Movatterモバイル変換


[0]ホーム

URL:


Jump to content
WikipediaThe Free Encyclopedia
Search

Rieche formylation

From Wikipedia, the free encyclopedia
Chemical reaction

Rieche formylation
Named afterAlfred Rieche
Reaction typeSubstitution reaction

Rieche formylation is a type offormylation reaction. The substrates are electron richaromatic compounds, such asmesitylene[1] orphenols,[2] withdichloromethyl methyl ether acting as the formyl source. Thecatalyst istitanium tetrachloride and the workup is acidic. The reaction is named afterAlfred Rieche who discovered it in 1960.[3]

See also

[edit]

Reimer–Tiemann reaction.

References

[edit]
  1. ^Rieche, A.; Gross, H.; Höft, E. (1967). "Aromatic Aldehydes. Mesitaldehyde".Organic Syntheses.47 (47): 1.doi:10.15227/orgsyn.047.0001.
  2. ^García, Oscar; Nicolás, Ernesto; Albericio, Fernando (June 2003). "o-Formylation of electron-rich phenols with dichloromethyl methyl ether and TiCl4".Tetrahedron Letters.44 (27):4961–4963.doi:10.1016/S0040-4039(03)01168-7.
  3. ^Rieche, Alfred; Gross, Hans; Höft, Eugen (January 1960). "Über α-Halogenäther, IV. Synthesen aromatischer Aldehyde mit Dichlormethyl-alkyläthern".Chemische Berichte.93 (1):88–94.doi:10.1002/cber.19600930115.
Stub icon

Thischemical reaction article is astub. You can help Wikipedia byexpanding it.

Retrieved from "https://en.wikipedia.org/w/index.php?title=Rieche_formylation&oldid=1307957200"
Categories:
Hidden categories:

[8]ページ先頭

©2009-2025 Movatter.jp