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Seifertite

From Wikipedia, the free encyclopedia
Dense silica mineral
Seifertite
Crystal structure
General
CategoryTectosilicates,quartzgroup
FormulaSiO2
IMA symbolSft[1]
Strunz classification4.DA.05 (oxides)
Dana classification75.01.06 (tectosilicates)
Crystal systemOrthorhombic
(Pbcn)
Crystal classDipyramidal (mmm)
H–M symbol: (2/m 2/m 2/m)
Identification
Formula mass60.08 g/mol
Crystal habitMicroscopic crystals
Specific gravity4.294
References[2][3]

Seifertite is asilicate mineral with the formula SiO2 and is one of the densest polymorphs ofsilica. It has only been found inMartian[4][5] andlunar meteorites,[6] where it is presumably formed from eithertridymite orcristobalite – other polymorphs ofquartz – as a result of heating during theatmospheric entry and impact to the Earth, at an estimated minimal pressure of 35 GPa. It can also be produced in the laboratory by compressing cristobalite in adiamond anvil cell to pressures above 40 GPa. The mineral is named afterFriedrich Seifert (born 1941), the founder of the Bayerisches Geoinstitut atUniversity of Bayreuth, Germany, and is officially recognized by theInternational Mineralogical Association.[4][5][7]

Seifertite forms micrometre-sized crystallinelamellae embedded into a glassy SiO2 matrix. The lamellae are rather difficult to analyze, as they vitrify within seconds under laser or electron beams used for standardRaman spectroscopy orelectron-beam microanalysis, even at much reduced beam intensities. Nevertheless, it was possible to verify that it is mainly composed of SiO2 with minor inclusions ofNa2O (0.40 wt.%) andAl2O3 (1.14 wt.%).X-ray diffraction reveals that the mineral hasscrutinyite (α-PbO2) type structure with anorthorhombic symmetry and Pbcn or Pb2nspace group. Its lattice constantsa = 4.097,b = 5.0462,c = 4.4946,Z = 4 correspond to the density of 4.294 g/cm3, which is among the highest for any forms of silica (for example, the density of quartz is 2.65 g/cm3).[3][4][5] Onlystishovite has a comparable density of about 4.287 g/cm3.[8]

See also

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References

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  1. ^Warr, L.N. (2021)."IMA–CNMNC approved mineral symbols".Mineralogical Magazine.85 (3):291–320.Bibcode:2021MinM...85..291W.doi:10.1180/mgm.2021.43.S2CID 235729616.
  2. ^Seifertite at Webmineral
  3. ^abSeifertite at Mindat.
  4. ^abcGoresy, Ahmed El; Dera, Przemyslaw; Sharp, Thomas G.; Prewitt, Charles T.; Chen, Ming; Dubrovinsky, Leonid; Wopenka, Brigitte; Boctor, Nabil Z.; Hemley, Russell J. (2008). "Seifertite, a dense orthorhombic polymorph of silica from the Martian meteorites Shergotty and Zagami".European Journal of Mineralogy.20 (4): 523.Bibcode:2008EJMin..20..523G.doi:10.1127/0935-1221/2008/0020-1812.First page preview.
  5. ^abcDera P.; Prewitt C. T.; Boctor N. Z.; Hemley R. J. (2002)."Characterization of a high-pressure phase of silica from the Martian meteorite Shergotty".American Mineralogist.87 (7): 1018.Bibcode:2002AmMin..87.1018D.doi:10.2138/am-2002-0728.S2CID 129400258.
  6. ^H. Chennaoui Aoudjehane & A. Jambon (2008)."First evidence of high-pressure silica: stishovite and seifertite in lunar meteorite Northwest Africa 4734".Meteoritics & Planetary Science.43 (7, Supplement): A32.doi:10.1111/j.1945-5100.2008.tb00711.x.
  7. ^The official IMA-CNMNC List of Mineral NamesArchived 2011-02-28 at theWayback Machine, International Mineralogical Association.
  8. ^Stishovite summary, Handbook of mineralogy.
Crystalline
Cryptocrystalline
Amorphous
Miscellaneous
Notable varieties
Chalcedony
Opal
Quartz
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