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Tetraoxidane

From Wikipedia, the free encyclopedia
Tetraoxidane
Names
IUPAC name
Tetraoxidane
Other names
Hydroxyperoxide, dihydrogen tetroxide, diperoxide, bisperoxide
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/H2O4/c1-3-4-2/h1-2H
    Key: RSPISYXLHRIGJD-UHFFFAOYSA-N
  • OOOO
Properties
H2O4
Molar mass66.012 g·mol−1
Density1.8±0.1 g/cm3
Related compounds
Related compounds
Pentaoxidane
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Tetraoxidane is an inorganic compound ofhydrogen andoxygen with the chemical formulaH
2
O
4
.[1][2][3] This is one of the unstablehydrogen polyoxides.[4]

Synthesis

[edit]

The compound is prepared by a chemical reaction betweenhydroperoxyl radicals (HOO•) at low temperatures:[5][6]

2 HOO• ⇌ H2O4

Physical properties

[edit]

This is the fourth member of the polyoxidanes. The first three are water [(mon)oxidane],hydrogen peroxide (dioxidane), andtrioxidane. Tetraoxidane is more unstable than the previous compounds. The term "tetraoxidane" extends beyond the parent compound to several daughter compounds of the general formulaR
2
O
4
, where R can be hydrogen, halogen atoms, or various inorganic and organic monovalent radicals. The two Rs together can be replaced by a divalent radical, so heterocyclic tetraoxidanes also exist.[7]

Ionization

[edit]

Tetraoxidaneautoionizes when in liquid form:

H2O4 ⇌ H+ + HO4
2 H2O4 ⇌ H3O+4 + HO4

References

[edit]
  1. ^Mckay, Daniel J.; Wright, James S. (1 February 1998)."How Long Can You Make an Oxygen Chain?".Journal of the American Chemical Society.120 (5):1003–1013.doi:10.1021/ja971534b.ISSN 0002-7863. Retrieved16 May 2023.
  2. ^"hydroxyperoxide". ChemScr. Retrieved15 May 2023.
  3. ^The Chemistry of Peroxides, Volume 3.John Wiley & Sons. 20 April 2015. p. 198.ISBN 978-1-118-41271-8. Retrieved15 May 2023.
  4. ^"Selected ATcT [1, 2] enthalpy of formation based on version 1.122 of the Thermochemical Network [3]". atct.anl.gov. Retrieved15 May 2023.
  5. ^Levanov, Alexander V.; Sakharov, Dmitri V.; Dashkova, Anna V.; Antipenko, Ewald E.; Lunin, Valeri V. (2011). "Synthesis of Hydrogen Polyoxides H2O4 and H2O3 and Their Characterization by Raman Spectroscopy".European Journal of Inorganic Chemistry.2011 (33):5144–5150.doi:10.1002/ejic.201100767.
  6. ^Möller, Detlev (19 February 2019).Fundamentals and Processes.Walter de Gruyter GmbH & Co KG. p. 276.ISBN 978-3-11-056126-5. Retrieved15 May 2023.
  7. ^Curutchet, Antton; Colinet, Pauline; Michel, Carine; Steinmann, Stephan N.; Le Bahers, Tangui (2020)."Two-sites are better than one: revisiting the OER mechanism on CoOOH by DFT with electrode polarization"(PDF).Physical Chemistry Chemical Physics.22 (13):7031–7038.Bibcode:2020PCCP...22.7031C.doi:10.1039/D0CP00281J.PMID 32195492.S2CID 213191538. Retrieved15 May 2023.
Alkali metal
(Group 1) hydrides
Alkaline (Group 2)
earth hydrides
Monohydrides
Dihydrides
Group 13
hydrides
Boranes
Alanes
Gallanes
Indiganes
Thallanes
Nihonanes (predicted)
  • NhH
  • NhH3
  • Nh2H6
  • NhH5
Group 14 hydrides
Hydrocarbons
Silanes
Silenes
Silynes
Germanes
Stannanes
Plumbanes
Flerovanes (predicted)
  • FlH
  • FlH2
  • FlH4
Pnictogen
(Group 15) hydrides
Azanes
Azenes
Phosphanes
Phosphenes
Arsanes
Stibanes
Bismuthanes
Moscovanes
Hydrogen
chalcogenides
(Group 16 hydrides)
Polyoxidanes
Polysulfanes
Selanes
Tellanes
Polanes
Livermoranes
Hydrogen halides
(Group 17 hydrides)
  • HF
  • HCl
  • HBr
  • HI
  • HAt
  • HTs (predicted)
  • Transition
    metal hydrides
    Lanthanide hydrides
    Actinide hydrides
    Exotic matter hydrides
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