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Samarium(III) phosphide

From Wikipedia, the free encyclopedia
"Samarium phosphide" redirects here. For the pentaphosphide, seeSamarium pentaphosphide.
Samarium(III) phosphide
Names
Other names
Phosphanylidynesamarium, samarium monophosphide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.031.869Edit this at Wikidata
EC Number
  • 235-069-8
  • InChI=1S/P.Sm
    Key: QRVXKVFNBYFEOG-UHFFFAOYSA-N
  • P#[Sm]
Properties
PSm
Molar mass181.3
AppearanceCrystals
Density6.3 g/cm3
Insoluble
Structure
Cubic
Related compounds
Otheranions
Samarium nitride
Samarium arsenide
Samarium antimonide
Samarium bismuthide
Othercations
Neodymium phosphide
Europium phosphide
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Samarium(III) phosphide is aninorganic compound ofsamarium andphosphorus with the chemical formulaSmP.[1][2][3]

Synthesis

[edit]

Samarium(III) phosphide can be obtained by heating samarium and phosphorus:

4 Sm + P4 → 4 SmP

Physical properties

[edit]

Samarium(III) phosphide forms crystals of acubic system,space groupFm3m, cell size a = 0.5760 nm, Z = 4, with a structure similar tosodium chloride NaCl.[4]

The compound exists in the temperature range of 1315–2020 °C and has a homogeneity region described by the SmP1÷0.982.[5]

Chemical properties

[edit]

Samarium(III) phosphide readily dissolves innitric acid.[6]

Uses

[edit]

Samarium(III) phosphide compound is asemiconductor used in high power, high frequency applications and inlaser diodes.[1]

References

[edit]
  1. ^ab"Samarium Phosphide".American Elements. Retrieved21 December 2021.
  2. ^Toxic Substances Control Act (TSCA) Chemical Substance Inventory.U.S. Government Printing Office. 1979. p. 49. Retrieved21 December 2021.
  3. ^Freeman, A. J. (2 December 2012).The Actinides: Electronic Structure and Related Properties.Elsevier. p. 201.ISBN 978-0-323-15304-1. Retrieved21 December 2021.
  4. ^Donnay, Joseph Désiré Hubert (1963).Crystal Data; Determinative Tables.American Crystallographic Association. p. 888. Retrieved21 December 2021.
  5. ^Predel, B. (1998)."P-Sm (Phosphorus-Samarium)".Ni-Np – Pt-Zr. Landolt-Börnstein - Group IV Physical Chemistry. p. 1.doi:10.1007/10542753_2381.ISBN 3-540-61712-4. Retrieved21 December 2021.{{cite book}}:|website= ignored (help)
  6. ^Soviet Progress in Chemistry. Faraday Press. 1966. p. 91. Retrieved21 December 2021.
Samarium(II)
Samarium(III)
Organosamarium(III)
Phosphides
Other compounds
Binary phosphides
Ternary phosphides
Quaternary phosphides
Quinary phosphides
See also
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