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Terphenyl

From Wikipedia, the free encyclopedia
para-Terphenyl
Skeletal formula of para-terphenyl
Skeletal formula of para-terphenyl
Ball-and-stick model of para-terphenyl
Ball-and-stick model of para-terphenyl
Names
Preferred IUPAC name
11,21:24,31-Terphenyl[1]
Other names
1,1′:4′,1″-Terphenyl[1]
p-Terphenyl
1,4-Diphenylbenzene
para-Diphenylbenzene
p-Diphenylbenzene
para-Triphenyl
p-Triphenyl
Identifiers
3D model (JSmol)
1908447
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard100.043.146Edit this at Wikidata
EC Number
  • 202-205-2
RTECS number
  • WZ6475000
UNII
  • InChI=1S/C18H14/c1-3-7-15(8-4-1)17-11-13-18(14-12-17)16-9-5-2-6-10-16/h1-14H ☒N
    Key: XJKSTNDFUHDPQJ-UHFFFAOYSA-N ☒N
  • (para): InChI=1/C18H14/c1-3-7-15(8-4-1)17-11-13-18(14-12-17)16-9-5-2-6-10-16/h1-14H
    Key: XJKSTNDFUHDPQJ-UHFFFAOYAJ
  • C1=CC=C(C=C1)C2=CC=C(C=C2)C3=CC=CC=C3
  • (para): c1ccc(cc1)c2ccc(cc2)c3ccccc3
Properties
C18H14
Molar mass230.310 g·mol−1
AppearanceWhite powder[2]
Density1.24 g/cm3
Melting point212 to 214 °C (414 to 417 °F; 485 to 487 K)[2]
212-213 °C[4]
Boiling point389 °C (732 °F; 662 K)[4]
Insoluble[2]
1.65[3]
Hazards
GHS labelling:
GHS07: Exclamation markGHS09: Environmental hazard
Warning
H315,H319,H335,H400
P261,P264,P271,P273,P280,P302+P352,P304+P340,P305+P351+P338,P312,P321,P332+P313,P337+P313,P362,P391,P403+P233,P405,P501
NFPA 704 (fire diamond)
Flash point207 °C (405 °F; 480 K)[4]
NIOSH (US health exposure limits):
PEL (Permissible)
C 9 mg/m3 (1 ppm)[5][6][7]
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Chemical compound

Terphenyls are a group ofaromatic hydrocarbons. Also known asdiphenylbenzenes ortriphenyls, they consist of a centralbenzene ring substituted with twophenyl groups. There are threesubstitution patterns:ortho-terphenyl,meta-terphenyl, andpara-terphenyl. Commercial grade terphenyl is generally a mixture of the threeisomers. This mixture is used in the production ofpolychlorinated terphenyls, which were formerly used as heat storage and transfer agents.[2]

Occurrence

[edit]

p-Terphenyl derivatives are found in various fungi and bacteria. One example isatromentin, a pigment found in some mushrooms. These naturalp-terphenyls are better described as diphenylquinones or diphenylhydroquinones. Some m-terphenyl compounds occur in plants.[8]

  • ortho-Terphenyl​​​
    ortho-Terphenyl
  • meta-Terphenyl​​​
    meta-Terphenyl
  • para-Terphenyl​​​
    para-Terphenyl

See also

[edit]

References

[edit]
  1. ^abNomenclature of Organic Chemistry : IUPAC Recommendations and Preferred Names 2013 (Blue Book). Cambridge:The Royal Society of Chemistry. 2014. p. 345.doi:10.1039/9781849733069-00130.ISBN 978-0-85404-182-4.
  2. ^abcdp-Terphenyl at chemicalland21.com
  3. ^"Organic molecular single crystals". cryos-beta.kharkov.ua.
  4. ^abcp-Terphenyl atSigma-Aldrich
  5. ^NIOSH Pocket Guide to Chemical Hazards."#0591".National Institute for Occupational Safety and Health (NIOSH).
  6. ^NIOSH Pocket Guide to Chemical Hazards."#0592".National Institute for Occupational Safety and Health (NIOSH).
  7. ^NIOSH Pocket Guide to Chemical Hazards."#0593".National Institute for Occupational Safety and Health (NIOSH).
  8. ^Liu, Ji-Kai (2006). "Natural Terphenyls: Developments since 1877".Chemical Reviews.106 (6):2209–2223.doi:10.1021/cr050248c.PMID 16771447.

External links

[edit]
Retrieved from "https://en.wikipedia.org/w/index.php?title=Terphenyl&oldid=1311746897"
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