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Prorobinetidin

From Wikipedia, the free encyclopedia

Prorobinetidins are a type ofcondensed tannins formed fromrobinetinidol. They formrobinetinidin when depolymerized under oxidative conditions.

Mimosa andquebracho tannins are, according to a comparative13C NMR study of polyflavonoids, found to be predominantly profisetinidin/prorobinetidin-type tannins.[1]

Stryphnodendron adstringens ( the barbatimão), a species of legume found in Brazil, produces prorobinetinidins in its stem bark. These arerobinetinidol-(4β → 8)-epigallocatechin,robinetinidol-(4α → 8)-epigallocatechin,robinetinidol-(4β → 8)-epigallocatechin 3-O-gallate,robinetinidol-(4α → 8)-epigallocatechin 3-O-gallate,robinetinidol-(4α → 6)-gallocatechin androbinetinidol-(4α → 6)-epigallocatechin, in addition to the tentatively characterized, robinetinidol [4β → 6(8)]-gallocatechin and robinetinidol-(4α → 8)-gallocatechin.[2][3]

References

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  1. ^Rahim, Afidah A; Rocca, Emmanuel; Steinmetz, Jean; Jain Kassim, M; Sani Ibrahim, M; Osman, Hasnah (2008). "Antioxidant activities of mangrove Rhizophora apiculata bark extracts".Food Chemistry.107:200–207.doi:10.1016/j.foodchem.2007.08.005.
  2. ^Prorobinetinidins from Stryphnodendron adstringens. Palazzo de Mello J.; Petereit F.; Nahrstedt A., Phytochemistry, 1996.
  3. ^Ishida, K; De Mello, J. C. P; Cortez, D. A. G; Filho, B. P. D; Ueda-Nakamura, T; Nakamura, C. V (2006). "Influence of tannins from Stryphnodendron adstringens on growth and virulence factors of Candida albicans".Journal of Antimicrobial Chemotherapy.58 (5):942–949.doi:10.1093/jac/dkl377.PMID 16973655.
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