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Selenophosphate

From Wikipedia, the free encyclopedia
Class of chemical compounds

Aselenophosphate is a chemical compound containingphosphateanions substituted withselenium. Over 7000 compounds are known with a bond between selenium and phosphorus. Compared to phosphorus-sulfur compounds selenophosphates are less thermally stable, and more easily destroyed by water. However they are more stable than tellurophosphates which have an even weaker phosphorus-tellurium bond.[1] Selenophosphates have an oxidation number for phosphorus of +5. But in many there are bonds between phosphorus atoms, reducing the oxidation state to +4, Some may be termed selenophosphites.[2]


Different structural anions include hexaselenohypodiphosphate [P2Se6]4− and [P6Se12]4− with decalin structure and [P4Se2]2− with dicyclobutane structure.[1]

Selenophosphates are coloured, often orange. They are semiconductors.

The first selenodiphosphate was discovered in 1973 by H. Hahn.[3]

Selenophosphate compounds may have some or all of the selenium replaced by sulfur.[4]

Formation

[edit]

Selenophosphates can be produced by meltingphosphorus selenide with metalselenides.

Molecular biology

[edit]

Selenocysteine is produced in many organisms from a selenophosphate. In humans and othereucaryotes, this is facilitated by the enzymeselenophosphate synthetase 1. Selenium is connected to phosphorus using a reaction with selenide andadenosine triphosphate[5]

List

[edit]
formulanamemwcrystal systemspace groupunit cell Åvolumedensitycommentsreferences
[(py2Li)]4[P2Se6]·2pywater stable[6]
(NH4)4(P2Se6)(H2O)2triclinicP1a=7.3306b=7.3761c=9.5501α =70.405°β =74.109°γ =60.681° Z=1420.372.544[7]
[pyH]4[P2Se6]·H2Owater stable[6]
(NBu4)2P2Se8bis(Tetrabutylammonium) 3,6-diselenoxo-1,2,4,5-tetraselena-3,6-diphosphacyclohexane 3,6-diselenide acetonitrile solvatemonoclinicP21/ca 9.6284b 16.9553c 16.0899β 96.875°chair config[8]
(NBu4)3P9Se14orange-red[9]
bis(1-Butyl-3-methylimidazolium) 3,6-diselenoxo-1,2,4,5-tetraselena-3,6-diphosphacyclohexane 3,6-diselenidemonoclinicP21/na =7.6642b =10.9948c =17.0380β =91.211°chair config[8]
bis(tetrakis(Acetonitrile-N)-lithium) 3,6-diselenoxo-1,2,4,5-tetraselena-3,6-diphosphacyclohexane 3,6-diselenideorthorhombicPbama 20.0535(6)Åb 12.1200(5)Åc 15.0831cradle config[8]
bis((Tetrapyridine)-lithium) 3,6-diselenoxo-1,2,4,5-tetraselena-3,6-diphosphacyclohexane 3,6-diselenidetriclinicP1a 10.1582b 10.7716c 12.750α 95.271°β 94.847°γ 114.219°cradle config[8]
Na2P4Se2red-brown; P4 bicyclo structure[10]
Na3PSe4cubicI43ma=7.3094 Z=23.53Na ion conductor 1 mS cm−1[11]
Na4P2Se6orthorhombicCmcaa = 11.836b = 13.311c = 8.061Z = 41270.03.283[12]
Na4(P2Se6)(H2O)6monoclinicP21/ca 26.0636b 7.2350c 20.7197β 113.387° Z=83586.132.726[7]
Mg2P2Se6R3a = 6.404c = 20.194 Z=3[13]
KPSe6orthorhombicPca21a = 11.49 b = 6.791 c = 11.29Z = 4orange; NLOχ(2)≈142.8 pm V−1; band gap 2.1 eV[14][15][16][17]
K4Sc2(PSe4)2(P2Se6)monoclinicC2/ca=22.668Åb=6.8147Åc=19.828β=113.91°[18]
K2P2Se6trigonalP3121a = 7.2728,c = 18.872Z = 3at 298 K; SHG 50× AgGaSe2[19]
K2P2Se6trigonalP3121a = 14.4916c = 18.7999Z = 12at 173 K[19]
K3PSe4·2Se6cubicFd3a = 16.415at 193 K[20]
K4(P2Se6)(H2O)4orthorhombicCmcaa =11.921b =12.46c =11.752 Z=41745.62.908[7]
K6P8Se181903.66monoclinicP21/na=9.746 b=8.332 c=23.054β=90.54° Z=21872.13.377orange[21]
Ca2P2Se6monoclinicP21/na = 9.664b = 7.519c = 6.859 β = 92.02°[22]
K4Sc2(PSe4)2(P2Se6)737.82monoclinicC2/ca=22.668 b=6.815 c=19.828 β =113.91° Z=82800.23.500orange-yellow; turns red in air; band gap 2.25 eV[18]
KTiPSe5[23]
K4Ti2(P2Se9)2(P2Se7)black[23]
Cr2P2Se6[24]
LiCrP2Se6[25]
MnPSe3trigonalR3band gap 2.5 eV[26][27]
K2MnP2Se6monoclinicP21/na=6.5349 b=12.696 c=7.589 β=102.67° Z=2614.3[28]
FePSe3[26]
Fe2P2Se6trigonalR3band gap 1.3 eV[13][27]
K2FeP2Se6monoclinicP21/na=6.421 b=12.720 c=7.535β=102.58 Z=2600.7red[28]
CuP2Se2D semiconductor; metallises under pressure[29]
m-Cu4P2Se6monoclinicP21/ca 6.370b 11.780c 20.013β 90.03°[30]
Cu3PSe4orthorhombicPmn21a=7.700 b=6.677 c=6.385328.3[31]
t-Cu4P2Se6triclinicP1a 7.104b 11.889c 12.759α 74.35°β 79.63°γ 80.85°[30]
Cu4P3Se4triclinicP1a 6.440b 7.085c 10.616α 73.11°β 74.86°γ 77.00°[30]
Cu4P4Se3monoclinicP21/ca 16.446b 6.515c 17.339β 119.08°[30]
CuP2SeorthorhombicPbcaa 5.608b 6.496c 16.570[30]
CuAl[P2Se6]trigonalR3a = 6.2795 c = 19.9713 Z =3[32]
K2Cu2P4Se101118.78monoclinicP21/na=10.627 b=7.767 c=11.966β=109.125° Z=2933.23.981red[33]
K3Cu3P3Se9monoclinicP21/ca = 8.741 b = 10.774, c = 20.033, β = 92.96°[34][35]
[Cu12(P2Se6){Se2P(OEt)2}8]Et=Ethyl; diethyl diselenophosphate hexaselenodiphosphate(IV)[36]
[Cu12(P2Se6){Se2P(OiPr)2}8]iPr=isopropyl[36]
CuCr[P2Se6]monoclinicC2/ma=6.193b=10.724c=6.909β=107.2°Z=2690.24.9melt 730 °C; dark red[3]
Zn2P2Se6R3a = 6.290c = 19.93 Z=3[13]
K2ZnP2Se6monoclinicP21/ca = 12.537b = 7.274c = 14.164β = 109.63°Z = 41216yellow[37][38]
LiGaP2Se6trigonalP31ca = 6.2993c = 13.308red; melt 458 °C; band gap 2.01 eV; water and air stable[25][39]
K4GeP4Se12orthorhombicPca21a=13.9465b=7.2435c=24.0511[40]
K4Ge4-xPxSe12monoclinicP21/ca = 6.7388b = 13.489c = 6.3904 β = 91.025°[41]
K7As3(P2Se6)4monoclinicP21/ca=25.0706b=9.5948c=59.6227β=93.384°melt 388 °C[42]
K6As2(P2Se6)3monoclinicP21/ca 8.0898b 23.3142c 12.1919β 124.809°melt 410 °C; orange; band gap 2.2 eV[42]
RbPSe6orthorhombicPca21a = 11.776b = 6.858c = 11.460Z = 4NLOχ(2)≈150 pm V−1[15][16]
Rb2P2Se6trigonalP3121a = 7.2982c = 19.002 andZ = 3100 K[19]
Rb4P2Se9monoclinicC2/ca = 9.725b = 10.468c = 19.155β = 93.627°Z = 41946.13.804[12]
Rb4P6Se12orthorhombicPca21a =16.409b =10.64c =15.105bicyclic with >PP< bridge and -SePSe2PSe2Se- ring[43]
Rb10P4Se25[44]
Rb4(P2Se6)(H2O)4orthorhombicPnnma 9.834b 12.456c 7.585 Z=2929.13.395[7]
RbTiPSe5[23]
Rb4Ti2(P2Se9)2(P2Se7)orthorhombicFdd2a=35.55 b=37.315 c=6.574 Z=487723.956black[23][45]
Rb2MnP2Se6[28]
Rb2ZnP2Se6triclinicP1a = 7.494b = 7.601c = 12.729α = 96.57°β = 105.52°γ = 110.54°Z = 2636.6[38]
Rb4GeP4Se12orthorhombicPca21a=14.1881b=7.3566c=24.2914[40]
Rb6Ge2P2Se14triclinicP1a = 7.2463b = 9.707c = 11.987 α = 79.516° β = 89.524° γ = 68.281°band gap 2.2 eV[41]
Sr2P2Se6monoclinicP21/na = 9.844b = 7.788c = 6.963 β = 91.50° Z=2[22]
NaYP2Se6647.6triclinicP1a=6.9456 b=7.4085 c=9.5306 α=88.819° β=87.748° γ=89.580° Z=2yellow[46][47] follow up refs
KYP2Se6orthorhombicP212121a = 6.7366b = 7.4286c = 21.603Z = 4[46][48]
[(Cp′′2Zr)2(μ,η1:1:1:1-P2Se4)]Cp′′ = C5H3tBu21269.41monoclinicP21/na=15.2831 b=9.91947 c=18.6250β=102.835° Z=227531.531dark purple[49]
KZrPSe6orthorhombicPmc21a=3.7079b=15.074c=18.491[50]
RbZrPSe6[50]
KNb2PSe10monoclinicPca=7.2931b=15.612c=13.557β=106.64°resistivity 4.5 Ω·cm[51]
RbNb2PSe10monoclinicPca=7.381b=7.8359c=13.564β=106.75°[51]
K3RuP5Se10monoclinicP21/ma 11.2099b 7.2868c 12.3474β 93.958°[52]
PdPSesemiconductor[53]
K2PdP2Se6[23]
Rb2PdP2Se6[23]
Ag4P2Se61013.69orthorhombicP212121a=6.5760 b=11.5819 c=14.137 Z=41076.85.966melt 642 °C; dark red[54]
AgAl[P2Se6]monoclinicC2/ma=6.348b=10.989c=7.028β=107.2°Z=2melt 588 °C; yellow[3]
K2Ag2P2Se6monoclinicP21/ca=8.528 b=11.251 c=20.975β=93.24° Z=42009orange[28]
AgCrP2Se6monoclinicC2/ma=6.305b=10.917;c=6.991β=107.7°Z=2melt 720 °C; dark red[3]
AgCrP2Se6P3112a=6.3257 c=20.0198layered; antiferromagnetic <42K; band gap 1.240 eV[55]
AgGa[P2Se6]orthorhombicPbcaα=12.169b=22.484c=7.473Z=42044.7melt 450 °C; orange[3]
AgGa[P2Se6]trigonalP31/ca=6.375c=13.320Z=2468.815.05dark red[3]
AgScP2Se6688.54trigonalP31/ca=6.463 c=13.249 Z=2482.934.735orange or brown[56]
CdPSe3[26]
K2CdP2Se6monoclinicP21/ndark yellow[37]
Rb2CdP2Se6819.05monoclinicP21/na=6.640b=12.729c=7.778β=98.24°Z=2650.54.180dark yellow; air stable[37]
Rb8Cd4(Se2)(PSe4)4[23]
InPSe3[26]
In2(P3Se9)monoclinicP21/n[34]
LiInP2Se6657.46trigonalP31/ca=6.397 c=13.350 Z=2473.154.615band gap 2.06 eV[57]
(Ph4P)[In(P2Se6)]monoclinicC2/ca = 23.127b = 6.564c = 19.083 β = 97.42°Z = 42873@23 °C yellow[58]
KInP2Se6monoclinicP21/na=7.511b=6.4861c=22.789β=98.91°Z=41096.9[59]
K5In3(μ3-Se)(P2Se6)3triclinicP1a 7.6603b 13.1854c 18.378α 87.04°β 88.659°γ 82.025°[60]
K4In4(μ-Se)2(P2Se6)3monoclinicP21/ca 19.707b 7.712c 13.229α 90°β 106.42°[60]
K4In2(PSe5)2(P2Se6)monoclinicCca=11.1564b=22.8771c=12.6525β=109.039°Z=4brick-red; air stable[61]
K4In4(μ-Se)(P2S2.36Se3.64)3triclinicP1a 7.7709b 13.0007c 18.9382α 105.382°β 92.632°γ 91.91°[60]
CuInP2Se6trigonalP31/ca=6.392c=13.338Z=2472.05.0melt 642 °C; dark red; phase transitions at 5.4 and 14.1 GPa; metallised at 25.1 GPa[3][62]
AgInP2Se6trigonalP31/ca=6.483c=13.330Z=2485.25.2semiconductor; melt 673 °C; dark red; band gap 1.79 eV[63][3]
SnP2Se6R3a = 6.3213 c = 19.962band gap 1.36–1.41 eV[64]
Sn2P2Se6[65]
Na11.1Sn2.1P0.9Se12tetragonalI41/acda=14.2446 c=28.473 Z=85777.43.403Na+ ion conductivity 3.0 mS/cm[66]
Rb3Sn(PSe5)(P2Se6)monoclinicP21/aa=14.013b=7.3436c=21.983β=106.61°Z=4black[61]
K10Sn3(P2Se6)4trigonalR3a = 24.1184c = 7.6482@100K; band gap 1.82 eV[67]
Rb4Sn5P4Se202638.41trigonalP3m1a=7.6163 c=18.6898 Z=1938.914.64black[68]
Rb4Sn2Ag4(P2Se6)2monoclinicP21/na=11.189 b=7.688 c=21.850β=94.31° Z=21874.24.639black[23][69]
Rb5[Sn(PSe5)3]triclinicP1a 11.745b 19.23c 7.278α 99.97°β 107.03°γ 87.16°[70]
Sb4(P2Se6)3monoclinicP21/na = 20.777 b = 7.4935 c = 9.4949 β = 91.25°[71]
KSbP2Se6696.55[34]
β-KSbP2Se6696.55monoclinicP21a=6.8925 b=7.8523 c=10.166β=91.487 Z=2550.44.203dark red[72]
AgSbP2Se6hygroscopic[73]
α-CsPSe6monoclinicP21/na = 6.877b = 12.713c = 11.242 β = 92.735°Z = 4orange[14][15]
β-CsPSe6637.64tetragonalP421ca = 12.526c = 12.781Z = 82005.34.224red orange; metastable; SHG χ(2) ~30 pm/V[14]
Cs2P2Se8orthorhombicCccea = 14.982b = 24.579c = 13.065band gap 2.44 ± 0.2 eV; P2Se4 ring; third harmonic generator coefficient 2.4 ± 0.1 × 105 pm2/V2[74]
Cs3PSe4orthorhombicPnmaa = 10.0146b = 11.990c = 9.9286Z = 41192.24.154[12]
Cs4P2Se9[23]
Cs4P2Se10triclinicP1a=7.359b=7.455c=10.142α=85.938°,β=88.055°γ=85.609°[P2Se10]4−[75]
Cs4[P6Se12]1664.98monoclinicP21/na =10.836b =10.5437c =12.273β =98.661°1386.33.989orange; melt 697; NLO[76]
Cs5[P5Se12]1766.92tetragonalP4a =13.968c =7.546 Z=21472.23.986orange; NLO; band gap 2.17 eV[76][77]
Cs10P8Se20orthorhombicPnnma = 26.5456b = 8.0254c = 11.9031Z = 22535.84.133(PSe2)3Se rings and P2Se6[78]
Cs4(P2Se6)(H2O)4orthorhombicPnnma=10.0514b=12.6867c=7.8403 Z=2999.83.775[7]
K0.6Cs0.4PSe6orthorhombicPca21a=11.830 b=6.908 c=11.516 Z=4941.14.085orange; band gap 2.1 eV; SHG χ(2) ~150 pm/V[14]
KCsP2Se8orthorhombicCccea = 14.782b = 23.954c = 13.044band gap 2.36 ± 0.2 eV[74]
Cs2MnP2Se6monoclinicP21/n6.4761 b=13.006 c=7.974β=93.09° Z=2670.6[28]
Cs2FeP2Se6[28]
Cs2Cu2P2Se6monoclinicP21/ca=9.958 b=13.067 c=10.720β=102.46° Z=41363dark green[28]
Cs2ZnP2Se6triclinicP1a = 7.6543b = 7.7006c = 12.737α = 97.007°β = 104.335°γ = 109.241°Z = 2669.5yellow; band gap 2.67 eV[38][77]
Cs4GeP4Se12orthorhombicPca21a=14.3268b=7.6202c=24.6301[40]
Cs6As2(P2Se6)3monoclinicP21/ca=19.5759b=7.9206c=13.0553β=101.914°orange band gap 2.1 eV[42]
Cs5As(P2Se6)2tetragonalP42/ma=13.826c=7.5173melt 416 °C; red; band gap 2.0 eV[42]
RbCsP2Se8orthorhombicCcceband gap 2.41 ± 0.2 eV[74]
CsZrPSe6band gap 2.0 eV[77][50]
CsNb2PSe10monoclinicPca=14.6257b=7.8097c=13.5533β=98.557°[51]
Cs4Pd(PSe4)2monoclinicP21/ca = 7.491b = 13.340c = 10.030 β = 92.21°Z = 2red[79]
Cs10Pd(PSe4)4tetragonalP42ca = 13.949c = 11.527Z = 4red[79]
Cs2PdP2Se6tetragonalP42/mnma = 8.5337c = 10.5595Z = 4black[79]
Cs2Ag2P2Se6monoclinicP21/na=6.807 b=12.517 c=8.462β=95.75° Z=2717.3yellow[28]
Cs2CdP2Se6monoclinicP21/nyellow[37]
Cs5In(P2Se6)2tetragonalP42/ma = 13.886c = 7.597Z = 21464.9@23 °C; dark orange[58]
Cs4Sn(P2Se6)21721.73trigonalR3a=7.808 c=37.905 Z=32001.44.285black[80]
α-Cs2SnP2Se6920.2monoclinicP21/ca=10.230 b =12.990 c=10.949 β=94.529°1450.54.2126orange[80]
Cs2SnP2Se6monoclinicP21/ca = 10.1160b = 12.7867c = 11.0828 β = 94.463°@100K[67]
Cs4(Sn3Se8)[Sn(P2Se6)]22828.17tyrigonalP3m1a=7.695 c=18.797 Z=1964.04.872black; 2D[80]
Cs6[Sn2Se4(PSe5)2]triclinicP1a 9.899b 12.416c 7.497α 91.62°β 110.19°γ 79.94°[70]
CuSbP2Se6C2/m[81]
AgSbP2Se6C2/m[81]
Cs8Sb4(P2Se6)5[34]
Ba2P2Se6monoclinicP21/na = 10.355b = 7.862c = 7.046 β = 90.83° Z=2[22]
Ba3(PSe4)2monoclinicP21/aa = 12.282b = 6.906c = 18.061β = 90.23°Z = 4[82][83]
Ba3PO4PSe4triclinicP1a=6.779 b=7.108 c=12.727 α=82.45 β=78.88 γ=81.34 Z=2orange[82]
KBaPSe4orthorhombicPnmaa=11.972 b=6.973 c=10.388 Z=4pale orange[82]
KLaP2Se6713.71monoclinicP21/ca=12.425 b=7.8047 c=11.9279 β=109.612°1089.64.351yellow[34]
K2La(P2Se6)1/2(PSe4)monoclinicP21/na = 9.4269b = 7.2054c = 21.0276 β = 97.484°Z = 4[84]
K3La(PSe4)2monoclinicP21/ca = 9.5782b = 17.6623c = 9.9869 β = 90.120°Z = 4[84]
K3LaP2Se8[85]
K4La0.67(PSe4)2orthorhombicIbama = 19.0962b = 9.1408c = 10.2588Z = 4[84]
K6LaP4Se16
K8.5La1+1/3(PSe4)4orthorhombicCccaa = 18.2133b = 38.0914c = 10.2665Z = 8[84]
Ce4(P2Se6)3722.06monoclinicP21/ca = 6.8057b = 22.969c = 11.7226 β = 124.096°Z = 64.741orange[86]
NaCeP2Se6monoclinicP21/ca = 12.1422b = 7.6982c = 11.7399 β = 111.545° Z=4yellow[86]
KCeP2Se6monoclinicP21/c[46]
Cu0.4Ce1.2P2Se6monoclinicP21/ca = 12.040b = 7.6418c = 11.700 β = 111.269° Z = 4yellow[86]
Rb2CeP2Se7monoclinicP21/nred; air sensitive[87]
Rb3CeP2Se81090.13monoclinicP21/ca = 9.6013b = 18.0604c = 10.0931 β = 90.619°Z = 41750.074.137orange; air sensitive[87]
Rb9Ce(PSe4)4monoclinicC2/ca=21.446 b=10.575 c=18.784 β =115.94° Z=438313.980orange; air and water destroyed; soluble in 18-crown-6 + dmf; band gap 2.26 eV[44]
AgCeP2Se6monoclinicP21/ca = 9.971b = 7.482c = 11.757 β = 145.630° Z=2orange[86]
CsCe[P2Se6]monoclinicP21/ca = 12.9786b = 7.7624c = 11.9843β = 106.589°Z = 4[88]
KPrP2Se6monoclinicP21/c[46]
Cs2PrP2Se7monoclinicP21/na=10.2118 b=7.2423 c=20.3741 β =98.624° Z=4[89]
Eu2P2Se6monoclinicP21/na = 9.779b = 7.793c = 6.957 β = 91.29° Z=2[22]
LiEuPSe4orthorhombicAma2a = 10.5592b = 10.415c = 6.4924Z = 4red; air unstable[90]
Na8Eu2(Si2Se6)2monoclinicC2/ma=7.090b=12.228c=7.950β=107.427°Z = 1657.6[91]
KEuPSe4monoclinicP21/ma = 6.8469b = 6.9521c = 9.0436 β = 107.677°Z = 2red; air unstable[90]
KEuPSe4orthorhombicPnmaa = 17.516b = 7.0126c = 6.9015Z = 4[84]
K4Eu(PSe4)2orthorhombicIbama = 19.020b = 9.131c = 10.198Z = 4[34][92]
Cs3GdP2Se8monoclinicP21/c[87]
NaSmP2Se6709.94triclinicP1a 6.8368b 7.5312c 9.557α 90.799°β 91.910°γ 90.351° Z=2red[46]
Na9Sm(Ge2Se6)2monoclinicC2/ma = 7.916b = 12.244c = 7.105β = 106.99°Z = 1658.6[91]
KSmP2Se6725.15monoclinicP21a=6.7888 b=7.6185 c=10.1962β=91.508 Z=2527.174.568red[93]
CsSmP2Se6orthorhombicP212121a = 6.8867b = 7.5448c = 22.152Z = 4[46][88]
NaGdP2Se6715.94triclinicP1a 6.8464b 7.4916c 9.5372α 90.813°β 92.026°γ 90.241° Z=2yellow[46]
KGdP2Se6monoclinicP21a=6.7802 b=7.5809 c=10.1967β=91.638 Z=2523.974.640yellow[46][93]
Rb2GdP2Se71037.73monoclinicP21/na = 10.137b = 7.212c = 20.299 β = 98.23°Z = 41468.84.692orange; air sensitive[87]
NaTbP2Se6717.61triclinicP1a 6.8854b 7.4580c 9.5196α 89.068°β 87.899°γ 89.974° Z=2yellow[46]
KTbP2Se6monoclinicP21a=6.7609 b=7.5570 c=10.2158β=91.732 Z=2521.714.671yellow[46][93]
KTbP2Se6orthorhombicred over 9.2 GPa[94]
NaDyP2Se6721.19triclinicP1a 6.9114b 7.4258c 9.5256α 88.914°β 87.829°γ 89.695° Z=2yellow[46]
CsEr[P2Se6]monoclinicP21/ca = 7.5381b = 12.8192c = 12.7647β = 106.898°Z = 4[88]
AgErP2Se6810.83trigonalP31/ca=6.578 c=13.410 Z=2502.65.358dark brown[56]
AgTmP2Se6812.50trigonalP31/ca=6.567 c=13.422 Z=2501.275.383dark brown[56]
K3AuP2Se8monoclinicCca = 7.122b = 12.527c = 18.666 β = 96.06°Z = 4[95]
Rb3AuP2Se8monoclinicCc[95]
Cs3AuP2Se8monoclinicCc[95]
K2Au2P2Se6monoclinicC2/ma = 12.289b = 7.210c = 8.107 β = 115.13°Z = 2black[95]
Rb2Au2P2Se6monoclinicC2/m[95]
Rb2Au2P2Se6monoclinicP21/na=11.961 b=10.069 c=32.137β=91.37° Z=1238694.653@-120 °C black[96]
Hg2P2Se6[34][97]
K2HgP2Se6monoclinicP21/ca=13.031b=7.308c=14.167β=110.63°Z=41262.64.285dark yellow[37]
Rb2HgP2Se6monoclinicP21/cdrak yellow[37]
Rb8Hg4(Se2)(PSe4)4P42/na=17.654c=7.226[23][98]
Tl4P2Se6trigonalR3a=6.3808 c= 20.014melt 963 K[34][99]
TlInP2Se6triclinicP1a=6.4488 b=7.5420 c=12.166α=100.72°β=93.63°γ=113.32°melt 875K[100][99]
TlSbP2Se6monoclinicP21a = 6.843 b = 7.841 c = 9.985 β = 90.77° Z = 2melt 720K; band gap 1.75 eV[101]
Pb2P2Se6monoclinicPna = 9.742 b = 7.662 c = 6.898 β=91.44° Z=2514.736.13melt 812 °C;band gap 1.88 eV;photoconductor[34][102][103]
Na1.5Pb0.75PSe4cubicI43da=14.3479Z=16band gap 2 eV[104]
RbPbPSe4red water stable[92]
Rb4Pb(PSe4)2orthorhombicIbama = 19.134b = 9.369c = 10.488Z = 4orange water unstable[92]
CsPbPSe4orthorhombicPnmaa = 18.607b = 7.096c = 6.612Z = 4red water stable[92]
Cs4Pb(PSe4)2orange water unstable[92]
Bi4(P2Se6)3monoclinicP21/na = 20.869 b = 7.4745 c = 9.5923 β = 91.73°[71]
β-Bi4(P2Se6)3triclinicP1a = 12.2303b = 6.7640c = 17.866 α = 90.493° β = 94.133° γ = 91.163°black[105]
KBiP2Se6783.78monoclinicP21a 6.9183b 7.663c 10.239β 91.508° Z=2542.64.797[34][72]
CuBiP2Se6R3a = 6.553c = 39.76lamellar; p-type semiconductor; work function 5.26 eV[106][107]
AgBiP2Se6R3a = 6.652c = 39.61lamellar[106]
Cs5BiP4Se12orthorhombicPmc21a = 7.5357b = 13.7783c = 28.0807Z = 4band gap 1.85 eV; melt 590 °C[108]
α-TlBiP2Se6monoclinicP2l/ca =12.539b =7.499c =12.248β =113.731°chains; band gap 1.23,1eV[109]
β-TlBiP2Se6monoclinicP2l/ca =12.25b =7.5518c =22.834β =97.65°melt 544 °C; layers; band gap 1.27 eV[109]
K2ThP3Se9triclinicP1a = 10.4582b = 16.5384c = 10.2245α = 107.637 β = 91.652γ = 90.343°Z = 2[110]
β-K2ThP3Se9monoclinicP21/na = 10.2697 b = 7.7765 c = 20.472 β = 92.877° Z = 4yellow[111]
Rb2ThP3Se9triclinicP1a = 10.5369b = 16.6914,c = 10.2864 α = 107.614° β = 92.059° γ = 90.409°Z = 2[110]
Rb7Th2P6Se21triclinicP1a = 11.531b = 12.359c = 16.161 α = 87.289° β = 75.903° γ = 88.041°Z = 2red; band gap 2.0 eV[112]
Cs4Th4P4Se26orthorhombicPbcaa = 12.0130b = 14.5747c = 27.134Z = 8orange; (P2Se9)6- anion[113]
Cs4Th2P5Se17monoclinicP2l/ca = 10.238b = 32.182c = 10.749 β = 95.832°Z = 4[110]
K2UP3Se9triclinicP1a = 10.407( b = 16.491 c = 10.143 α= 107.51° β = 91.74° γ = 90.28° Z = 4black[23][114]
Rb4U2P5Se17triclinicP1a =10.0824b = 10.6905c = 15.7845α = 84.678β = 76.125γ = 85.874°@100K[115]
Rb4U4P4Se263470.84orthorhombicPbcaa=11.9779 b=14.4874 c=27.1377 Z=44709.174.895U5+[116]
Cs2U2(P2Se9)(Se2)2orthorhombicPbcaa 11.769b 14.389c 26.537black[117]


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Salts and covalent derivatives of theselenide ion
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