Polarimetry is the measurement and interpretation of thepolarization oftransverse waves, most notablyelectromagnetic waves, such asradio orlight waves. Typically polarimetry is done on electromagnetic waves that have traveled through or have beenreflected,refracted ordiffracted by some material in order to characterize that object.[1][2]
Plane polarized light: According to thewave theory of light, an ordinaryray of light is considered to be vibrating in all planes of right angles to the direction of itspropagation. If this ordinary ray of light is passed through anicol prism, the emergent ray has its vibration only in one plane.
Polarimetry of thin films and surfaces is commonly known asellipsometry.
Polarimetry is used inremote sensing applications, such asplanetary science,astronomy, andweather radar.
Polarimetry can also be included in computational analysis of waves. For example, radars often consider wave polarization in post-processing to improve the characterization of the targets. In this case, polarimetry can be used to estimate the fine texture of a material, help resolve the orientation of small structures in the target, and, when circularly-polarized antennas are used, resolve the number of bounces of the received signal (thechirality of circularly polarized waves alternates with each reflection).
In 2003, a visible-near IR (VNIR) Spectropolarimetric Imager with anacousto-optic tunable filter (AOTF) was reported.[3] These hyperspectral and spectropolarimetric imager functioned in radiation regions spanning from ultraviolet (UV) to long-wave infrared (LWIR). In AOTFs apiezoelectric transducer converts a radio frequency (RF) signal into anultrasonic wave. This wave then travels through a crystal attached to the transducer and upon entering an acoustic absorber is diffracted. The wavelength of the resulting light beams can be modified by altering the initial RF signal.[3] VNIR and LWIRhyperspectral imaging consistently perform better as hyperspectral imagers.[4] This technology was developed at theU.S. Army Research Laboratory.[3]
The researchers reported visible near infrared system (VISNIR) data (.4-.9 micrometers) which required an RF signal below 1 W power. The reported experimental data indicates that polarimetric signatures are unique to manmade items and are not found in natural objects. The researchers state that a dual system, collecting both hyperspectral and spectropolarimetric information, is an advantage in image production for target tracking.[3]
Polarimetric infrared imaging and detection can also highlight and distinguish different features in a scene and give unique signatures of different objects. A nano-plasmonic chirped metal structure for polarimetric detection in the mid-wave and long-wave infrared dual bands can give unique characteristics about the different detected materials, objects, and surfaces.[5]
Gemologists usepolariscopes to identify various properties of gems under examination. Proper examination may require the gem to be inspected in various positions and angles.[6] A gemologist's polariscope is a vertically oriented device, usually with twopolarizing lenses with one over the other with some space in between. A light source is built into the polariscope underneath the bottom polarizing lens and pointing upwards. A gemstone will be placed on top of the lower lens and may be properly examined by looking down at it through the top lens. To operate the polariscope, a gemologist may turn the polarizing lenses by hand to observe various characteristics about a gemstone. Polariscopes make use of their polarizing filters to reveal properties of a gem about how it affects light waves passing through it.
A polariscope may be first used to determine the optic character of a gem and whether it is singly refracting (isotropic), anomalously doubly refracting (isotropic), doubly refracting (anisotropic), or aggregate. If the stone is doubly refracting and is not an aggregate, the polariscope may be used to further determine the optic figure of the gemstone, or whether it is uniaxial or biaxial. This step may require use of aloupe, also known as a conoscope.[7] Finally, a polariscope can be used to detect thepleochroism of a gemstone, although adichroscope may be preferred for this purpose as it may show pleochroic colors side by side for easier identification.
Apolarimeter is the basicscientific instrument used to make these measurements, although this term is rarely used to describe a polarimetry process performed by a computer, such as is done in polarimetricsynthetic aperture radar.
Polarimetry can be used to measure variousoptical properties of a material, including linearbirefringence, circular birefringence (also known asoptical rotation or optical rotary dispersion),linear dichroism,circular dichroism andscattering.[8] To measure these various properties, there have been many designs of polarimeters, some archaic and some in current use. The most sensitive are based oninterferometers, while more conventional polarimeters are based on arrangements ofpolarising filters,wave plates or other devices.
Polarimetry is used in many areas of astronomy to study physical characteristics of sources includingactive galactic nuclei andblazars,exoplanets, gas anddust in theinterstellar medium,supernovae,gamma-ray bursts,stellar rotation,[9] stellar magnetic fields,debris disks, reflection in binary stars[10] and thecosmic microwave background radiation. Astronomical polarimetry observations are carried out either as imaging polarimetry, where polarization is measured as a function of position in imaging data, or spectropolarimetry, where polarization is measured as a function ofwavelength of light, or broad-band aperture polarimetry.
Optically active samples, such as solutions of chiral molecules, often exhibit circularbirefringence. Circular birefringence causes rotation of the polarization of plane polarized light as it passes through the sample.
In ordinary light, the vibrations occur in all planes perpendicular to the direction of propagation. When light passes through aNicol prism its vibrations in all directions except the direction of axis of the prism are cut off. The light emerging from the prism is said to beplane polarised because its vibration is in one direction. If two Nicol prisms are placed with their polarization planes parallel to each other, then the light rays emerging out of the first prism will enter the second prism. As a result, no loss of light is observed. However, if the second prism is rotated by an angle of 90°, the light emerging from the first prism is stopped by the second prism and no light emerges. The first prism is usually called thepolarizer and the second prism is called theanalyser.
A simple polarimeter to measure this rotation consists of a long tube with flatglass ends, into which the sample is placed. At each end of the tube is aNicol prism or other polarizer.Light is shone through the tube, and the prism at the other end, attached to an eye-piece, is rotated to arrive at the region of complete brightness or that of half-dark, half-bright or that of complete darkness. The angle of rotation is then read from a scale. The same phenomenon is observed after an angle of 180°. Thespecific rotation of the sample may then be calculated. Temperature can affect the rotation of light, which should be accounted for in the calculations.
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