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Protactinium(IV) oxide

From Wikipedia, the free encyclopedia
Protactinium(IV) oxide
Names
IUPAC name
Protactinium(IV) oxide
Identifiers
3D model (JSmol)
  • InChI=1S/2O.Pa checkY
    Key: FUMADFKVOBAYPE-UHFFFAOYSA-N checkY
  • O=[Pa]=O
Properties
O2Pa
Molar mass263.034 g·mol−1
AppearanceBlack crystals
Melting point2,927 °C (5,301 °F; 3,200 K)[1]
Structure
Fluorite (cubic),cF12
Fm3m, No. 225
a = 544.6 pm[1]
Hazards
NFPA 704 (fire diamond)
Related compounds
Othercations
Thorium(IV) oxide
Uranium(IV) oxide
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Protactinium(IV) oxide is a chemical compound with the formulaPaO2. The black oxide is formed by reducingPa2O5 withhydrogen at 1 550 °C. Protactinium(IV) oxide does not dissolve in H2SO4, HNO3, or HCl solutions, but reacts with HF.[2][3]: 195 

As protactinium(IV) oxide, like other protactinium compounds, isradioactive, toxic and very rare, it has no known technological use.

References

[edit]
  1. ^abChristine Guéneau; Alain Chartier; Paul Fossati; Laurent Van Brutzel; Philippe Martin (2020). "Thermodynamic and Thermophysical Properties of the Actinide Oxides".Comprehensive Nuclear Materials 2nd Ed.7:111–154.doi:10.1016/B978-0-12-803581-8.11786-2.ISBN 9780081028667.S2CID 261051636.
  2. ^Sellers, Philip A.; Fried, Sherman; Elson, Robert E.; Zachariasen, W. H. (1954)."The Preparation of Some Protactinium Compounds and the Metal".Journal of the American Chemical Society.76 (23): 5935.Bibcode:1954JAChS..76.5935S.doi:10.1021/ja01652a011.
  3. ^Boris F. Myasoedov, H. W. Kirby, & Ivan G. Tananaev (2006) Protactinium, Chapter 4 in Morss, Lester R. & Edelstein, Norman M. & Fuger, Jean, (edit.)The Chemistry of the Actinide and Transactinide ElementsArchived 2017-08-26 at theWayback Machine (PDF) (3. painos). Dordrecht: Springer. ss. 161–252.
Pa(II)
Pa(III)
Pa(IV)
Pa(V)
Mixed oxidation states
+1 oxidation state
+2 oxidation state
+3 oxidation state
+4 oxidation state
+5 oxidation state
+6 oxidation state
+7 oxidation state
+8 oxidation state
Related
Oxides are sorted byoxidation state.Category:Oxides


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