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Tetrasaccharide

From Wikipedia, the free encyclopedia
Polysaccharide with four sugar units
Chemical structure of stachyose

Atetrasaccharide is acarbohydrate which gives uponhydrolysis four molecules of the same or differentmonosaccharides. For example,stachyose upon hydrolysis gives one molecule each ofglucose andfructose and two molecules ofgalactose. The general formula of a tetrasaccharide is typically C24H42O21.

Structure and occurrence of tetrasaccharides
Namechemical compoundfunction/occur
Lychnose (1-α-Galactosyl-raffinose)O-α-D-Galp-(1→6)-O-α-D-Glup-(1→2)-O-β-D-Fruf-(1→1)-O-α-D-Galp
MaltotetraoseO-α-D-Glcp-(1→4)-O-α-D-Glcp-(1→4)-O-α-D-Glcp-(1→4)-D-GlcpinStarchsyrup
NigerotetraoseO-α-D-Glcp-(1→3)-O-α-D-Glcp-(1→3)-O-α-D-Glcp-(1→3)-D-Glcp
Nystose (β-D-Fructosyl-1-kestose)O-α-D-Glcp-(1→2)-β-D-Fruf-(1→2)-β-D-Fruf-(1→2)-β-D-Fruf
SesamoseO-α-D-Galp-(1→6)-O-α-D-Galp-(1→6)-O-β-D-Fruf-(2→1)-O-α-D-Glcp
StachyoseO-α-D-Galp-(1→6)-O-α-D-Galp-(1→6)-O-α-D-Glcp-(1→2)-β-D-Frufwidespread in plants (artichoke,soybean)

In addition to free tetrasaccharides, the term tetrasaccharide is often used to describe subunits or bioconjugates. Thus, tetrasaccharide groups appended to red blood cells are responsible forblood types.[1] A repeating modified tetrasaccharide (gal-gal-gal-raf) comprisesgellan.[2]

References

[edit]
  1. ^Lichtenthaler, Frieder W. (2010). "Carbohydrates: Occurrence, Structures and Chemistry".Ullmann's Encyclopedia of Industrial Chemistry.doi:10.1002/14356007.a05_079.pub2.ISBN 978-3-527-30385-4.
  2. ^Morris, Edwin R.; Nishinari, Katsuyoshi; Rinaudo, Marguerite (2012). "Gelation of gellan – A review".Food Hydrocolloids.28 (2):373–411.doi:10.1016/j.foodhyd.2012.01.004.
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