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Paper

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(Redirected fromPrinting and writing paper)
Material for writing, printing, etc.
For other uses, seePaper (disambiguation).
Paper
A photo of various products made from paper.
MaterialCellulose, oftenlignocellulose
Introduced105 CE,China
Manufacturer

Paper
"Paper" in Traditional (top) and Simplified (bottom) Chinese characters
Traditional Chinese
Simplified Chinese
Transcriptions
Standard Mandarin
Hanyu Pinyinzhǐ
IPA[ʈʂɨ̀]
Yue: Cantonese
Yale Romanization
Jyutpingzi2
Southern Min
HokkienPOJchoá
Tâi-lôtsuá

Paper is a thin sheet of mattedcellulosefibers. Largely derived fromlignocellulose, paper is created from apulp dissolved into aslurry that is drained and dried into sheets. Different types of paper are defined byconstituent fiber,paper pulp,sizing,coating,paper size,paper density andgrammage.

The papermaking process developed inEast Asia at least as early as 105CE by theHan courteunuchCai Lun, although archaeological evidence exists of 2nd century BCE paper-like material in China. Before theindustrialization of paper production, the most common paper wasrag paper, made from discardednatural fibertextiles collected byragpickers. The 1843 invention ofwood pulp, coupled with theSecond Industrial Revolution, madepulpwood paper the dominant variety to this day.[1]

Etymology

Further information:Papyrus

The wordpaper is etymologically derived fromLatinpapyrus, which comes from theGreekπᾰ́πῡρος (pápūros), the word for theCyperus papyrus plant.[2][3]Papyrus is a thick, paper-like material produced from the pith of theCyperus papyrus plant, which was used inancient Egypt and otherMediterranean cultures forwriting before the introduction of paper.[4] Although the wordpaper is etymologically derived frompapyrus, the two are separate technological developments that use different materials and production methods. Papyrus is a lamination of natural plant fibre, while paper is manufactured from fibres whose properties have been changed by maceration.[5]

History

Main article:History of paper

Precursors

Further information:Writing material

Paper was preceded by and coexisted with otherearly writing materials, such aspapyrus,parchment,vellum,barkcloth,birch bark,palm leaves, andbamboo and wooden slips.

Papyrus, superficially similar to paper, has several downsides that eventually caused it to be replaced by paper: It was geographically limited to a plant primarily grown in Egypt; it was both more expensive and laborious to produce compared to paper; and it was more fragile and sensitive to moisture, making it prone to break apart in damp conditions.[6]

Invention and development

Hempwrapping paper, China,c. 100 BCE

The oldest known archaeological fragments of the immediate precursor to modern paper date to the 2nd century BCE inChina. The pulp papermaking process is ascribed toCai Lun, a 2nd-century CEHan courteunuch.[5][7]

In the 13th century, the knowledge and uses of paper spread from theMiddle East tomedieval Europe, where the first water-poweredpaper mills were built.[8] Because paper was introduced to the West through the city ofBaghdad, it was first calledbagdatikos.[9]

In the 19th century, industrialization greatly reduced the cost of manufacturing paper. In 1844, the Canadian inventorCharles Fenerty and the German inventorFriedrich Gottlob Keller independently developed processes for pulping wood fibres.[10]

Battle of Talas

Main articles:Battle of Talas § Papermaking, andSamarkand paper § History

Popular history points to theBattle of Talas in 751 CE as when papermaking spread to the Islamic world, purporting thatTang dynastypapermakers were captured as prisoners and used to extract 'the secrets' of papermaking.[11] However,archaeological finds from 313 CE inSamarkand suggest paper's presence outside China centuries before.[12]

Papermaking

Main article:Papermaking

Pulp

Main article:Pulp (paper)

Pulp is alignocellulosic mixture of isolatedfibers. Traditional low-lignin pulp sources likerags andpaper mulberry can be mechanically broken down;industrial pulpmaking largely makes use ofpulpwood, which can be pulped chemically or mechanically.

Chemical pulping

Main articles:Kraft process,sulfite process, andsoda pulping

To make pulp from wood, achemical pulping process separateslignin fromcellulose fibre. A cooking liquor is used to dissolve the lignin, which is then washed from the cellulose; this preserves the length of the cellulose fibres. Paper made from chemical pulps are also known aswood-free papers (not to be confused withtree-free paper); this is because they do not contain lignin, which deteriorates over time. The pulp can also bebleached to produce white paper, but this consumes 5% of the fibres. Chemical pulping processes are not used to make paper made from cotton, which is already 90% cellulose.

The microscopic structure of paper:Micrograph of tissue paperautofluorescing underultraviolet illumination. The individual fibres in this sample are around 10μm in diameter.

There are three main chemical pulping processes: thesulfite process dates back to the 1840s and was the dominant method before the second world war. Thekraft process, invented in the 1870s and first used in the 1890s, is now the most commonly practised strategy; one of its advantages is the chemical reaction with lignin produces heat, which can be used to run a generator. Most pulping operations using the kraft process are net contributors to the electricity grid or use the electricity to run an adjacent paper mill. Another advantage is that this process recovers and reuses all inorganic chemical reagents.Soda pulping is another specialty process used to pulpstraws,bagasse andhardwoods with highsilicate content.

Mechanical pulping

There are two major mechanical pulps: thermomechanical pulp (TMP) and groundwood pulp (GW). In the TMP process, wood is chipped and then fed into steam-heated refiners, where the chips are squeezed and converted to fibres between two steel discs. In the groundwood process, debarked logs are fed into grinders where they are pressed against rotating stones to be made into fibres. Mechanical pulping does not remove thelignin, so the yield is very high, > 95%; however, lignin causes the paper thus produced to turn yellow and become brittle over time. Mechanical pulps have rather short fibres, thus producing weak paper. Although large amounts ofelectrical energy are required to produce mechanical pulp, it costs less than the chemical kind.

Recycling and de-inked pulp

A process for removing printing inks fromrecycled paper was invented by German juristJustus Claproth in 1774. Today this method is calleddeinking.[1]

Paper recycling processes can use either chemically or mechanically produced pulp; by mixing it with water and applying mechanical action thehydrogen bonds in the paper can be broken and fibres separated again. Most recycled paper contains a proportion of virgin fibre for the sake of quality; generally speaking, de-inked pulp is of the same quality or lower than the collected paper it was made from.

There are three main classifications of recycled fibre:

  • Mill broke or internal mill waste – This incorporates any substandard or grade-change paper made within the paper mill itself, which then goes back into the manufacturing system to be re-pulped back into paper. Such out-of-specification paper is not sold and is therefore often not classified as genuine reclaimed recycled fibre; however most paper mills have been reusing their own waste fibre for many years, long before recycling became popular.
  • Preconsumer waste – This is offcut and processing waste, such as guillotine trims and envelope blank waste; it is generated outside the paper mill and could potentially go to landfill, and is a genuine recycled fibre source; it includes de-inked preconsumer waste (recycled material that has been printed but did not reach its intended end use, such as waste from printers and unsold publications).[13]
  • Postconsumer waste – This is fibre from paper that has been used for its intended end use and includes office waste, magazine papers and newsprint. As the vast majority of this material has been printed – either digitally or by more conventional means such as lithography or rotogravure – it will either be recycled as printed paper or go through a de-inking process first.

Recycled papers can be made from 100% recycled materials or blended with virgin pulp, although they are (generally) not as strong nor as bright as papers made from the latter.

Producing paper

Main articles:Paper machine andpapermaking
Paper mill inMänttä-Vilppula,Finland

Thepulp is fed to a paper machine, where it is formed as a paper web and the water is removed from it by pressing and drying.

Pressing the sheet removes the water by force. Once the water is forced from the sheet, a special kind of felt, which is not to be confused with the traditional one, is used to collect the water. When making paper by hand, a blotter sheet is used instead.

Drying involves using air or heat to remove water from the paper sheets. In the earliest days of papermaking, this was done by hanging the sheets like laundry; in more modern times, various forms of heated drying mechanisms are used. On the paper machine, the most common is the steam-heated can dryer. These can reach temperatures above 93 °C (200 °F) and are used in long sequences of more than forty cans where the heat produced by these can easily dry the paper to less than six percent moisture.

Paper grain

All paper produced by paper machines such as theFourdrinier machine are wove paper, i.e. the wire mesh that transports the web leaves a pattern that has the same density along the paper grain and across the grain. Textured finishes,watermarks and wire patterns imitating hand-madelaid paper can be created by the use of appropriate rollers in the later stages of the machine.

Wove paper does not exhibit "laidlines", which are small regular lines left behind on paper when it was handmade in adeckle mould made from rows of metal wires or bamboo. Laidlines are very close together. They run perpendicular to the "chainlines", which are further apart. Handmade paper similarly exhibits"deckle edges", or rough and feathery borders.[14]

Sizing and finishing

Further information:Sizing andCoated paper
Lower quality paper (used to print the book in 1991) with visible bits of wood

Papers may have their surfaces polished bycalendering orburnishing. Paper can be further processed intocoated paper bysizing the paper with a thin layer of material such ascalcium carbonate orkaolin, applied to one or both sides. This treatment manipulates the final feel of the paper, which improve its characteristics for specific purposes, such as avoiding ink running onprinter paper.[15][16]

The paper is then fed onto reels if it is to be used on web printing presses, orcut into sheets for other printing processes or other purposes. Sheets are usually cut "long-grain", i.e. with the grain parallel to the longer dimension of the sheet.Continuous form paper (or continuous stationery) is cut to width with holes punched at the edges, and folded into stacks.[citation needed]

Applications

Further information:List of paper products andCategory:Paper products
Paper money from different countries

It is estimated that paper-based storage solutions captured 0.33% of the total in 1986 and only 0.007% in 2007, even though in absolute terms the world's capacity to store information on paper increased from 8.7 to 19.4petabytes.[17] It is estimated that in 1986 paper-based postal letters represented less than 0.05% of the world's telecommunication capacity, with sharply decreasing tendency after the massive introduction of digital technologies.[17]

Paper has a major role in the visual arts. It is used by itself to form two- and three-dimensional shapes andcollages.[18][19] It has also evolved to being a structural material used in furniture design.[20]Watercolor paper has a long history of production and use.

Types, thickness and weight

Main articles:Paper size,Grammage, andPaper density
Card and paper stock forcrafts use comes in a wide variety of textures and colors.

The thickness of paper is often measured by caliper, which is typically given in thousandths of an inch in the United States and in micrometres (μm) in the rest of the world.[21] Paper may be between 0.07 and 0.18 millimetres (0.0028 and 0.0071 in) thick.[22]

Paper is often characterized by weight. In the United States, the weight is the weight of a ream (bundle of 500 sheets) of varying "basic sizes" before the paper is cut into the size it is sold to end customers. For example, a ream of 20 lb, 8.5 in × 11 in (216 mm × 279 mm) paper weighs 5 pounds because it has been cut from larger sheets into four pieces.[23] In the United States, printing paper is generally 20 lb, 24 lb, 28 lb, or 32 lb at most.Cover stock is generally 68 lb, and 110 lb or more is consideredcard stock.

In Europe and other regions using theISO 216 paper-sizing system, the weight is expressed in grams per square metre (g/m2 or usually gsm) of the paper. Printing paper is generally between 60 gsm and 120 gsm. Anything heavier than 160 gsm is considered card. The weight of a ream therefore depends on the dimensions of the paper and its thickness.

Most commercial paper sold in North America is cut to standardpaper sizes based oncustomary units and is defined by the length and width of a sheet of paper.

The ISO 216 system used in most other countries is based on the surface area of a sheet of paper, not on a sheet's width and length. It was first adopted in Germany in 1922 and generally spread as nations adopted the metric system. The largest standard size paper is A0 (A zero), measuring one square metre (approx. 1189 × 841 mm). A1 is half the size of a sheet of A0 (i.e., 594 mm × 841 mm), such that two sheets of A1 placed side by side are equal to one sheet of A0. A2 is half the size of a sheet of A1, and so forth. Common sizes used in the office and the home are A4 and A3 (A3 is the size of two A4 sheets).

Thedensity of paper ranges from 250 kg/m3 (16 lb/cu ft) for tissue paper to1500 kg/m3 (94 lb/cu ft) for some specialty paper. Printing paper is about 800 kg/m3 (50 lb/cu ft).[24]

Inmarketing andbranding, paper weight (grammage) is utilized to influence consumer perception through haptic feedback. Research in sensory marketing indicates that heavier paper stock is frequently associated with higher perceived quality, professional reliability, and brand prestige compared to lighter alternatives.[25][26]

Types of paper

Main article:List of types of paper

Paper may be classified into seven categories:[27]

  • Printing papers of wide variety.
  • Wrapping papers for the protection of goods and merchandise. This includes wax and kraft papers.
  • Writing paper suitable for stationery requirements. This includes ledger, bank, and bond paper.
  • Blotting papers containing little or no size.
  • Drawing papers usually with rough surfaces used by artists and designers, including cartridge paper.
  • Handmade papers including most decorative papers,Ingres papers,Japanese paper andtissues, all characterized by lack of grain direction.
  • Specialty papers including cigarette paper, toilet tissue, and other industrial papers.

Environmental impact

Main articles:Environmental impact of paper andDeforestation

The production and use of paper has a number of adverse effects on the environment.

Worldwide consumption of paper has risen by 400% in the past 40 years[clarification needed] leading to increase indeforestation, with 35% of harvested trees being used for paper manufacture. Most paper companies also plant trees to help regrow forests. Logging ofold growth forests accounts for less than 10% of wood pulp,[28] but is one of the most controversial issues.

Paper waste accounts for up to 40% of total waste produced in the United States each year, which adds up to 71.6 million tons of paper waste per year in the United States alone.[29] The average office worker in the US prints 31 pages every day.[30] Americans also use in the order of 16 billionpaper cups per year.

Conventional bleaching of wood pulp using elemental chlorine produces and releases into the environment large amounts ofchlorinated organic compounds, including chlorinateddioxins.[31] Dioxins are recognized as a persistent environmental pollutant, regulated internationally by theStockholm Convention on Persistent Organic Pollutants. Dioxins are highly toxic, and health effects on humans include reproductive, developmental, immune and hormonal problems. They are known to be carcinogenic. Over 90% of human exposure is through food, primarily meat, dairy, fish and shellfish, as dioxins accumulate in the food chain in the fatty tissue of animals.[32]

The paper pulp and print industries emitted together about 1% of worldgreenhouse-gas emissions in 2010[33] and about 0.9% in 2012.[34]

Current production and use

In the 2022−2024 edition of the annual "Pulp and paper capacites survey", theFood and Agriculture Organization of the United Nations (FAO) reports that Asia has superseded North America as the top pulp- and paper-producing continent.[35]

FAO figures for 2021 show the production of graphic papers continuing its decline from a mid-2000s peak to hover below 100 million tonnes a year. By contrast, the production of other papers and paperboard – which includes cardboard and sanitary products – has continued to soar, exceeding 320 million tonnes.[35]

FAO has documented the expanding production of cardboard in paper and paperboard, which has been increasing in response to the spread of e-commerce since the 2010s.[35] Data from FAO suggest that it has been even further boosted by COVID-19-related lockdowns.[36]

See also

Citations

  1. ^abGöttsching, Lothar; Gullichsen, Johan; Pakarinen, Heikki; Paulapuro, Hannu; Yhdistys, Suomen Paperi-Insinöörien; Technical Association of the Pulp and Paper Industry (2000).Recycling fiber and deinking. Finland: Fapet Oy. pp. 12–14.ISBN 978-952-5216-07-3.OCLC 247670296.
  2. ^πάπυροςArchived 16 June 2013 at theWayback Machine, Henry George Liddell, Robert Scott,A Greek–English Lexicon, on Perseus
  3. ^"papyrus".Lexico UK English Dictionary.Oxford University Press. Archived fromthe original on 29 January 2020.
  4. ^"papyrus".Dictionary.com Unabridged (Online). n.d. Retrieved20 November 2008.
  5. ^abTsien 1985, p. 38
  6. ^Monro 2016, p. 20-23, 34, 210.
  7. ^Hogben, Lancelot. "Printing, Paper and Playing Cards". Bennett, Paul A. (ed.)Books and Printing: A Treasury for Typophiles. New York: The World Publishing Company, 1951. pp. 15–31. p. 17. & Mann, George.Print: A Manual for Librarians and Students Describing in Detail the History, Methods, and Applications of Printing and Paper Making. London: Grafton & Co., 1952. p. 77
  8. ^Burns 1996, pp. 417f.
  9. ^Murray, Stuart A. P.The Library: An illustrated History. Skyhorse Publishing, 2009, p. 57.
  10. ^Burger, Peter (2007).Charles Fenerty and his paper invention. Toronto: Peter Burger. pp. 25–30.ISBN 978-0-9783318-1-8.OCLC 173248586.Archived from the original on 19 April 2009. Retrieved19 May 2009.
  11. ^Ward, James (2015).The Perfection of the Paper Clip: Curious Tales of Invention, Accidental Genius, and Stationery Obsession. Atria Books.ISBN 978-1476799865.
  12. ^Bloom, Jonathan M. (December 2005),"Silk Road or Paper Road?"(PDF),The Silk Road, vol. 3, no. 2, American University, pp. 21–26, retrieved3 September 2025
  13. ^"Natural Resource Defense Council".Archived from the original on 24 February 2011. Retrieved20 February 2008.
  14. ^"ARCHIVED – Introduction – Detecting the Truth. Fakes, Forgeries and Trickery – Library and Archives Canada"Archived 2 August 2018 at theWayback Machine in a virtual museum exhibition at Library and Archives Canada
  15. ^Appropriate Technology. Intermediate Technology Publications. 1996.
  16. ^Thorn, Ian; Au, Che On (24 July 2009).Applications of Wet-End Paper Chemistry. Springer Science & Business Media.Bibcode:2009aowp.book.....T.ISBN 978-1-4020-6038-0.
  17. ^ab"The World's Technological Capacity to Store, Communicate, and Compute Information"Archived 12 June 2018 at theWayback Machine, especiallySupporting online materialArchived 18 October 2017 at theWayback Machine, Martin Hilbert and Priscila López (2011),Science, 332(6025), 60–65; free access to the article through here: martinhilbert.net/WorldInfoCapacity.htmldoi:10.1126/science.1200970
  18. ^"Lynette Schweigert".NEA. 5 November 2015.Archived from the original on 4 October 2018. Retrieved3 October 2018.
  19. ^"Herminia Albarrán Romero".NEA. 24 January 2013.Archived from the original on 4 October 2018. Retrieved3 October 2018.
  20. ^Morris (August–September 2018). "Material Values, Paper".The Economist. p. 38.
  21. ^"Paper Thickness (Caliper) Chart".Case Paper. Archived fromthe original(PDF) on 1 May 2016. Retrieved27 May 2017.
  22. ^Elert, Glenn."Thickness of a Piece of Paper".The Physics Factbook. Archived fromthe original on 8 June 2017. Retrieved27 May 2017.
  23. ^McKenzie, Bruce G. (1989).The Hammerhill guide to desktop publishing in business. Hammerhill. p. 144.ISBN 978-0-9615651-1-4.OCLC 851074844.
  24. ^"Density of paper and paperboard". PaperOnWeb.Archived from the original on 19 October 2007. Retrieved31 October 2007.
  25. ^Hultén, B. (2011). "Sensory marketing: the multi-sensory brand-experience concept".European Business Review.23 (3):256–273.doi:10.1108/09555341111130245.A brand's sensory cues, such as the feel of high-quality paper or a heavy package, can create a multi-sensory brand experience that communicates prestige and exclusivity.
  26. ^Krishna, A. (2010).Sensory Marketing: Smells, Sounds, and the Other Five Senses That Sell. Routledge.ISBN 978-0415802482.For instance, a heavier business card might signify a more important or higher-status person... weight is frequently associated with seriousness and professionalism in a business context.
  27. ^Johnson, Arthur (1978).The Thames and Hudson manual of bookbinding. London: Thames and Hudson.OCLC 959020143.
  28. ^Martin, Sam (2004)."Paper Chase". Ecology Communications, Inc. Archived fromthe original on 19 June 2007. Retrieved21 September 2007.
  29. ^EPA (28 June 2006)."General Overview of What's in America's Trash". United States Environmental Protection Agency. Archived fromthe original on 5 January 2012. Retrieved4 April 2012.
  30. ^Groll, T. 2015In vielen Büros wird unnötig viel ausgedrucktArchived 17 August 2015 at theWayback Machine, Zeit Online, 20 June 2015.
  31. ^Effluents from Pulp Mills using Bleaching – PSL1. Health Canada DSS. 1991.ISBN 978-0-662-18734-9.Archived from the original on 5 July 2017. Retrieved21 September 2007.PdfArchived 12 September 2017 at theWayback Machine
  32. ^"Dioxins and their effects on human health".World Health Organization. June 2014.Archived from the original on 27 April 2018. Retrieved7 January 2015.More than 90% of human exposure is through food
  33. ^"World GHG Emissions Flow Chart 2010"(PDF).Ecofys.Archived(PDF) from the original on 19 October 2020. Retrieved5 July 2020.
  34. ^"World GHG Emissions 2012".SANKEY DIAGRAMS. Ecofys. 22 February 2019.Archived from the original on 19 January 2021. Retrieved5 July 2020.
  35. ^abcSustainability by numbers: Forest products at FAO. Rome: FAO. 2023.doi:10.4060/cc7561en.
  36. ^"COVID-19 leads to changes in paper and paperboard production".www.fao.org. 3 September 2021.Archived from the original on 3 November 2023. Retrieved3 November 2023.

General references

Further reading

External videos
video iconDiscussion with Mark Kurlansky onPaper: Paging Through History, June 12, 2016,C-SPAN

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