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Thulium dibromide

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(Redirected fromThulium(II) bromide)
Thulium dibromide
Names
Other names
Thulium(II) bromide
Identifiers
3D model (JSmol)
  • InChI=1S/2BrH.Tm/h2*1H;/q;;+2/p-2
    Key: AZLHTMVBZVOUEC-UHFFFAOYSA-L
  • [Tm+2].[Br-].[Br-]
Properties
TmBr2
Molar mass328.74
Appearancedark green solid[1]
Melting point619 °C[1]
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Thulium dibromide is aninorganic compound, with thechemical formula of TmBr2. It is a dark green solid that is easy to dissolve, with theSrI2 structure and it needs to be stored in an inert atmosphere.

Preparation

[edit]

Thulium dibromide can be prepared by reactingthulium withthulium tribromide at 800~900 °C in a vacuum.[1] At high temperatures, the alkali metals can also obtain bromide, but only lithium and sodium reactions obtain thulium dibromide, and the response to the participation ofpotassium,rubidium, andcaesium.[2]

References

[edit]
  1. ^abcGeorg Brauer (Hrsg.), unter Mitarbeit von Marianne Baudler u. a.: Handbuch der Präparativen Anorganischen Chemie. 3., umgearbeitete Auflage. Band I, Ferdinand Enke, Stuttgart 1975, ISBN 3-432-02328-6, S. 1081.
  2. ^Schilling, Gaby; Kunert, Christine; Schleid, Thomas; Meyer, Gerd. Metallothermic reduction of the tribromides and triiodides of thulium and ytterbium by alkali metals.Zeitschrift fuer Anorganische und Allgemeine Chemie, 1992. 618: 7-12.ISSN 0044-2313
Tm(II)
Tm(III)
Salts and covalent derivatives of thebromide ion
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