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Phosphinate

From Wikipedia, the free encyclopedia
Phosphinate
Sodium hypophosphite
Identifiers
3D model (JSmol)
ChemSpider
UNII
  • InChI=1S/H3O2P/c1-3-2/h3H2,(H,1,2)/p-1
    Key: ACVYVLVWPXVTIT-UHFFFAOYSA-M
  • [O-][PH2]=O
Properties
H2O2P
Molar mass64.988 g·mol−1
Related compounds
Related compounds
phosphite;phosphine oxide
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Phosphinates orhypophosphites are a class ofphosphorus compounds conceptually based on the structure ofhypophosphorous acid.IUPAC prefers the term phosphinate in all cases, however in practice hypophosphite is usually used to describe inorganic species (e.g.sodium hypophosphite), while phosphinate typically refers toorganophosphorus species.

Hypophosphites

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Thehypophosphiteion is(H
2
PO
2
)
. The salts are prepared by heating white phosphorus in warm aqueous alkali e.g. Ca(OH)2:[1]

P4 + 2 Ca(OH)2 + 4 H2O → 2 Ca(H2PO2)2 + 2 H2

Hypophosphites arereducing agents:[1]

(H
2
PO
2
)
+ 3 OH(HPO
3
)2−
+ 2 H2O + 2 e

Hypophosphites are used inelectroless nickel plating as the reducing agent to deposit for example Ni metal from Ni salts.[1] The hypophosphite ion is thermodynamically unstable, anddisproportionates on heating tophosphine andphosphatesalts:

2H
2
PO
2

→ PH3 +HPO
4
2−

See also

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References

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  1. ^abcGreenwood, Norman N.; Earnshaw, Alan (1997).Chemistry of the Elements (2nd ed.).Butterworth-Heinemann. p. 512.ISBN 978-0-08-037941-8.
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