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Polonium dibromide

From Wikipedia, the free encyclopedia
Polonium dibromide
Names
Systematic IUPAC name
Polonium dibromide
Identifiers
3D model (JSmol)
  • InChI=1S/2BrH.Po/h2*1H;/q;;+2/p-2
    Key: XAIILPQZTLHLLU-UHFFFAOYSA-L
  • [Br-].[Br-].[Po+2]
Properties
PoBr2
Molar mass369.791 g mol−1
Appearancepurple-brown crystalline solid[1][2]
Melting point270 °C (518 °F; 543 K) (decomposes)[1][2] (sublimes at 110 °C)[2]
Solubilitysoluble inhydrobromic acid andketones[2]
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Polonium dibromide (also known aspolonium(II) bromide) is a chemical compound with the formulaPoBr2. This salt is a purple-brown crystalline solid at room temperature.[1][2] It sublimes (decomposing slightly) at 110 °C/30μ and decomposes when melted innitrogen gas at 270–280 °C.[2]

Preparation

[edit]

Polonium dibromide may be prepared by:

Chemistry

[edit]

Polonium dibromide forms purple solutions inhydrobromic acid (prepared similarly to solutions ofpolonium dichloride) andketones, although the latter are rapidly oxidised to polonium(IV). Solid polonium dibromide is rapidlyreduced to metallic polonium upon reaction withammonia.[2]

References

[edit]
  1. ^abcdHolleman, Arnold Frederik; Wiberg, Egon (2001), Wiberg, Nils (ed.),Inorganic Chemistry, translated by Eagleson, Mary; Brewer, William, San Diego/Berlin: Academic Press/De Gruyter, p. 594,ISBN 0-12-352651-5
  2. ^abcdefghiBagnall, K. W. (1962). "The Chemistry of Polonium".Advances in Inorganic Chemistry and Radiochemistry. New York:Academic Press. pp. 197–230.ISBN 978-0-12-023604-6. RetrievedJune 14, 2012.
Polonium(−II)
Polonium(II)
Polonium(IV)
Polonium(VI)
Salts and covalent derivatives of thebromide ion
Retrieved from "https://en.wikipedia.org/w/index.php?title=Polonium_dibromide&oldid=1146168199"
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