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Selenidogermanate

From Wikipedia, the free encyclopedia
Type of chemical compound

Selenidogermanates are compounds withanions withselenium bound togermanium. They are analogous withgermanates,thiogermanates, andtelluridogermanates.[1]

List

[edit]
nameformulaformula weightcrystal

system

space

group

cell dimensionsvolumedensitycommentref
GeSe2[2]
Ge4Se9orthorhombicPca21a 17.8204b 7.0029c 12.0854[2]
Li3Ge3Se6triclinicP1a 6.7728b 8.6804c 10.6300α 74.519°β 76.334°γ 69.185°[3]
[Li4(H2O)16][Ge4Se10]·4.33H2OmonoclinicP21a=10.2246b=20.4503c=28.7242β=97.850°[4]
{Li4(thf)12}Ge4Se10monoclinicC2/ca=24.845b =12.692c=25.625β=119.00°[4]
[Li2(H2O)8][MnGe4Se10]tetragonalI4a=9.103c =15.130[4]
[NH4]2[H2N(CH3)2]2Ge2Se6monoclinicP21/na 13.503b 7.777c 19.583β 106.03°[5]
(N2H5)4Ge2Se6tetragonalI41cda = 12.708c = 21.955Z = 8[6]
[NEt4]2[enH]2[Ge2Se6]triclinicP1a = 7.805,b = 10.747,c = 11.445, α = 110.33°, β = 97.19°, γ = 92.62°V =889.0[7]
tetrakis(Tripropylammonium) hexakis(μ2-selenido)-tetrakis(selenoxo)-tetra-germanium(iv)monoclinicP21/ca 18.759b 16.104c 21.211β 108.52°[8]
(C2C1Im)4[Ge4Se10]1524.63tetragonalP42/na=13.675 c=12.042 Z=22251.92.249yellowish[1]
1-Ethyl-3-methyl-imidazolium(C2C1Im)6[Ge8Se19];2747.96triclinicP1a=10.2607 b=17.6852 c=21.994 α=100.889

β= 95.600  γ=105.240 Z=2

3735.52.443yellowish[1]
(C2C1Im)6[Ge8Se19]2747.96monoclinicP121/c1a=22.206 b=9.544 c=36.823 β=105.37 Z=47524.82.426yellow[1]
(C2C1Im)8[Ge16Se36]4893.34monoclinicC12/c1a=20.527 b=28.744 c=19.720 β=94.640 Z=4115972.803yellow[1]
2(C2C1Im)6[Ge12Se27]7340.01monoclinicP121/n1a=14.834 b=30.647 c=20.465 β=107.603 Z=288682.749red[1]
(C4C1im)+2{[SnII(GeIV4Se10)]2−}monoclinicP21/na 9.9685b 26.2588c 13.9736β 98.766°[9]
Na2GeSe3monoclinicP21/ca =7.097 b=16.068 c=6.073β =113.69° Z=43.72yellow[10]
Na4GeSe4orthorhombicPnmaa = 28.518 b=9.447 c=7.128 Z=8orange-yellow[11]
Na4[Ge4Se10]orthorhombicCmcma=13.507 b=13.363 c=11.034 Z=41881.6[12]
Na4Ge(Se2)4red[13]
Na6Ge2Se6monoclinicP21a = 8.367 b = 11.924 c = 8.158β = 118.6°[14]
Na6Ge2Se7monoclinicC2/ca=9.451 b=10.914 c=15.874β=104.7°3.51yellow[15][16]
Na8Ge4Se10triclinicP1a = 7.074 b = 8.098 c = 10.657α = 73.4°β = 70.8°γ= 81.7°[14]
Na8Ge4Se10monoclinicP21/ca = 13.104 b=12.057 c=14.101β= 92.9° Z=43.77orange yellow[10]
[Na4(H2O)14][GeSe4]monoclinicC2a = 12.862, b = 11.205, c = 8.141 Å, β = 107.40°[17]
Na4Ge2Se6 · 16 H2OmonoclinicP21/ca = 9.894 b = 11.781 c = 12.225 β = 92.90° Z = 2[18]
Na6Ge2Se6 · 4 CH3OH[19]
Na3GeSe3Br[20]
Mg2GeSe4437.05orthorhombicPnmaa 13.50b 7.85c 6.37 Z=46754.302yellow[21]
Li2MgGeSe4orthorhombicPmn21a = 8.2961 b = 7.0069 c = 6.6116, Z = 2384.333.686yellow[22]
Na4MgGe2Se6735.21monoclinicC2a 7.722b 11.994c 7.096β 106.66° Z=2629.73.878orange-yellow[23]
K2GeSe4monoclinicP21/ca=11.989 b=8.275 c=8.915β=106.38° Z=4848.83.65orange[24]
K2Ge4Se8monoclinicP21/ca=7.3752b=12.239c=17.468 β=96.102°,Z=41156.8band gap 1.8 eV[25]
K4[GeSe4]cubicP43na=13.1893[26]
[K4(H2O)4][GeSe4]triclinicP1a 7.8695b 7.9576c 12.314,α 80.24°β 87.66°γ 74.07°[26]
[K4(H2O)3][Ge2Se6]monoclinicP21/ca 14.583b 8.3858c 14.17β 96.27°[26]
[K4(H2O)3][Ge4Se10][1]
K6Ge2Se6monoclinicC2/ca=9.076 b=12.851 c=8.480β=116.76°[27]
[V(en)2(ea)]2[Ge2Se6]monoclinicP21/na 8.733b 13.432c 13.583β 91.486° Z=41592.82.256red[28]
[V(teta)(ea)]2[Ge2Se6]monoclinicP21/na 9.0574b 14.209c 13.1189°β 91.384° Z=41687.82.232red[28]
[V2(en)6(μ-O)][Ge2Se6]triclinicP1a 9.448b 10.178c 10.436α 109.090°β 104.169°γ 111.520° Z=1802.72.271brown[28]
Na2MnGe2Se61439.72tetragonalI4/mcma = 7.772c = 19.077Z = 21152.34.150@153K band gap 1.93 eV; brown[29]
Na8Mn2(Ge2Se6)2monoclinicC2a 7.727b 11.943c 7.085β 106.682°band gap 1.95 eV[30]
K2MnGe2Se6tetragonalI4/mcma =8.1315c =18.877[31]
[Mn(en)3]2Ge2Se6monoclinicP21/na 9.058b 16.319c 11.628β 92.264°[32]
(enH2)[{Mn(en)2(enH)}2(μ-en)](Ge2Se7)2orthorhombicPbcaa 15.816b 13.638c 24.677[33]
[Mn(dien)2]2Ge2Se7monoclinicP21/ca 16.489b 14.524c 15.860β 101.03°[33]
[{Mn(tepa)}2(μ-Ge2Se6)]tetragonalI 41/aa=26.387c 9.9435[34]
[K2(H2O)3][MnGe4Se10]tetragonalI4a=8.988c=15.49[35]
Bis(trimethylammonium) decaselenidotetragermanatomanganate(II)[(CH3)3NH]2[MnGe4Se10]tetragonalI4a 9.559c 14.808[36]
[Fe(dien)2]2Ge2Se6monoclinicP21/na 12.426b 9.312c 15.385β 101.422°[32]
[{Fe(tepa)}2(μ-Ge2Se6)]tetragonalI 41/aa 26.285c 9.882[34]
K2FeGe3Se8monoclinicP21a 7.409b 12.268c 34.974β 96.04°band gap 1.95 eV[37]
[Ni(dien)2]2Ge2Se5(Se2)monoclinicP21/ca 15.741b 14.463c 16.390β 103.03°[5]
[{Ni(tepa)}2(μ-Ge2Se6)]tetragonalI41/aa=26.001c=9.708[5]
triethylenetetramine[Ni(teta)2]2Ge4Se10·0.5H2OmonoclinicP21/ca 21.202b 13.345c 20.872β 107.46°[38]
(enH2)5[Cu16Ge6Se19(Se2)6]·encubicPa3a=a 20.8113 Z=12[39]
[(CH3)2NH2]6[Cu8Ge6Se19]·0.25H2OIm3a=22.43070[39]
[NH3CH3]0.75Cu1.25GeSe3tetragonalP421ma=12.9345c 8.9057[40]
decakis(1-ethyl-3-methyl-1H-imidazol-3-ium) hexakis(μ-cyanido)-nonatriacontakis(μ-selenido)-selenido-hepta-copper(i)-hexadeca-germanium(iv)-penta-sodium(C2C1Im)10[Na5(CN)6@Cu6(Ge4Se10)4(Cu)]triclinicP1a 19.2790b 20.4268c 23.2357α 105.275°β 93.657°γ 115.206° Z=27822.62.610red[41]
decakis(1-ethyl-3-methyl-1H-imidazol-3-ium) hexakis(μ-cyanido)-nonatriacontakis(μ-selenido)-selenido-hepta-copper(i)-hexadeca-germanium(iv)-penta-sodium(C2C1Im)10[Na5(CN)6@Cu6(Ge4Se10)4(Cu)]6147.36triclinicP1a 20.3454b 20.8202c 23.120α 72.172°β 68.184°γ 60.802° Z=27842.12.472red[41]
1,2-dap = 1,2-diaminopropane[Mn(1,2-dap)2][Cu2GeSe5]monoclinicP21/ca 6.673b 18.210c 15.070β 96.078°[42]
[Cu2GeSe5][Mn(Hen)2(en)]monoclinicP21/ca 9.6327b 20.6934c 10.3704β 100.646°band gap 1.69 eV[43]
tren =tris(2-aminoethyl)amine[Ni(tren)(en)]2∙[Cu2GeSe5]2orthorhombicP212121a 9.8574b 13.0311c 32.77[42]
[Ni(dien)2]2Ge2Se5(Se2)monoclinicP21/ca=15.741b=14.463c=16.390β=103.03(3)°[5]
{Ni(tepa)}2(μ-Ge2Se6)tetragonalI41/aa=26.001c=9.7079[5]
[NH3CH3]0.75Cu1.25GeSe3tetragonalP421ma 12.9345c 8.9057[40]
Na2ZnGe2Se6tetragonalI4/mcma 7.757c 18.734band gap 2.36 eV[44][45]
Cu2ZnGeSe4tetragonalI4band gap 1.38; air stable; SHG 43 pm/V at λ = 2900 nm[46]
Cu4ZnGe2Se7monoclinicC2a 12.3443b 5.6195c 8.7904β 98.693°band gap 0.91 eV; air stable[46]
N-(2-aminoethyl)piperazine(H2NC4H8NCH2CH2NH2)(HNCH2CH2NH2)3Zn2Ge2Se8orthorhombicP21212a=18.928b=30.849c=6.3954[47]
[NH4]2Ga4Se8Ge4monoclinicP21/c[48]
NaGaGe3Se8monoclinicP21/ca 7.233b 11.889c 17.550β 101.75° Z=41477.54.235orange[49]
K2Ga2Ge2Se8monoclinicP21/ca 7.3552b 12.4151c 17.6213β 97.026° Z=41597.024.136yellow[50]
K3Ga3Ge7Se202413.79monoclinicP21/ca 7.0520b 39.033c 6.9488β 90.433° Z=21912.674.191orange[49]
K3Ga3(Ge4.95Si2.05)Se20monoclinicPca 7.0101b 38.928c 6.9594β 90.531°[51]
Rb2GeSe4559.4monoclinicP2/ma=7.390 b=3.704 c=8.623β=104.87 Z=1228.14.07orange-brown[24]
Rb4Ge4Se10monoclinicC2/ca = 16.095 b = 16.09 c = 9.390β= 105.79°[52]
Rb4Ge4Se12orthorhombicPna21a 14.870b 13.800c 12.445 Z=425544.109red[53]
Rb4Ge4Se10 • CH3OH1453.9monoclincC2a=17.099 b=9.287 c=9.503β=118.49 Z=21326.33.64yellow[24]
Rb2MnGe3Se8orthorhombicP212121a 7.2756b 12.1668c 16.8351[54]
Rb2[MnGe4Se10]·3H2Otetragonal[55]
Rb3(AlSe2)3(GeSe2)7monoclinicP21/ca = 7.0580b = 39.419c = 7.0412 β = 90.360°Z = 2#190K; band gap 2.4 eV[56]
RbGaGeSe4orthorhombicPnmaa=17.5750 b= 7.4718 c= 12.4449 Z=81634.234.419colourless; air sensitive[50]
γ-Sr2GeSe4orthorhombicAma2a = 10.284b = 10.543c = 7.411 Z=4[57][58]
Strontium Selenogermanate(III)Sr2Ge2Se5monoclinicP21/na=8.445b=12.302c=9.179β=93.75°Z=4Ge-Ge bond[59]
tepa=tetraethylenepentamine(H2peha)[Y2(μ-OH)2(tepa)2Cl2]{[Y2(μ-OH)2(tepa)2Cl]2(μ-Ge2Se6)}[Ge2Se6]Cl2triclinicP1a 9.1861b 17.3698c 19.5422α 103.218°β 95.414°γ 101.439°[60]
Y2(tepa)2(μ-OH)2(μ-Ge2Se6)]·H2OmonoclinicC2/ca 21.87b 12.245c 18.724β 127.58°[61]
AgxNa(6-x)Ge2Se7x=1.76[62]
AgxNa(8-x)Ge4Se10C2/c[62]
K2Ag2GeSe4orthorhombicFddda 6.613b 13.776c 21.822[63]
Ag2FeGeSe4orthorhombic[64]
AgGaGeSe4tetragonalI42da = 5.8056 c = 10.349348.81band gap 2.27 eV[65]
Rb2Ag2GeSe41579.76orthorhombicFddda 6.5943b 13.9740c 22.627[66]
RbAg3Ga8Se14monoclinicCma 12.9155b 11.7376c 9.6693β 116.367°[67]
Ag2Sr3Ge2Se8cubicI43d[68]
Rb3[AgGe4Se10]·2H2O[55]
Li7Cd4.5Ge4Se16orthorhombicPna21a 14.165b 8.2990c 6.6869band gap 2.18 eV; melt 985K[69]
Na2CdGe2Se6monoclinicCca 7.589b 13.182c 12.069β 98.829°SHG 2×AgGaS2 at 2.09 μm[44]
K2CdGe3Se81040.05monoclinicP21a=7.6069b=12.4016c=17.6585β=95.306° Z=41658.714.165brownish yellow[70]
SrCdGeSe4orthorhombicAma2a = 10.8245b = 10.6912c = 6.6792 Z=4red; band gap 1.9 eV; melt 851; SHG 5× AgGaS2[71]
[NH4]2In4Se8Ge4monoclinicP21/ca 7.642b 12.470c 18.222β 95.214°[48]
KInGeSe4monoclinicP21/ca=7.6108 b=12.4473 c=18.0896β=97.238° Z=81700.04.239yellow[72]
RbInGeSe4orthorhombicPnmaa=17.9948 b=7.6908 c=12.6003 Z=81743.84.475yellow[72]
K3Ga3(Ge6.17Sn0.83)Se20monoclinicPca 7.0843b 39.404c 7.0212β 90.567°[51]
Na9Sb(Ge2Se6)2monoclinicC2/ca = 8.95 b = 24.33 c = 7.066 β = 122.10° Z=213033.992red[73]
Sr3GeSb2Se8orthorhombicPnmaa = 12.633b = 4.301c = 28.693Z = 41558.8band gap 0.75 eV[74]
Cs4Ge2Se6monoclinicP21/na 7.6295b 9.6884c 19.773β=98.78°[75]
Cs4Ge2Se81308.5monoclinicC2a=17.503 b=9.549 c=9.751β=118.16° Z=21436.83.87orange-yellow[76]
Cs4Ge4Se10monoclinicC2/ca = 16.348 b = 16.49 c = 9.771β = 107.10°[52]
Cs4Ge4Se10 · 2CH3OH1675.7monoclinicC2/ma=15.278b=7.624c=10.090β=121.71° Z=2999.84.34yellow[76]
Cs4Ge4Se121769.52orthorhombicPna21a 15.193b 13.944c 12.845 Z=42721.44.319red[53]
(C4C1C1im)+7{[Cs@SnII4(GeIV4Se10)4]7−}cubicP43ma=15.446Cs in a tetrahedron[9]
heptakis(1-ethyl-3-methyl-1H-imidazol-3-ium) hexatriacontakis(μ-selenido)-tetraselenido-cesium-tetra-germanium(ii)-hexadeca-germanium(iv)(C2C1Im)7[Cs@GeII4(GeIV4Se10)4]4831.2orthorhombicP212121a 18.1595b 18.5017c 36.632 Z=412307.82.980yellow[41]
Cs2MgGe3Se8orthorhombicP212121a 7.6635b 12.7242c 17.7724[77]
Cs[Cr(en)2GeSe4]693.57monoclinicP21/na=11.3115 b=12.3519 c=11.4514β =93.359 Z=41597.22.884black[78]
Cs2MnGe3Se8orthorhombicP212121a 7.6376b 12.648c 17.762[54]
Cs2[MnGe4Se10]·3H2Otetragonal[55]
Cs2Cu2GeSe4monoclinicC2/ca 7.8231b 23.953c 6.0197β 113.75°[66]
Cs2ZnGe3Se8orthorhombicP212121a 7.5756b 12.6191c 17.6543[77]
CsGaGeSe4orthorhombicPnmaa= 17.7666 b= 7.5171 c= 12.6383 Z=81687.94.652colourless[50]
Cs2Ge3Ga6Se14P3m1a = 7.6396 c =13.5866 Z = 1686.72dark red[79]
(Cs6Cl)2Cs5[Ga15Ge9Se48]tetragonalI4/ma 14.3870c 28.012[80]
[Cs6Cl][Ga5GeQ12]band gap 2.89 eV; porous layers[81]
(Cs6Br)2Cs5[Ga15Ge9Se48]tetragonalI4/ma 14.3806c 27.934[80]
(Cs6I0.6Cl0.5)2Cs5[Ga15Ge9Se48]tetragonalI4/ma 14.4267c 28.082[80]
(Cs5KCl)2Cs5[Ga15Ge9Se48]tetragonalI4/ma=14.3309 c=27.797[80]
(Rb6Cl)2Cs5[Ga15Ge9Se48]tetragonalI4/ma=14.2193 c=27.410 Z=25542[80]
(Rb6Br)2Cs5[Ga15Ge9Se48]tetragonalI4/ma=14.4034 c=27.598 Z=25646.3[80]
Cs3AsGeSe5monoclinicC2/ma 14.252b 7.4c 10.335β 124.07°[75]
CsAg3Ga8Se14monoclinicCma 12.9694b 11.7931c 9.7011β 116.805°[67]
Cs3[AgGe4Se10]·2H2O[55]
Cs2CdGe3Se8orthorhombicP2121217.7048b 12.6822c 17.8208[77]
Cs2Ge3In6Se14R3ma = 7.9951c = 41.726band gap 2.08 eV[82]
Ba2Ge2Se5orthorhombicPnmaa=12.594b=9.174c=9.160Z=4[59]
[Ba2(H2O)9][GeSe4]825.25orthorhombicPbcaa 13.916b 15.097c 16.116 Z=83385.93.238light yellow[83]
Ba6Ge2Se12monoclinicP21/ca = 10.0903b = 9.3640c = 25.7643 β = 90.303°[84]
Ba7Ge2Se17orthorhombicPnmaa = 12.652b = 20.069c = 12.3067[84]
Ba4Ge3Se9Cl2P63a 10.0924b 10.0924c 12.512[85]
Ba3[Mn6Ge4Se17]·19H2O2716.66triclinicP1a 12.184b 15.089c 15.868α 88.73°β 73.68°γ 71.06° Z=22640.43.412red[83]
Ba3[Mn6Ge4Se17]·30H2OrhombohedralR3ca 20.463c 25.11 Z=691093.188orange-red[83]
BaCu2GeSe4P3121a 6.5014c 16.266red[86]
BaZnGeSe4orthorhombicAma2a = 11.3255b = 11.2527c = 6.2917band gap 2.46 eV[87]
LiBa4Ga5Se12orthorhombicP421ca 13.0056b 13.0056c 6.2671band gap 2.44 eV[88]
Ba4Ge3Se9Br2hexagonalP63a = 10.2345c = 12.5306
BaCdGeSe4orthorhombicFdd2a=22.167b=22.768c=13.303band gap 1.67 eV; SHG 0.5 × AgGaS2[89]
Ba4GeSb2Se111734.01orthorhombicCmc21a = 9.37b = 25.85,c = 8.80 Z=421315.404[90]
La4Ge3Se2S10rhombohedralR3ca=19.5575 c=8.14682698.64.605Yellow-orange[91]
La4Ge3Se4S8rhombohedralR3c2745.3Yellow-orange[91]
La4Ge3Se6S6rhombohedralR3c2792.6orange[91]
La4Ge3Se8S4rhombohedralR3c2845.3red[91]
La4Ge3Se10S2rhombohedralR3c2912.1red[91]
lanthanum(III) bis[hexaselenodigermanate]Na9La[Ge2Se6]2monoclinicC12/m1a =7.974 b=12.337 c=7.114 β=107.101° Ζ=1669.0orange[92]
Ba4LaSbGe3Se13monoclinicP21/ca=16.3330b=12.5115c=13.0321β=103.457°Z=42590.0red; band gap 2.0 eV[93]
[Ce4(tepa)4(μ-GeSe4)(μ-GeSe5)(μ-Ge2Se6)triclinicP1a 12.273b 16.624c 18.281α 91.264°β 101.034°γ 96.497°[60]
KCeGeSe4monoclinicP21a = 6.852b = 7.025c = 9.017 β = 108.116° Z = 2[94]
Pr(teta)(tren)Cl]2[Ge2Se6](en)triclinicP1a 10.3153b 10.4707c 14.0511α 99.606°β 92.679°γ 119.146°[95]
Nd(teta)(tren)Cl]2[Ge2Se6](en)triclinicP1a 10.2840b 10.4774c 14.0341α 99.655°β 92.651°γ 119.161°[95]
Na9Sm(Ge2Se6)2monoclinicC2/ma = 7.916b = 12.244c = 7.105β = 106.99°Z = 1658.6[96][97]
Sm2(μ-OH)2(tepa)2(μ-Ge2Se6)monoclinicP21/na 12.10b 11.41c 12.71β 92.81°[60]
Sm(teta)(tren)Cl]2[Ge2Se6](en)triclinicP1a 10.3327b 10.482c 14.003α 77.816°β 87.499°γ 60.62°[95]
NaSmGeSe4·0.25Na2SemonoclinicC2/ca 22.508b 11.0307c 6.8261β 103.038°[98]
KSmGeSe4monoclinicP21a = 6.774b = 6.994c = 8.960 β = 108.225°Z = 2403.2[99]
RbSmGeSe4orthorhombicP212121a = 6.7347b = 7.0185c = 17.723Z=4837.7[99]
CsSmGeSeorthorhombicP212121a=6.707b=7.067c=18.334 Z=4869.1[99]
Eu2GeSe4monoclinicP21a = 6.964 b = 7.055 c = 8.400 β = 108.12° Z = 2deep red[100]
Eu2GeSe4monoclinicP21/ma = 6.969 b = 7.059 c = 8.516 β = 107.99° Z = 2@673K[100]
Eu2Ge2Se5monoclinicP21/na = 8.421 b = 12.235 c = 9.127 β = 93.67° Z = 4deep red[100]
{Eu(en)3}2(μ-OH)2]Ge2Se6monoclinicP21/na 10.062b 11.538c 15.227β 98.470°[101]
Eu(teta)(tren)Cl]2[Ge2Se6](en)triclinicP1a 10.364b 10.549c 14.1157α 77.299°β 87.606°γ 60.697°[95]
{Eu(tepa)(μ-OH)}2(μ-Ge2Se8)monoclinicP21/na 12.384b 11.697c 12.965β 94.107°[102]
Na2EuGeSe4cubicI43ma=7.3466Z=2[103]
Na0.75Eu1.625GeSe4cubicI43da=14.7065Z=16[103]
K2EuGeSe5monoclinicP21/ca = 11.8056b = 9.9630c = 8.9456 β = 91.195°Z = 41051.94.404@167K; band gap 1.84 eV; Eu(II)[104]
EuCdGeSe4orthorhombicAma2a 10.7525b 10.6275c 6.6740 Z=4762.65.685red; band gap 2.25 eV; SHG 3.8 × AgGaS2[105]
Gd(teta)(tren)Cl]2[Ge2Se6](en)triclinicP1a 10.310b 10.495c 14.055α 77.50°β 87.51°γ 60.81°[95]
{Gd(tepa)(μ-OH)}2(μ-Ge2Se8)monoclinicP21/na 12.316b 11.667c 12.868β 93.70°[102]
{Dy(tepa)(μ-OH)}2(μ-Ge2Se8)monoclinicP21/na 12.329b 11.627c 12.882β 94.177°[102]
[{Dy(en)3}2(μ-OH)2]Ge2Se6a 10.026b 11.526c 15.147β 99.030°[102]
Tb2(tepa)2(μ-OH)2(μ-Ge2Se8)monoclinicP21/na 12.228b 11.587c 12.782β 93.458°[61]
Tb(teta)(tren)Cl]2[Ge2Se6](en)triclinicP1a 10.2303b 10.4499c 14.0083α 99.655°β 92.737°γ 119.069°[95]
[Tb2(tepa)2(μ-OH)2(μ-Ge2Se6)]·0.5H2OmonoclinicC2/ca 22.007b 12.3363c 18.2590β 125.196°[106]
[{Ho(en)3}2(μ-OH)2]Ge2Se6monoclinicP21/na 9.997b 11.550c 15.109β 99.289°[101]
[{Ho(dien)2}2(μ-OH)2]Ge2Se6monoclinicP21/na 11.920b 11.583c 13.691β 98.154°[101]
Ho2(μ-OH)2(tepa)2(μ-Ge2Se6)orthorhombicPbcaa 12.1791b 13.487c 20.346[60]
(H2peha)[Er2(μ-OH)2(tepa)2Cl2]{[Er2(μ-OH)2(tepa)2Cl]2(μ-Ge2Se6)}[Ge2Se6]Cl2triclinicP1a 9.1544b 17.382c 19.443,α 102.994°β 95.306°γ 101.406°[60]
(H3O)[Tm(teta)2][Ge2Se6]orthorhombicPccna 13.7846b 14.3998c 17.9221[95]
Tm2(tepa)2(μ-OH)2(μ-Ge2Se6)orthorhombicPbcaa 12.1702b 13.528c 20.281[106]
Li2HgGeSe4602.90orthorhombicPna21a=14.150 b=8.260 c=6.692 Z=4782.25.119yellow[107]
Na2Hg3Ge2Se81424.61tetragonalP4c2a=9.1938 c=9.5437 Z=2806.695.865red[107]
SrHgGeSe4orthorhombicAma2a 10.8375b 10.7456c 6.6377NLO 5 × AgGaS2[108]
BaHgGeSe4orthorhombicAma2a 11.255b 11.033c 6.685NLO 5 × AgGaS2[108]
EuHgGeSe4orthorhombicAma2a 10.6530b 10.5990c 6.5986band gap; SHG 3.1 × AgGaS2[109]
TlGaGeSe4orthorhombicPnmaa= 17.4742 b= 7.4105 c= 11.9406 Z=81546.225.692red[50]
Tl2Ga2GeSe6tetragonalI4/mmca = 8.0770c = 6.2572Z = 4[110]
TlInGeSe4702monoclinicP21/ca= 7.586 b= 12.134 c=18.023 β= 96.037° Z=81649.85.653yellow[72]
TlInGe2Se6trigonalR3a = 10.1798c = 9.2872band gap 2.38 eV[111]
α-Pb2GeSe4[57]
Na0.5Pb1.75GeSe4cubicI43da = 14.662[97]
PbGa2GeSe6melt 687 °C; phase transition 522 °C[112]
Pb4Ga4GeSe12[112]
Pb3Ga2GeSe8P421cmelt incongruently 656 °C[112]
Sr1.31Pb0.69GeSe4orthorhombicAma2a = 10.31220b = 10.39320c = 7.42140[57]
Sr0.19Pb1.81GeSe4I42da = 14.6177[57]
Sr12.6Pb6.4Ge11Se44hexagonalP63a = 19.9867c = 12.05464170.28black; band gap 1.8 eV[113]
Ag0.5Pb1.75GeS3Seband gap 2.0 eV[114]

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Salts and covalent derivatives of theselenide ion
Ge(II)
Ge(IV)
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