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Samarium monosulfide

From Wikipedia, the free encyclopedia
Samarium monosulfide
Identifiers
3D model (JSmol)
  • InChI=1S/S.Sm/q-2;+2
    Key: KASDAGLLEDDKAA-UHFFFAOYSA-N
  • [S-2].[Sm+2]
Properties
SSm
Molar mass182.42 g·mol−1
Appearancedark brown crystals
Melting point1,940 °C (3,520 °F; 2,210 K)
Structure
cubic
Related compounds
Othercations
Neodymium sulfide
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Samarium monosulfide is a binaryinorganic chemical compound ofsamarium metal andsulfur with the chemical formulaSmS.[1]

Synthesis

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Fusion of stoichiometric amounts of pure substances:

Sm + S → SmS

Physical properties

[edit]

Samarium monosulfide forms crystals ofcubic system, spatial groupFm3m, cell parameters a = 0.5970–0.5863 nm, Z = 4, structurally isomorphic with NaCl.[2]

The compound melts congruently at a temperature of 1500 °C, 1940 °C, or 2080 °C.[3]

SmS is a chalcogenide material that exists in two possible states: as a metal (also called "golden") and as asemiconductor ("blue" or "black").[4] As a result, SmS has gained considerable interest as a switchable material.[5]

Uses

[edit]

Samarium monosulfide has a high sensitivity to deformation. Therefore, SmS is a promising material for creating pressure sensors of force, torque, accelerations, etc.[6]

References

[edit]
  1. ^Comprehensive Inorganic Chemistry II: From Elements to Applications. Newnes. 23 July 2013. p. 537.ISBN 978-0-08-096529-1. Retrieved25 July 2024.
  2. ^Okamoto, H. (1 December 2010)."S-Sm (Sulfur-Samarium)".Journal of Phase Equilibria and Diffusion.31 (6): 577.Bibcode:2010JPED...31..577O.doi:10.1007/s11669-010-9790-9.ISSN 1863-7345. Retrieved25 July 2024.
  3. ^Predel, B. (1998)."S-Sm (Sulfur-Samarium)".Pu-Re – Zn-Zr. Landolt-Börnstein - Group IV Physical Chemistry.5 J:1–2.doi:10.1007/10551312_2657.ISBN 3-540-61742-6. Retrieved25 July 2024.
  4. ^Volchkov, Ivan; Baskakov, Evgeniy; Strelov, Vladimir; Kanevskii, Vladimir (1 November 2022)."Thermoelectric and electrical characteristics of SmS ceramic samples after exposure to a pulsed magnetic field".Journal of Rare Earths.40 (11):1778–1784.Bibcode:2022JREar..40.1778V.doi:10.1016/j.jre.2022.01.008.ISSN 1002-0721. Retrieved25 July 2024.
  5. ^Sousanis, Andreas; Smet, Philippe F.; Poelman, Dirk (16 August 2017)."Samarium Monosulfide (SmS): Reviewing Properties and Applications".Materials.10 (8): 953.Bibcode:2017Mate...10..953S.doi:10.3390/ma10080953.ISSN 1996-1944.PMC 5578319.PMID 28813006.
  6. ^BOLSHEV, K. N. (2014)."Application of barorezistor from samarium monosulfide when carrying out heatphysical experiments"(PDF).ВЕСТНИК МАХ (3). Retrieved26 July 2024.
Samarium(II)
Samarium(III)
Organosamarium(III)
Sulfides(S2−)
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