define the philosophically modern notion of empty space as a quantified extension of volume. By the ancient definition however, directional information and magnitude were conceptually distinct.[citation needed]

Torricelli'smercurybarometer produced one of the first sustained vacuums in a laboratory.

Medievalthought experiments into the idea of a vacuum considered whether a vacuum was present, if only for an instant, between two flat plates when they were rapidly separated.[17] There was much discussion of whether the air moved in quickly enough as the plates were separated, or, asWalter Burley postulated, whether a 'celestial agent' prevented the vacuum arising.Jean Buridan reported in the 14th century that teams of ten horses could not pull openbellows when the port was sealed.[9]

TheCrookes tube, used to discover and studycathode rays, was an evolution of theGeissler tube.

The 17th century saw the first attempts to quantify measurements of partial vacuum.[18]Evangelista Torricelli'smercurybarometer of 1643 andBlaise Pascal's experiments both demonstrated a partial vacuum.

In 1654,Otto von Guericke invented the firstvacuum pump[19] and conducted his famousMagdeburg hemispheres experiment, showing that, owing to atmospheric pressure outside the hemispheres, teams of horses could not separate two hemispheres from which the air had been partially evacuated.Robert Boyle improved Guericke's design and with the help ofRobert Hooke further developed vacuum pump technology. Thereafter, research into the partial vacuum lapsed until 1850 whenAugust Toepler invented theToepler pump and in 1855 whenHeinrich Geissler invented the mercury displacement pump, achieving a partial vacuum of about 10 Pa (0.1 Torr). A number of electrical properties become observable at this vacuum level, which renewed interest in further research.

While outer space provides the most rarefied example of a naturally occurring partial vacuum, the heavens were originally thought to be seamlessly filled by a rigid indestructible material calledaether. Borrowing somewhat from thepneuma ofStoic physics, aether came to be regarded as the rarefied air from which it took its name, (seeAether (mythology)). Early theories of light posited a ubiquitous terrestrial and celestial medium through which light propagated. Additionally, the concept informedIsaac Newton's explanations of bothrefraction and of radiant heat.[20] 19th century experiments into thisluminiferous aether attempted to detect a minute drag on the Earth's orbit. While the Earth does, in fact, move through a relatively dense medium in comparison to that of interstellar space, the drag is so minuscule that it could not be detected. In 1912,astronomerHenry Pickering commented: "While the interstellar absorbing medium may be simply the ether, [it] is characteristic of a gas, and free gaseous molecules are certainly there".[21] Thereafter, however, luminiferous aether was discarded.

Later, in 1930,Paul Dirac proposed a model of the vacuum as an infinite sea of particles possessing negative energy, called theDirac sea. This theory helped refine the predictions of his earlier formulatedDirac equation, and successfully predicted the existence of thepositron, confirmed two years later.Werner Heisenberg'suncertainty principle, formulated in 1927, predicted a fundamental limit within which instantaneous position andmomentum, or energy and time can be measured. This far reaching consequences also threatened whether the "emptiness" of space between particles exists.

Classical field theories

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The strictest criterion to define a vacuum is a region of space and time where all the components of thestress–energy tensor are zero. This means that this region is devoid of energy and momentum, and by consequence, it must be empty of particles and other physical fields (such as electromagnetism) that contain energy and momentum.

Gravity

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Ingeneral relativity, a vanishing stress–energy tensor implies, throughEinstein field equations, the vanishing of all the components of theRicci tensor. Vacuum does not mean that the curvature ofspace-time is necessarily flat: the gravitational field can still produce curvature in a vacuum in the form of tidal forces andgravitational waves (technically, these phenomena are the components of theWeyl tensor). Theblack hole (with zero electric charge) is an elegant example of a region completely "filled" with vacuum, but still showing a strong curvature.

Electromagnetism

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Inclassical electromagnetism, thevacuum of free space, or sometimes justfree space orperfect vacuum, is a standard reference medium for electromagnetic effects.[22][23] Some authors refer to this reference medium asclassical vacuum,[22] a terminology intended to separate this concept fromQED vacuum orQCD vacuum, wherevacuum fluctuations can produce transientvirtual particle densities and arelative permittivity andrelative permeability that are not identically unity.[24][25][26]

In the theory of classical electromagnetism, free space has the following properties:

The vacuum of classical electromagnetism can be viewed as an idealized electromagnetic medium with theconstitutive relations in SI units:[32]

D(r, t)=ε0E(r, t){\displaystyle {\boldsymbol {D}}({\boldsymbol {r}},\ t)=\varepsilon _{0}{\boldsymbol {E}}({\boldsymbol {r}},\ t)\,}
H(r, t)=1μ0B(r, t){\displaystyle {\boldsymbol {H}}({\boldsymbol {r}},\ t)={\frac {1}{\mu _{0}}}{\boldsymbol {B}}({\boldsymbol {r}},\ t)\,}

relating theelectric displacement fieldD to theelectric fieldE and themagnetic field orH-fieldH to themagnetic induction orB-fieldB. Herer is a spatial location andt is time.

Quantum mechanics

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Main article:Quantum vacuum state
A video of an experiment showingvacuum fluctuations (in the red ring) amplified byspontaneous parametric down-conversion.

Inquantum mechanics andquantum field theory, the vacuum is defined as the state (that is, the solution to the equations of the theory) with the lowest possible energy (theground state of theHilbert space). Inquantum electrodynamics this vacuum is referred to as 'QED vacuum' to distinguish it from the vacuum ofquantum chromodynamics, denoted asQCD vacuum. QED vacuum is a state with no matter particles (hence the name), and nophotons. As described above, this state is impossible to achieve experimentally. (Even if every matter particle could somehow be removed from a volume, it would be impossible to eliminate all theblackbody photons.) Nonetheless, it provides a good model for realizable vacuum, and agrees with a number of experimental observations as described next.

QED vacuum has interesting and complex properties. In QED vacuum, the electric and magnetic fields have zero average values, but their variances are not zero.[33] As a result, QED vacuum containsvacuum fluctuations (virtual particles that hop into and out of existence), and a finite energy calledvacuum energy. Vacuum fluctuations are an essential and ubiquitous part of quantum field theory. Some experimentally verified effects of vacuum fluctuations includespontaneous emission and theLamb shift.[15]Coulomb's law and theelectric potential in vacuum near an electric charge are modified.[34]

Theoretically, in QCD multiple vacuum states can coexist.[35] The starting and ending ofcosmological inflation is thought to have arisen from transitions between different vacuum states. For theories obtained by quantization of a classical theory, eachstationary point of the energy in theconfiguration space gives rise to a single vacuum.String theory is believed to have a huge number of vacua – the so-calledstring theory landscape.

Outer space

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Main article:Outer space
Structure of themagnetosphere - is not a perfect vacuum, but a tenuousplasma awash with charged particles, free elements such ashydrogen,helium andoxygen,electromagnetic fields.

Outer space has very low density and pressure, and is the closest physical approximation of a perfect vacuum. But no vacuum is truly perfect, not even in interstellar space, where there are still a few hydrogen atoms per cubic meter.[5]

Stars, planets, and moons keep theiratmospheres by gravitational attraction, and as such, atmospheres have no clearly delineated boundary: the density of atmospheric gas simply decreases with distance from the object. The Earth's atmospheric pressure drops to about 32 millipascals (4.6×10−6 psi) at 100 kilometres (62 mi) of altitude,[36] theKármán line, which is a common definition of the boundary with outer space. Beyond this line, isotropic gas pressure rapidly becomes insignificant when compared toradiation pressure from theSun and thedynamic pressure of thesolar winds, so the definition of pressure becomes difficult to interpret. Thethermosphere in this range has large gradients of pressure, temperature and composition, and varies greatly due tospace weather. Astrophysicists prefer to usenumber density to describe these environments, in units of particles per cubic centimetre.

But although it meets the definition of outer space, the atmospheric density within the first few hundred kilometers above the Kármán line is still sufficient to produce significantdrag onsatellites. Most artificial satellites operate in this region, calledlow Earth orbit, and must fire their engines every couple of weeks or a few times a year (depending on solar activity).[37] The drag here is low enough that it could theoretically be overcome by radiation pressure onsolar sails, a proposed propulsion system forinterplanetary travel.[38]

All of theobservable universe is filled with large numbers ofphotons, the so-calledcosmic background radiation, and quite likely a correspondingly large number ofneutrinos. The currenttemperature of this radiation is about 3 K (−270.15 °C; −454.27 °F).

Measurement

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Main article:Pressure measurement

The quality of a vacuum is indicated by the amount of matter remaining in the system, so that a high quality vacuum is one with very little matter left in it. Vacuum is primarily measured by itsabsolute pressure, but a complete characterization requires further parameters, such astemperature and chemical composition. One of the most important parameters is themean free path (MFP) of residual gases, which indicates the average distance that molecules will travel between collisions with each other. As the gas density decreases, the MFP increases, and when the MFP is longer than the chamber, pump, spacecraft, or other objects present, the continuum assumptions offluid mechanics do not apply. This vacuum state is calledhigh vacuum, and the study of fluid flows in this regime is called particle gas dynamics. The MFP of air at atmospheric pressure is very short, 70 nm, but at 100 mPa (≈10−3 Torr) the MFP of room temperature air is roughly 100 mm, which is on the order of everyday objects such asvacuum tubes. TheCrookes radiometer turns when the MFP is larger than the size of the vanes.

Vacuum quality is subdivided into ranges according to the technology required to achieve it or measure it. These ranges were defined in ISO 3529-1:2019 as shown in the following table (100 Pa corresponds to 0.75 Torr; Torr is a non-SI unit):

Pressure rangeDefinitionThe reasoning for the definition of the ranges is as follows (typical circumstances):
Prevailing atmospheric pressure (31 kPa to 110 kPa) to 100 Palow (rough) vacuumPressure can be achieved by simple materials (e.g. regular steel) and positive displacement vacuum pumps; viscous flow regime for gases
<100 Pa to 0.1 Pamedium (fine) vacuumPressure can be achieved by elaborate materials (e.g. stainless steel) and positive displacement vacuum pumps; transitional flow regime for gases
<0.1 Pa to1×10−6 Pahigh vacuum (HV)Pressure can be achieved by elaborate materials (e.g. stainless steel), elastomer sealings and high vacuum pumps; molecular flow regime for gases
<1×10−6 Pa to1×10−9 Paultra-high vacuum (UHV)Pressure can be achieved by elaborate materials (e.g. low-carbon stainless steel), metal sealings, special surface preparations and cleaning, bake-out and high vacuum pumps; molecular flow regime for gases
below1×10−9 Paextreme-high vacuum (XHV)Pressure can be achieved by sophisticated materials (e.g. vacuum fired low-carbon stainless steel, aluminium, copper-beryllium, titanium), metal sealings, special surface preparations and cleaning, bake-out and additional getter pumps; molecular flow regime for gases
  • Atmospheric pressure is variable but 101.325 and 100 kilopascals (1013.25 and 1000.00 mbar) are commonstandard or reference pressures.
  • Deep space is generally much more empty than any artificial vacuum. It may or may not meet the definition of high vacuum above, depending on what region of space and astronomical bodies are being considered. For example, the MFP of interplanetary space is smaller than the size of the Solar System, but larger than small planets and moons. As a result, solar winds exhibit continuum flow on the scale of the Solar System, but must be considered a bombardment of particles with respect to the Earth and Moon.
  • Perfect vacuum is an ideal state of no particles at all. It cannot be achieved in alaboratory, although there may be small volumes which, for a brief moment, happen to have no particles of matter in them. Even if all particles of matter were removed, there would still bephotons, as well asdark energy,virtual particles, and other aspects of thequantum vacuum.

Relative versus absolute measurement

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Vacuum is measured in units ofpressure, typically as a subtraction relative to ambient atmospheric pressure on Earth. But the amount of relative measurable vacuum varies with local conditions. On the surface ofVenus, where ground-level atmospheric pressure is much higher than on Earth, much higher relative vacuum readings would be possible. On the surface of the Moon with almost no atmosphere, it would be extremely difficult to create a measurable vacuum relative to the local environment.

Similarly, much higher than normal relative vacuum readings are possible deep in the Earth's ocean. Asubmarine maintaining an internal pressure of 1 atmosphere submerged to a depth of 10 atmospheres (98 metres; a 9.8-metre column of seawater has the equivalent weight of 1 atm) is effectively a vacuum chamber keeping out the crushing exterior water pressures, though the 1 atm inside the submarine would not normally be considered a vacuum.

Therefore, to properly understand the following discussions of vacuum measurement, it is important that the reader assumes the relative measurements are being done on Earth at sea level, at exactly 1 atmosphere of ambient atmospheric pressure.

Measurements relative to 1 atm

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A glass McLeod gauge, drained of mercury

TheSI unit of pressure is thepascal (symbol Pa), but vacuum is often measured intorrs, named for an Italian physicist Torricelli (1608–1647). A torr is equal to the displacement of a millimeter of mercury (mmHg) in amanometer with 1 torr equaling 133.3223684 pascals above absolute zero pressure. Vacuum is often also measured on thebarometric scale or as a percentage ofatmospheric pressure inbars oratmospheres. Low vacuum is often measured inmillimeters of mercury (mmHg) or pascals (Pa) below standard atmospheric pressure. "Below atmospheric" means that the absolute pressure is equal to the current atmospheric pressure.

In other words, most low vacuum gauges that read, for example 50.79 Torr. Many inexpensive low vacuum gauges have a margin of error and may report a vacuum of 0 Torr but in practice this generally requires a two-stage rotary vane or other medium type of vacuum pump to go much beyond (lower than) 1 torr.

Measuring instruments

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Many devices are used to measure the pressure in a vacuum, depending on what range of vacuum is needed.[39]

Hydrostatic gauges (such as the mercury columnmanometer) consist of a vertical column of liquid in a tube whose ends are exposed to different pressures. The column will rise or fall until its weight is in equilibrium with the pressure differential between the two ends of the tube. The simplest design is a closed-end U-shaped tube, one side of which is connected to the region of interest. Any fluid can be used, butmercury is preferred for its high density and low vapour pressure. Simple hydrostatic gauges can measure pressures ranging from 1 torr (100 Pa) to above atmospheric. An important variation is theMcLeod gauge which isolates a known volume of vacuum and compresses it to multiply the height variation of the liquid column. The McLeod gauge can measure vacuums as high as 10−6 torr (0.1 mPa), which is the lowest direct measurement of pressure that is possible with current technology. Other vacuum gauges can measure lower pressures, but only indirectly by measurement of other pressure-controlled properties. These indirect measurements must be calibrated via a direct measurement, most commonly a McLeod gauge.[40]

The kenotometer is a particular type of hydrostatic gauge, typically used in power plants using steam turbines. The kenotometer measures the vacuum in the steam space of the condenser, that is, the exhaust of the last stage of the turbine.[41]

Mechanical orelastic gauges depend on a Bourdon tube, diaphragm, or capsule, usually made of metal, which will change shape in response to the pressure of the region in question. A variation on this idea is thecapacitance manometer, in which the diaphragm makes up a part of a capacitor. A change in pressure leads to the flexure of the diaphragm, which results in a change in capacitance. These gauges are effective from 103 torr to 10−4 torr, and beyond.

Thermal conductivity gauges rely on the fact that the ability of a gas to conduct heat decreases with pressure. In this type of gauge, a wire filament is heated by running current through it. Athermocouple orResistance Temperature Detector (RTD) can then be used to measure the temperature of the filament. This temperature is dependent on the rate at which the filament loses heat to the surrounding gas, and therefore on the thermal conductivity. A common variant is thePirani gauge which uses a single platinum filament as both the heated element and RTD. These gauges are accurate from 10 torr to 10−3 torr, but they are sensitive to the chemical composition of the gases being measured.

Ionization gauges are used in ultrahigh vacuum. They come in two types: hot cathode and cold cathode. In thehot cathode version an electrically heated filament produces an electron beam. The electrons travel through the gauge and ionize gas molecules around them. The resulting ions are collected at a negative electrode. The current depends on the number of ions, which depends on the pressure in the gauge. Hot cathode gauges are accurate from 10−3 torr to 10−10 torr. The principle behindcold cathode version is the same, except that electrons are produced in a discharge created by a high voltage electrical discharge. Cold cathode gauges are accurate from 10−2 torr to 10−9 torr. Ionization gauge calibration is very sensitive to construction geometry, chemical composition of gases being measured, corrosion and surface deposits. Their calibration can be invalidated by activation at atmospheric pressure or low vacuum. The composition of gases at high vacuums will usually be unpredictable, so a mass spectrometer must be used in conjunction with the ionization gauge for accurate measurement.[42]

Uses

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Light bulbs contain a partial vacuum, usually backfilled withargon, which protects thetungsten filament

Vacuum is useful in a variety of processes and devices. Its first widespread use was in theincandescent light bulb to protect the filament from chemical degradation. The chemical inertness produced by a vacuum is also useful forelectron-beam welding,cold welding,vacuum packing andvacuum frying.Ultra-high vacuum is used in the study of atomically clean substrates, as only a very good vacuum preserves atomic-scale clean surfaces for a reasonably long time (on the order of minutes to days). High to ultra-high vacuum removes the obstruction of air, allowing particle beams to deposit or remove materials without contamination. This is the principle behindchemical vapor deposition,physical vapor deposition, anddry etching which are essential to the fabrication ofsemiconductors andoptical coatings, and tosurface science. The reduction of convection provides the thermal insulation ofthermos bottles. Deep vacuum lowers theboiling point of liquids and promotes low temperatureoutgassing which is used infreeze drying,adhesive preparation,distillation,metallurgy, and process purging. The electrical properties of vacuum makeelectron microscopes andvacuum tubes possible, includingcathode-ray tubes.Vacuum interrupters are used in electrical switchgear.Vacuum arc processes are industrially important for production of certain grades of steel or high purity materials. The elimination of airfriction is useful forflywheel energy storage andultracentrifuges.

This shallow water well pump reduces atmospheric air pressure inside the pump chamber. Atmospheric pressure extends down into the well, and forces water up the pipe into the pump to balance the reduced pressure. Above-ground pump chambers are only effective to a depth of approximately 9 meters due to the water column weight balancing the atmospheric pressure.

Vacuum-driven machines

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Vacuums are commonly used to producesuction, which has an even wider variety of applications. TheNewcomen steam engine used vacuum instead of pressure to drive a piston. In the 19th century, vacuum was used for traction onIsambard Kingdom Brunel's experimentalatmospheric railway.Vacuum brakes were once widely used ontrains in the UK but, except onheritage railways, they have been replaced byair brakes.

Manifold vacuum can be used to driveaccessories onautomobiles. The best known application is thevacuum servo, used to provide power assistance for thebrakes. Obsolete applications include vacuum-drivenwindscreen wipers andAutovac fuel pumps. Some aircraft instruments (Attitude Indicator (AI) and theHeading Indicator (HI)) are typically vacuum-powered, as protection against loss of all (electrically powered) instruments, since early aircraft often did not have electrical systems, and since there are two readily available sources of vacuum on a moving aircraft, the engine and an external venturi.Vacuum induction melting uses electromagnetic induction within a vacuum.

Maintaining a vacuum in thecondenser is an important aspect of the efficient operation ofsteam turbines. A steam jetejector orliquid ring vacuum pump is used for this purpose. The typical vacuum maintained in the condenser steam space at the exhaust of the turbine (also called condenser backpressure) is in the range 5 to 15 kPa (absolute), depending on the type of condenser and the ambient conditions.

Outgassing

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Main article:Outgassing

Evaporation andsublimation into a vacuum is calledoutgassing. All materials, solid or liquid, have a smallvapour pressure, and their outgassing becomes important when the vacuum pressure falls below this vapour pressure. Outgassing has the same effect as a leak and will limit the achievable vacuum. Outgassing products may condense on nearby colder surfaces, which can be troublesome if they obscure optical instruments or react with other materials. This is of great concern to space missions, where an obscured telescope or solar cell can ruin an expensive mission.

The most prevalent outgassing product in vacuum systems is water absorbed by chamber materials. It can be reduced by desiccating or baking the chamber, and removing absorbent materials. Outgassed water can condense in the oil ofrotary vane pumps and reduce their net speed drastically if gas ballasting is not used. High vacuum systems must be clean and free of organic matter to minimize outgassing.

Ultra-high vacuum systems are usually baked, preferably under vacuum, to temporarily raise the vapour pressure of all outgassing materials and boil them off. Once the bulk of the outgassing materials are boiled off and evacuated, the system may be cooled to lower vapour pressures and minimize residual outgassing during actual operation. Some systems are cooled well below room temperature byliquid nitrogen to shut down residual outgassing and simultaneouslycryopump the system.

Pumping and ambient air pressure

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Deep wells have the pump chamber down in the well close to the water surface, or in the water. A "sucker rod" extends from the handle down the center of the pipe deep into the well to operate the plunger. The pump handle acts as a heavy counterweight against both the sucker rod weight and the weight of the water column standing on the upper plunger up to ground level.
Main article:Vacuum pump

Fluids cannot generally be pulled, so a vacuum cannot be created bysuction. Suction can spread and dilute a vacuum by letting a higher pressure push fluids into it, but the vacuum has to be created first before suction can occur. The easiest way to create an artificial vacuum is to expand the volume of a container. For example, thediaphragm muscle expands the chest cavity, which causes the volume of the lungs to increase. This expansion reduces the pressure and creates a partial vacuum, which is soon filled by air pushed in by atmospheric pressure.

To continue evacuating a chamber indefinitely without requiring infinite growth, a compartment of the vacuum can be repeatedly closed off, exhausted, and expanded again. This is the principle behindpositive displacement pumps, like the manual water pump for example. Inside the pump, a mechanism expands a small sealed cavity to create a vacuum. Because of the pressure differential, some fluid from the chamber (or the well, in our example) is pushed into the pump's small cavity. The pump's cavity is then sealed from the chamber, opened to the atmosphere, and squeezed back to a minute size.

A cutaway view of aturbomolecular pump, a momentum transfer pump used to achieve high vacuum

The above explanation is merely a simple introduction to vacuum pumping, and is not representative of the entire range of pumps in use. Many variations of the positive displacement pump have been developed, and many other pump designs rely on fundamentally different principles.Momentum transfer pumps, which bear some similarities to dynamic pumps used at higher pressures, can achieve much higher quality vacuums than positive displacement pumps.Entrapment pumps can capture gases in a solid or absorbed state, often with no moving parts, no seals and no vibration. None of these pumps are universal; each type has important performance limitations. They all share a difficulty in pumping low molecular weight gases, especiallyhydrogen,helium, andneon.

The lowest pressure that can be attained in a system is also dependent on many things other than the nature of the pumps. Multiple pumps may be connected in series, called stages, to achieve higher vacuums. The choice of seals, chamber geometry, materials, and pump-down procedures will all have an impact. Collectively, these are calledvacuum technique. And sometimes, the final pressure is not the only relevant characteristic. Pumping systems differ in oil contamination, vibration, preferential pumping of certain gases, pump-down speeds, intermittent duty cycle, reliability, or tolerance to high leakage rates.

Inultra high vacuum systems, some very "odd" leakage paths and outgassing sources must be considered. The water absorption ofaluminium andpalladium becomes an unacceptable source of outgassing, and even the adsorptivity of hard metals such as stainless steel ortitanium must be considered. Some oils and greases will boil off in extreme vacuums. The permeability of the metallic chamber walls may have to be considered, and the grain direction of the metallic flanges should be parallel to the flange face.

The lowest pressures currently achievable in laboratory are about 1×10−13 torrs (13 pPa).[43] However, pressures as low as 5×10−17 torrs (6.7 fPa) have been indirectly measured in a 4 K (−269.15 °C; −452.47 °F) cryogenic vacuum system.[4] This corresponds to ≈100 particles/cm3.

Effects on humans and animals

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See also:Space exposure andUncontrolled decompression
This painting,An Experiment on a Bird in the Air Pump byJoseph Wright of Derby, 1768, depicts an experiment performed byRobert Boyle in 1660.

Humans and animals exposed to vacuum will loseconsciousness after a few seconds and die ofhypoxia within minutes, but the symptoms are not nearly as graphic as commonly depicted in media and popular culture. The reduction in pressure lowers the temperature at which blood and other body fluids boil, but the elastic pressure of blood vessels ensures that this boiling point remains above the internal body temperature of37 °C.[44] Although the blood will not boil, the formation of gas bubbles in bodily fluids at reduced pressures, known asebullism, is still a concern. The gas may bloat the body to twice its normal size and slow circulation, but tissues are elastic and porous enough to prevent rupture.[45] Swelling and ebullism can be restrained by containment in aflight suit.Shuttle astronauts wore a fitted elastic garment called the Crew Altitude Protection Suit (CAPS) which prevents ebullism at pressures as low as 2 kPa (15 Torr).[46] Rapid boiling will cool the skin and create frost, particularly in the mouth, but this is not a significant hazard.

Animal experiments show that rapid and complete recovery is normal for exposures shorter than 90 seconds, while longer full-body exposures are fatal and resuscitation has never been successful.[47] A study by NASA on eight chimpanzees found all of them survived two and a half minute exposures to vacuum.[48] There is only a limited amount of data available from human accidents, but it is consistent with animal data. Limbs may be exposed for much longer if breathing is not impaired.[49]Robert Boyle was the first to show in 1660 that vacuum is lethal to small animals.

An experiment indicates that plants are able to survive in a low pressure environment (1.5 kPa) for about 30 minutes.[50][51]

Cold or oxygen-rich atmospheres can sustain life at pressures much lower than atmospheric, as long as the density of oxygen is similar to that of standard sea-level atmosphere. The colder air temperatures found at altitudes of up to 3 km generally compensate for the lower pressures there.[49] Above this altitude, oxygen enrichment is necessary to preventaltitude sickness in humans that did not undergo prioracclimatization, andspacesuits are necessary to prevent ebullism above 19 km.[49] Most spacesuits use only 20 kPa (150 Torr) of pure oxygen. This pressure is high enough to prevent ebullism, butdecompression sickness andgas embolisms can still occur if decompression rates are not managed.

Rapid decompression can be much more dangerous than vacuum exposure itself. Even if the victim does not hold his or her breath, venting through the windpipe may be too slow to prevent the fatal rupture of the delicatealveoli of thelungs.[49]Eardrums and sinuses may be ruptured by rapid decompression, soft tissues may bruise and seep blood, and the stress of shock will accelerate oxygen consumption leading to hypoxia.[52] Injuries caused by rapid decompression are calledbarotrauma. A pressure drop of 13 kPa (100 Torr), which produces no symptoms if it is gradual, may be fatal if it occurs suddenly.[49]

Someextremophilemicroorganisms, such astardigrades, can survive vacuum conditions for periods of days or weeks.[53]

Examples

[edit]
See also:Vacuum pump
Pressure (Pa if not explained)Pressure (Torr, atm)Mean free pathMolecules per cm3
Standard atmosphere, for comparison101.325 kPa760 torrs (1.00 atm)66 nm2.5×1019[54]
Intensehurricaneapprox. 87 to 95 kPa650 to 710
Vacuum cleanerapproximately 80 kPa60070 nm1019
Steam turbine exhaust (Condenser backpressure)9 kPa
liquid ring vacuum pumpapproximately 3.2 kPa24 torrs (0.032 atm)1.75 μm1018
Mars atmosphere1.155 kPa to 0.03 kPa (mean 0.6 kPa)8.66 to 0.23 torrs (0.01139 to 0.00030 atm)
freeze drying100 to 101 to 0.1100 μm to 1 mm1016 to 1015
Incandescent light bulb10 to 10.1 to 0.01 torrs (0.000132 to 1.3×10−5 atm)1 mm to 1 cm1015 to 1014
Thermos bottle1 to 0.01[1]1×10−2 to 1×10−4 torrs (1.316×10−5 to 1.3×10−7 atm)1 cm to 1 m1014 to 1012
Earththermosphere1 Pa to1×10−710−2 to 10−91 cm to 100 km1014 to 107
Vacuum tube1×10−5 to1×10−810−7 to 10−101 to 1,000 km109 to 106
Pressure on theMoonapproximately1×10−910−1110,000 km4×105[55]
CryopumpedMBE chamber1×10−6 to1×10−1010−8 to 10−1210 to 100,000 km108 to 104
Densenebula  10,000[1]
Interplanetary space  11[1]
Interstellar space  1[56]
Intergalactic space 10−6[1]

See also

[edit]

References

[edit]
  1. ^abcdeChambers, Austin (2004).Modern Vacuum Physics. Boca Raton: CRC Press.ISBN 978-0-8493-2438-3.OCLC 55000526.[page needed]
  2. ^Harris, Nigel S. (1989).Modern Vacuum Practice. McGraw-Hill. p. 3.ISBN 978-0-07-707099-1.
  3. ^Campbell, Jeff (2005).Speed cleaning. Rodale. p. 97.ISBN 978-1-59486-274-8. Note that 1 inch of water is ≈0.0025 atm.
  4. ^abGabrielse, G.; Fei, X.; Orozco, L.; Tjoelker, R.; Haas, J.; Kalinowsky, H.; Trainor, T.; Kells, W. (1990)."Thousandfold improvement in the measured antiproton mass"(PDF).Physical Review Letters.65 (11):1317–1320.Bibcode:1990PhRvL..65.1317G.doi:10.1103/PhysRevLett.65.1317.PMID 10042233.
  5. ^abTadokoro, M. (1968). "A Study of the Local Group by Use of the Virial Theorem".Publications of the Astronomical Society of Japan.20 (3): 230.Bibcode:1968PASJ...20..230T.doi:10.1093/pasj/20.3.230. This source estimates a density of7×10−29 g/cm3 for theLocal Group. Adalton is1.66×10−24 g, for roughly 40 atoms per cubic meter.
  6. ^Jörg Hüttner & Martin Walter (Ed.) (2022).Clemens Timpler: Physicae seu philosophiae naturalis systema methodicum. Pars prima; complectens physicam generalem. Hildesheim / Zürich / New York: Georg Olms Verlag. pp. 28–37.ISBN 978-3-487-16076-4.
  7. ^How to Make an Experimental Geissler Tube,Popular Science monthly, February 1919, Unnumbered page. Bonnier Corporation
  8. ^"What words in the English language contain two u's in a row?".Oxford Dictionaries Online. Archived fromthe original on August 8, 2018. Retrieved2011-10-23.
  9. ^abGenz, Henning (1994).Nothingness: The Science of Empty Space. New York: Perseus Book Publishing (published 1999).ISBN 978-0-7382-0610-3.OCLC 48836264.
  10. ^Druart, Therese-Anne (2016),"al-Farabi", in Zalta, Edward N. (ed.),Stanford Encyclopedia of Philosophy (Winter 2021 ed.), retrieved2022-10-25
  11. ^McGinnis, Jon (2022),"Arabic and Islamic Natural Philosophy and Natural Science", in Zalta, Edward N. (ed.),Stanford Encyclopedia of Philosophy (Spring 2022 ed.), retrieved2022-08-11.
  12. ^Dallal, Ahmad (2001–2002)."The Interplay of Science and Theology in the Fourteenth-century Kalam". From Medieval to Modern in the Islamic World, Sawyer Seminar at theUniversity of Chicago. Archived fromthe original on 2012-02-10. Retrieved2008-02-02.
  13. ^Donald Routledge Hill, "Mechanical Engineering in the Medieval Near East",Scientific American, May 1991, pp. 64–69 (cf.Donald Routledge Hill,Mechanical EngineeringArchived 2007-12-25 at theWayback Machine).
  14. ^Donald Routledge Hill (1996),A History of Engineering in Classical and Medieval Times,Routledge, pp. 143, 150–152.
  15. ^abBarrow, John D. (2000).The Book of Nothing: Vacuums, Voids, and the Latest Ideas about the Origins of the Universe (1st American ed.). New York: Pantheon Books.ISBN 978-0-09-928845-9.OCLC 46600561.
  16. ^Barrow, J.D. (2002).The Book of Nothing: Vacuums, Voids, and the Latest Ideas About the Origins of the Universe. Vintage Series. Vintage. pp. 71–72, 77.ISBN 978-0-375-72609-5.LCCN 00058894.
  17. ^Grant, Edward (1981).Much ado about nothing: theories of space and vacuum from the Middle Ages to the scientific revolution. Cambridge University Press.ISBN 978-0-521-22983-8.
  18. ^"The World's Largest Barometer". Archived fromthe original on 2008-04-17. Retrieved2008-04-30.
  19. ^"Otto von Guericke | Prussian physicist, engineer, and philosopher | Britannica".www.britannica.com. Retrieved2022-08-11.
  20. ^Robert Hogarth Patterson,Essays in History and Art 10, 1862.
  21. ^Pickering, W.H. (1912)."Solar system, the motion of the, relatively to the interstellar absorbing medium".Monthly Notices of the Royal Astronomical Society.72 (9): 740.Bibcode:1912MNRAS..72..740P.doi:10.1093/mnras/72.9.740.
  22. ^abWerner S. Weiglhofer (2003)."§ 4.1 The classical vacuum as reference medium". In Werner S. Weiglhofer; Akhlesh Lakhtakia (eds.).Introduction to complex mediums for optics and electromagnetics. SPIE Press. pp. 28, 34.ISBN 978-0-8194-4947-4.
  23. ^Tom G. MacKay (2008)."Electromagnetic Fields in Linear Bianisotropic Mediums". In Emil Wolf (ed.).Progress in Optics. Vol. 51. Elsevier. p. 143.ISBN 978-0-444-52038-8.
  24. ^Gilbert Grynberg; Alain Aspect; Claude Fabre (2010).Introduction to Quantum Optics: From the Semi-Classical Approach to Quantized Light. Cambridge University Press. p. 341.ISBN 978-0-521-55112-0....deals with the quantum vacuum where, in contrast to the classical vacuum, radiation has properties, in particular, fluctuations, with which one can associate physical effects.
  25. ^For a qualitative description of vacuum fluctuations and virtual particles, seeLeonard Susskind (2006).The cosmic landscape: string theory and the illusion of intelligent design. Little, Brown and Co. pp. 60ff.ISBN 978-0-316-01333-8.
  26. ^The relative permeability and permittivity of field-theoretic vacuums is described inKurt Gottfried; Victor Frederick Weisskopf (1986).Concepts of particle physics. Vol. 2. Oxford University Press. p. 389.ISBN 978-0-19-503393-9. and more recently inJohn F. Donoghue; Eugene Golowich; Barry R. Holstein (1994).Dynamics of the standard model. Cambridge University Press. p. 47.ISBN 978-0-521-47652-2. and alsoR. Keith Ellis; W.J. Stirling; B.R. Webber (2003).QCD and collider physics. Cambridge University Press. pp. 27–29.ISBN 978-0-521-54589-1.Returning to the vacuum of a relativistic field theory, we find that both paramagnetic and diamagnetic contributions are present.QCD vacuum isparamagnetic, whileQED vacuum isdiamagnetic. SeeCarlos A. Bertulani (2007).Nuclear physics in a nutshell. Princeton University Press. p. 26.Bibcode:2007npn..book.....B.ISBN 978-0-691-12505-3.
  27. ^"Speed of light in vacuum,c, c0".The NIST reference on constants, units, and uncertainty: Fundamental physical constants. NIST. Retrieved2011-11-28.
  28. ^Chattopadhyay, D. & Rakshit, P.C. (2004).Elements of Physics. Vol. 1. New Age International. p. 577.ISBN 978-81-224-1538-4.
  29. ^"Electric constant, ε0".The NIST reference on constants, units, and uncertainty: Fundamental physical constants. NIST. Retrieved2011-11-28.
  30. ^"Magnetic constant, μ0".The NIST reference on constants, units, and uncertainty: Fundamental physical constants. NIST. Retrieved2011-11-28.
  31. ^"Characteristic impedance of vacuum,Z0".The NIST reference on constants, units, and uncertainty: Fundamental physical constants. Retrieved2011-11-28.
  32. ^Mackay, Tom G & Lakhtakia, Akhlesh (2008)."§ 3.1.1 Free space". In Emil Wolf (ed.).Progress in Optics. Vol. 51. Elsevier. p. 143.ISBN 978-0-444-53211-4.
  33. ^For example, seeCraig, D.P. & Thirunamachandran, T. (1998).Molecular Quantum Electrodynamics (Reprint of Academic Press 1984 ed.). Courier Dover Publications. p. 40.ISBN 978-0-486-40214-7.
  34. ^In effect, the dielectric permittivity of the vacuum of classical electromagnetism is changed. For example, seeZeidler, Eberhard (2011)."§ 19.1.9 Vacuum polarization in quantum electrodynamics".Quantum Field Theory III: Gauge Theory: A Bridge Between Mathematicians and Physicists. Springer. p. 952.ISBN 978-3-642-22420-1.
  35. ^Altarelli, Guido (2008)."Chapter 2: Gauge theories and the Standard Model".Elementary Particles: Volume 21/A of Landolt-Börnstein series. Springer. pp. 2–3.ISBN 978-3-540-74202-9.The fundamental state of minimum energy, the vacuum, is not unique and there are a continuum of degenerate states that altogether respect the symmetry...
  36. ^Squire, Tom (September 27, 2000)."U.S. Standard Atmosphere, 1976".Thermal Protection Systems Expert and Material Properties Database. Archived fromthe original on October 15, 2011. Retrieved2011-10-23.
  37. ^"Catalog of Earth Satellite Orbits".earthobservatory.nasa.gov. 2009-09-04. Retrieved2019-01-28.
  38. ^Andrews, Dana G.; Zubrin, Robert M. (1990)."Magnetic Sails & Interstellar Travel"(PDF).Journal of the British Interplanetary Society.43:265–272.doi:10.2514/3.26230.S2CID 55324095. Archived fromthe original(PDF) on 2019-03-02. Retrieved2019-07-21.
  39. ^John H., Moore; Christopher Davis; Michael A. Coplan & Sandra Greer (2002).Building Scientific Apparatus. Boulder, Colorado: Westview Press.ISBN 978-0-8133-4007-4.OCLC 50287675.[page needed]
  40. ^Beckwith, Thomas G.; Roy D. Marangoni & John H. Lienhard V (1993). "Measurement of Low Pressures".Mechanical Measurements (Fifth ed.). Reading, Massachusetts: Addison-Wesley. pp. 591–595.ISBN 978-0-201-56947-6.
  41. ^"Kenotometer Vacuum Gauge". Edmonton Power Historical Foundation. 22 November 2013. Retrieved3 February 2014.
  42. ^Robert M. Besançon, ed. (1990). "Vacuum Techniques".The Encyclopedia of Physics (3rd ed.). Van Nostrand Reinhold, New York. pp. 1278–1284.ISBN 978-0-442-00522-1.
  43. ^Ishimaru, H (1989). "Ultimate Pressure of the Order of 10−13 torr in an Aluminum Alloy Vacuum Chamber".Journal of Vacuum Science and Technology.7 (3–II):2439–2442.Bibcode:1989JVSTA...7.2439I.doi:10.1116/1.575916.
  44. ^Landis, Geoffrey (7 August 2007)."Human Exposure to Vacuum". geoffreylandis.com. Archived fromthe original on 21 July 2009. Retrieved25 March 2006.
  45. ^Billings, Charles E. (1973). "Chapter 1) Barometric Pressure". In Parker, James F.; West, Vita R. (eds.).Bioastronautics Data Book (Second ed.). NASA. p. 5.hdl:2060/19730006364. NASA SP-3006.
  46. ^Webb P. (1968). "The Space Activity Suit: An Elastic Leotard for Extravehicular Activity".Aerospace Medicine.39 (4):376–383.PMID 4872696.
  47. ^Cooke, J.P.; Bancroft, R.W. (1966). "Some cardiovascular responses in anesthetized dogs during repeated decompressions to a near-vacuum".Aerospace Medicine.37 (11):1148–1152.PMID 5972265.
  48. ^Koestler, A. G. (November 1965)."The Effect on the Chimpanzee of Rapid Decompression to a near Vacuum"(PDF).NASA.
  49. ^abcdeHarding, Richard M. (1989).Survival in Space: Medical Problems of Manned Spaceflight. London: Routledge.ISBN 978-0-415-00253-0.OCLC 18744945..
  50. ^Wheeler, R.M.; Wehkamp, C.A.; Stasiak, M.A.; Dixon, M.A.; Rygalov, V.Y. (2011). "Plants survive rapid decompression: Implications for bioregenerative life support".Advances in Space Research.47 (9):1600–1607.Bibcode:2011AdSpR..47.1600W.doi:10.1016/j.asr.2010.12.017.hdl:2060/20130009997.
  51. ^Ferl, RJ; Schuerger, AC; Paul, AL; Gurley, WB; Corey, K; Bucklin, R (2002). "Plant adaptation to low atmospheric pressures: Potential molecular responses".Life Support & Biosphere Science.8 (2):93–101.PMID 11987308.
  52. ^Czarnik, Tamarack R. (1999)."EBULLISM AT 1 MILLION FEET: Surviving Rapid/Explosive Decompression".unpublished review by Landis, Geoffrey A. geoffreylandis.
  53. ^Jönsson, K. Ingemar; Rabbow, Elke; Schill, Ralph O.; Harms-Ringdahl, Mats & Rettberg, Petra (9 September 2008)."Tardigrades survive exposure to space in low Earth orbit".Current Biology.18 (17):R729 –R731.Bibcode:2008CBio...18.R729J.doi:10.1016/j.cub.2008.06.048.PMID 18786368.S2CID 8566993.
  54. ^Computed using"1976 Standard Atmosphere Properties" calculator. Retrieved 2012-01-28
  55. ^Öpik, E.J. (1962). "The lunar atmosphere".Planetary and Space Science.9 (5):211–244.Bibcode:1962P&SS....9..211O.doi:10.1016/0032-0633(62)90149-6.
  56. ^University of New Hampshire Experimental Space Plasma Group."What is the Interstellar Medium".The Interstellar Medium, an online tutorial. Archived fromthe original on 2006-02-17. Retrieved2006-03-15.

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