 | |
| Names | |
|---|---|
| IUPAC name Poly(Styrene-co-Maleic Anhydride) | |
| Other names SMA; XIRAN | |
| Identifiers | |
| ECHA InfoCard | 100.211.126 |
| EC Number |
|
| Properties | |
| (C8H8)n-(C4H2O3)m | |
| Molar mass | Variable |
| Appearance | crystal clear polymer |
| Density | 1.080 g/cm3 |
| Solubility | Soluble in alkaline solutions and polar organic solvents |
Refractive index (nD) | 1.577 |
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa). | |
Styrene maleic anhydride (SMA orSMAnh) is a syntheticpolymer that is built-up ofstyrene andmaleic anhydridemonomers. In onecopolymer, the monomers can be almost perfectly alternating.[1] but (random) copolymerisation with less than 50% maleic anhydride content is also possible.[2] The polymer is formed by aradical polymerization, using anorganic peroxide as the initiator. The main characteristics of SMA copolymer are its transparent appearance, high heat resistance, high dimensional stability, and the specific reactivity of the anhydride groups. The latter feature results in the solubility of SMA in alkaline (water-based) solutions and dispersion.
SMA is available in a broad range of molecular weights and maleic anhydride (MA) contents. In a typical combination of those two properties, SMA is available as a crystal clear granule that can be used in a wide variety of applications. SMA polymers with a highmolecular weight are widely used in engineering plastic applications, normally in the impact modified and optionalglass fibre filled variants. Alternatively, SMA is applied using its transparency in combination with other transparent materials likePMMA or the heat resistance to heat-boost other polymers materials likeABS orPVC. The solubility of SMA in alkaline solutions makes it suitable for various applications in the field of sizings (paper), binders, dispersants and coatings. The specific reactivity of SMA makes it a suitable agent for compatibilizing normally incompatible polymers (e.g. ABS/PA blends) or cross-linking.
There are only a few commercial suppliers of SMA polymers. The three major producers are Solenis (Scripset), Aurorium (Xiran), Sartomer (SMA).Nova Chemicals (Dylark) is no longer produced. While the Sartomer product range covers low molecular weight products with high MA contents (and sometimes chemically modified), the Nova materials are high molecular products with low MA content (and mainly impact modified). Aurorium's Xiran product range covers the full spectrum of SMA polymers, including chemically modified types. Each of those products have their own specific features.
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