Movatterモバイル変換


[0]ホーム

URL:


Jump to content
WikipediaThe Free Encyclopedia
Search

Plutonium(III) phosphide

From Wikipedia, the free encyclopedia
(Redirected fromPlutonium phosphide)
Plutonium compound
Plutonium(III) phosphide
Names
Other names
Plutonium monophosphide[1]
Identifiers
3D model (JSmol)
  • InChI=1S/P.Pu
    Key: PLULROOTRMPUIM-UHFFFAOYSA-N
  • [Pu]#[P]
Properties
PPu
Molar mass274.97
AppearanceBlack crystals
Density10.08 g/cm3
Structure
Cubic
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Plutonium(III) phosphide is a binaryinorganic compound ofplutonium andphosphorus with the formula PuP.[2][3]

Synthesis

[edit]

Fusion of excess phosphorus and powdered plutonium, followed by distillation of unreacted phosphorus:[4]

4 Pu + P4 → 4 PuP

Passingphosphine through heatedplutonium hydride:

PuH3 + PH3 → PuP + 3 H2

Physical properties

[edit]

Plutonium(III) phosphide forms black crystals of acubic system, space groupFm3m,[5] cell parameters a = 0.5660 nm, Z = 4, structure of theNaCl type.[6][7]

References

[edit]
  1. ^Lam, D. J.; Fradin, F. Y.; Kruger, O. O. (10 November 1969). "Magnetic Properties of Plutonium Monophosphide".Physical Review.187 (2):606–610.Bibcode:1969PhRv..187..606L.doi:10.1103/PhysRev.187.606.ISSN 0031-899X.
  2. ^Nuclear Science Abstracts. Oak Ridge Directed Operations, Technical Information Division. 1969. Retrieved10 January 2022.
  3. ^Fundamental Nuclear Energy Research.United States Atomic Energy Commission. 1964. p. 235. Retrieved10 January 2022.
  4. ^Reactor Fuel Processing. U.S. Argonne National Laboratory. 1964. p. 188. Retrieved10 January 2022.
  5. ^"mp-926: PuP (cubic, Fm-3m, 225)".materialsproject.org. Retrieved10 January 2022.
  6. ^NBS Monograph.National Bureau of Standards. 1959. p. 65. Retrieved10 January 2022.
  7. ^Gorum, A. E. (10 February 1957). "The crystal structures of PuAs, PuTe, PuP and PuOSe".Acta Crystallographica.10 (2): 144.Bibcode:1957AcCry..10..144G.doi:10.1107/S0365110X5700047X.
Phosphides
Other compounds
Plutonium(II)
  • PuH2
  • [K(2.2.2-crypt)][PuCp'3]
Plutonium(III)
Organoplutonium(III) componunds
Plutonium(III,IV)
Plutonium(IV)
Organoplutonium(IV) compounds
Hexachloroplutonates(IV)
Plutonium(V)
Plutonium(VI)
Plutonyl compounds
Plutonium(VIII)
Binary phosphides
Ternary phosphides
Quaternary phosphides
Quinary phosphides
See also
Retrieved from "https://en.wikipedia.org/w/index.php?title=Plutonium(III)_phosphide&oldid=1297728913"
Categories:
Hidden categories:

[8]ページ先頭

©2009-2025 Movatter.jp