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Pollucite

From Wikipedia, the free encyclopedia
Zeolite mineral
Pollucite
Euhedral, tabular crystal of colorless, translucent and lustrous pollucite with frosted crystal faces fromAfghanistan (size: 2.7 x 2.4 x 1.2 cm)
General
CategoryTectosilicateminerals,zeolitegroup
FormulaCs(Si2Al)O6·nH2O
IMA symbolPol[1]
Strunz classification9.GB.05
Dana classification77.1.1.2
Crystal systemIsometric
Crystal classHexoctahedral (m3m)
H-M symbol: (4/m3 2/m)
Space groupIa3d
Unit cella = 13.67 Å; Z = 16
Identification
ColorUsually colorless; also white, grey, pink, blue or violet
Crystal habitUsually massive; rare crystals are normally trapezohedral or cubic
CleavageNone observed
FractureConchoidal to uneven
TenacityBrittle
Mohs scale hardness6.5 to 7
LusterVitreous to greasy
StreakWhite
DiaphaneityTransparent to translucent
Specific gravity2.7 to 3.0
Optical propertiesIsotropic or very weakly anisotropic
Refractive index1.508–1.528
SolubilityReadily soluble in HF; dissolves with difficulty in hot HCl
Other characteristicsSometimes weakly fluorescent under SW and LW UV
References[2][3][4][5][6]

Pollucite is azeolite mineral with the formula(Cs,Na)2Al2Si4O12·2H2O withiron,calcium,rubidium andpotassium as common substituting elements. It is important as a significant ore ofcaesium and sometimesrubidium. It forms a solid solution series withanalcime. It crystallizes in theisometric-hexoctahedral crystal system as colorless, white, gray, or rarely pink and blue masses. Well-formed crystals are rare. It has aMohs hardness of 6.5 and aspecific gravity of 2.9, with a brittle fracture and no cleavage.

Discovery and occurrence

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A pollucite ore sample held in theRoyal Ontario Museum

It was first described byAugust Breithaupt in 1846 for occurrences on the island ofElba,Italy. It is named forPollux, the twin of Castor on the grounds that it is often found associated withpetalite (previously known ascastorite).[7] The high caesium content was missed by the first analysis byKarl Friedrich Plattner in 1848,[8] but after the discovery of caesium in 1860 a second analysis in 1864 was able to show the high caesium content of pollucite.[9]

Its typical occurrence is inlithium-rich granitepegmatites in association withquartz,spodumene,petalite,amblygonite,lepidolite,elbaite,cassiterite,columbite,apatite,eucryptite,muscovite,albite andmicrocline.

About 82% of the world's known reserves of pollucite occur nearBernic Lake in Manitoba, Canada, where they are mined for their caesium content for use in caesium formate oil drilling assistance.[10] This ore is about 23%[11]: 1  to 25%[12]: 2  caesium by weight.

References

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  1. ^Warr, L.N. (2021)."IMA–CNMNC approved mineral symbols".Mineralogical Magazine.85 (3):291–320.Bibcode:2021MinM...85..291W.doi:10.1180/mgm.2021.43.S2CID 235729616.
  2. ^Mineralienatlas
  3. ^Gaines, et al. (1997)Dana's New Mineralogy, WileyISBN 978-0471193104
  4. ^Pollucite on Mindat.org
  5. ^Pollucite data on Webmineral
  6. ^Handbook of Mineralogy
  7. ^Breithaupt, August (1846)."Neue Mineralien".Annalen der Physik und Chemie.69 (11): 439–442.Bibcode:1846AnP...145..429B.doi:10.1002/andp.18461451111.
  8. ^Plattner, C. F. (1846)."Chemische Untersuchung zweier neuen, vom Herrn Prof. Breithaupt mineralogisch bestimmten Mineralien von der Insel Elba".Annalen der Physik und Chemie.145 (11):443–447.Bibcode:1846AnP...145..443P.doi:10.1002/andp.18461451112.
  9. ^Pisani, F. (1864)."Étude chimique et analyse du pollux de l'ile d'Elbe".Comptes rendus.58:714–716.
  10. ^http://www.encyclopedia.com/doc/1G1-75752682.html Original reference toMining Journal, March 2, 2001, p 160. Accessed March 28, 2009. (dead link 15 February 2022)
  11. ^Harris, Keith L. (1979).Cesium. US Department of the Interior, Bureau of Mines.
  12. ^Nichols, Ivan L.; Dean, Karl C. (1966).Volatilization of Cesium Chloride from Pollucite Ore. Vol. 6780. US Department of the Interior, Bureau of Mines.
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