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Platinum(IV) bromide

From Wikipedia, the free encyclopedia
Platinum(IV) bromide
Names
IUPAC name
Platinum(IV) bromide
Other names
Platinic bromide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.066.481Edit this at Wikidata
EC Number
  • 273-151-5
  • InChI=1S/4BrH.Pt/h4*1H;/q;;;;+4/p-4
    Key: SNPHNDVOPWUNON-UHFFFAOYSA-J
  • Br[Pt](Br)(Br)Br
Properties
PtBr4
Molar mass514.694 g/mol
Appearancebrownish-black crystals
Melting pointdecomposes at 180°C
0.41 g/100mL @ 20°C
Solubilityslightly soluble inethanol,diethyl ether[1]
Hazards
GHS labelling:
GHS05: Corrosive
Danger
H314
P260,P264,P280,P301+P330+P331,P303+P361+P353,P304+P340,P305+P351+P338,P310,P321,P363,P405,P501
NFPA 704 (fire diamond)
Flash pointnon-flammable
Safety data sheet (SDS)[1]
Related compounds
Otheranions
Platinum(IV) fluoride
Platinum(IV) chloride
Platinum(IV) iodide
Othercations
Nickel(II) bromide
Palladium(II) bromide
Related compounds
Platinum(II) bromide
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound

Platinum(IV) bromide is theinorganic compound with theformula PtBr4. It is a brown solid. It is a little-used compound mainly of interest for academic research.[2] It is a component of a reagent used inqualitative inorganic analysis.[3]

In terms of structure, the compound is an inorganic polymer consisting of interconnected PtBr6 octahedra.

References

[edit]
  1. ^Lide, David R. (1998),Handbook of Chemistry and Physics (87 ed.), Boca Raton, Florida: CRC Press, p. 481,ISBN 0-8493-0594-2, retrieved2008-06-19
  2. ^Lagrow, Alec P.; Knudsen, Kristian Rahbek; Alyami, Noktan M.; Anjum, Dalaver H.; Bakr, Osman M. (2015). "Effect of Precursor Ligands and Oxidation State in the Synthesis of Bimetallic Nano-Alloys".Chemistry of Materials.27 (11):4134–4141.doi:10.1021/acs.chemmater.5b01247.hdl:10754/553018.
  3. ^Wenger, P. E. (2007),Reagents for Qualitative Inorganic Analysis, Read Country Books, p. 242,ISBN 978-1-4067-4847-5, retrieved2008-06-18
Pt(−II)
Pt(0)
Pt(II)
Organoplatinum(II) compounds
Pt(IV)
Hexachloroplatinates
Pt(V)
Pt(VI)
Salts and covalent derivatives of thebromide ion
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