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Tellurium tetrabromide

From Wikipedia, the free encyclopedia
Tellurium tetrabromide
Tellurium tetrabromide
Tellurium tetrabromide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.030.070Edit this at Wikidata
EC Number
  • 233-090-7
UNII
  • InChI=1S/Br4Te/c1-5(2,3)4
    Key: PTYIPBNVDTYPIO-UHFFFAOYSA-N
  • Br[Te](Br)(Br)Br
Properties
TeBr4
Molar mass447.22 g/mol
Appearanceyellow-orange crystals
Density4.3 g/cm3, solid
Melting point388 °C (730 °F; 661 K)[1]
Boiling pointdecomposes at 420 °C (788 °F; 693 K)
Structure
monoclinic
Hazards
GHS labelling:[2]
GHS05: CorrosiveGHS06: Toxic
Danger
H301,H314
P260,P264,P280,P301+P330+P331,P303+P361+P353,P304+P340,P305+P351+P338,P310,P321,P363,P405,P501
Related compounds
Otheranions
Tellurium tetrafluoride
Tellurium tetrachloride
Tellurium tetraiodide
Othercations
Selenium tetrabromide
Related compounds
Ditellurium bromide
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Tellurium tetrabromide (TeBr4) is aninorganicchemical compound. It has a similar tetrameric structure toTeCl4.[3] It can be made by reacting bromine and tellurium.[4] In the vapour TeBr4 dissociates:[3]

TeBr4TeBr2 + Br2

It is a conductor when molten, dissociating into the ions TeBr3+ and Br. When dissolved inbenzene andtoluene, TeBr4 is present as the unionized tetramer Te4Br16.[3] In solvents with donor properties such asacetonitrile, CH3CN ionic complexes are formed which make the solution conducting:

TeBr4 + 2CH3CN → (CH3CN)2TeBr3+ + Br

References

[edit]
  1. ^Thermochemical Data of Elements and Compounds, M. Binnewies, E. Milke, Wiley-VCH, 2002,ISBN 3-527-30524-6
  2. ^"C&L Inventory".echa.europa.eu.
  3. ^abcInorganic Chemistry,Egon Wiberg, Arnold Frederick Holleman Elsevier 2001ISBN 0-12-352651-5
  4. ^Greenwood, Norman N.; Earnshaw, Alan (1997).Chemistry of the Elements (2nd ed.).Butterworth-Heinemann.doi:10.1016/C2009-0-30414-6.ISBN 978-0-08-037941-8.
Br(−I)
Br(−I,I)
Br(I)
Br(II)
Br(I,V)
Br(III)
Br(IV)
Br(V)
Br(VII)


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