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Thomas Andrews (scientist)

From Wikipedia, the free encyclopedia
Irish chemist and physicist (1813–1885)
For other people named Thomas Andrews, seeThomas Andrews (disambiguation).

Thomas Andrews
Born19 December 1813
Belfast, Ireland
Died26 November 1885 (aged 71)
Belfast, Ireland
Alma materUniversity of Glasgow
Known forPhase transitions
AwardsRoyal Medal(1844)
Scientific career
FieldsChemistry
Physics

Thomas AndrewsFRSFRSE (19 December 1813 – 26 November 1885) was an Irishchemist andphysicist who did important work onphase transitions between gases and liquids. He was a longtime professor of chemistry atQueen's University of Belfast.

Life

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Andrews was born in Belfast, Ireland, where his father was alinenmerchant. He attended theBelfast Academy and theRoyal Belfast Academical Institution, where at the latter of which he studied mathematics underJames Thomson. In 1828 he went to theUniversity of Glasgow to study chemistry under ProfessorThomas Thomson, then studied atTrinity College, Dublin, where he gained distinction inclassics as well as in science. Finally, atUniversity of Edinburgh in 1835, he was awarded a doctorate in medicine.[1]

Andrews began a successful medical practice in his native Belfast in 1835, also giving instruction in chemistry at the Academical Institution. In 1845 he was appointed vice-president of the newly establishedQueen's University of Belfast, and professor of chemistry there. He held these two offices until his retirement in 1879 at age 66.[1] He died in 1885, and was buried in the Borough Cemetery in Belfast.

In 1842, Andrews married Jane Hardie Walker (1818–1899). They had six children, including the geologistMary Andrews.[2]

Work

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Andrews first became known as a scientific investigator with his work on the heat developed in chemical actions, for which theRoyal Society awarded him aRoyal Medal in 1844. Another important investigation, undertaken in collaboration withPeter Guthrie Tait, was devoted toozone.[1]

The pV diagram of carbon dioxide. Andrews estimated that the critical point of carbon dioxide is around 30.92 C (modern value is 30.98 C). Note that unlike modern conventions, this diagram shows pressure on the x-axis and volume on the y-axis.[3]

His reputation mainly rests on his work withliquefaction of gases. In the 1860s he carried out a very complete inquiry into thegas laws—expressing the relations ofpressure,temperature, andvolume incarbon dioxide. In particular, he established the concepts ofcritical temperature andcritical pressure, showing that a substance passes from vapor to liquid state without any breach of continuity.[1][4][5] He concluded that

... the gaseous and liquid states are only distant stages of the same condition of matter, and are capable of passing into one another by a process of continuous change.

In Andrews' experiments on phase transitions, he showed that carbon dioxide may be carried from any of the states we usually call liquid to any of those we usually call gas, without losing homogeneity. The mathematical physicistWillard Gibbs cited these results in support of theGibbs free energy equation. They also set off a race among researchers to liquify various other gases. In 1877-78Louis Paul Cailletet was the first to liquefy oxygen.[6]

Selected writings

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  • Thomas Andrews, "The Bakerian Lecture: On the Continuity of the Gaseous and Liquid States of Matter", Philosophical Transactions of the Royal Society of London, vol. 159 (1869), pp. 575–590.
  • Tait, P. G.; Crum Brown, A. (1889).The Scientific Papers of the Late Thomas Andrews. London and New York: Macmillan and Company. - Contains a biographical memoir of Andrews by Tait and Crum Brown

References

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  1. ^abcdWikisource One or more of the preceding sentences incorporates text from a publication now in thepublic domainChisholm, Hugh, ed. (1911). "Andrews, Thomas".Encyclopædia Britannica. Vol. 1 (11th ed.). Cambridge University Press. p. 974.
  2. ^Mary R. S. Creese; Thomas M. Creese (2004).Ladies in the Laboratory 2. Scarecrow Press. p. 51.ISBN 978-0-8108-4979-2. Retrieved7 October 2012.
  3. ^Andrews, Thomas (1869)."The Bakerian Lecture: On the Continuity of the Gaseous and Liquid States of Matter".Philosophical Transactions of the Royal Society of London.159:575–590.ISSN 0261-0523.JSTOR 109009.
  4. ^Andrews coined the term "critical point" in 1869 in: Andrews, Thomas (1869)"The Bakerian lecture: On the continuity of the gaseous and liquid states of matter,"Philosophical Transactions of the Royal Society (London),159 : 575-590; the term "critical point" appears on page 588.
  5. ^Goudaroulis, Yorgos (1994)."Searching for a name: the development of the concept of the critical point (1822-1869)".Revue d'histoire des sciences.47 (3/4):353–379.doi:10.3406/rhs.1994.1210.ISSN 0151-4105.JSTOR 23633496.
  6. ^Papanelopoulou, Faidra (20 December 2013)."Louis Paul Cailletet: The liquefaction of oxygen and the emergence of low-temperature research".Notes and Records of the Royal Society of London.67 (4):355–373.doi:10.1098/rsnr.2013.0047.ISSN 0035-9149.PMC 3826198.

Further reading

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Wikisource has the text of theDictionary of National Biography 1901 supplement's article aboutAndrews, Thomas.
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