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Sorbose

From Wikipedia, the free encyclopedia
Sorbose
Names
IUPAC name
L-xylo-Hex-2-ulose
Systematic IUPAC name
(3S,4R,5S)-1,3,4,5,6-Pentahydroxyhexan-2-one
Other names
Sorbinose
L-xylo-Hexulose
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.001.611Edit this at Wikidata
UNII
  • InChI=1S/C6H12O6/c7-1-3(9)5(11)6(12)4(10)2-8/h3,5-9,11-12H,1-2H2/t3-,5+,6+/m0/s1 ☒N
    Key: BJHIKXHVCXFQLS-OTWZMJIISA-N ☒N
  • InChI=1/C6H12O6/c7-1-3(9)5(11)6(12)4(10)2-8/h3,5-9,11-12H,1-2H2/t3-,5+,6+/m0/s1
    Key: BJHIKXHVCXFQLS-OTWZMJIIBK
  • C([C@@H]([C@H]([C@@H](C(=O)CO)O)O)O)O
Properties[1]
C6H12O6
Molar mass180.156 g·mol−1
Appearancewhite solid
Density1.65 g/cm3 (15 °C)
Melting point165 °C (329 °F; 438 K)
Highly Soluble
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound

Sorbose is aketose belonging to the group ofsugars known asmonosaccharides. It has a sweetness that is equivalent tosucrose (table sugar).[1] The commercial production ofvitamin C (ascorbic acid) often begins with sorbose.L-Sorbose is the configuration of the naturally occurring sugar. It can be prepared from inexpensive O-benzylglucose.

Synthesis

[edit]

Under conditions employed for aMeerwein-Ponndorf-Verley reduction, the tetra-O-benzyl aldose converts to tetra-O-benzylsorbose.Hydrogenolysis removes the fourbenzyl groups, leaving sorbose.[2]

References

[edit]
  1. ^abMerck Index, 12th Edition,8874
  2. ^Frihed, Tobias Gylling; Bols, Mikael; Pedersen, Christian Marcus (2015). "Synthesis of l-Hexoses".Chemical Reviews.115 (9):3615–3676.doi:10.1021/acs.chemrev.5b00104.PMID 25893557.
General
Geometry
Monosaccharides
Dioses
Trioses
Tetroses
Pentoses
Hexoses
Heptoses
Above 7
Multiple
Disaccharides
Trisaccharides
Tetrasaccharides
Other
oligosaccharides
Polysaccharides
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