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Phosphide silicide

From Wikipedia, the free encyclopedia

Phosphide silicides orsilicide phosphides orsilicophosphides are compounds containinganions composed ofsilicide (Si4−) andphosphide (P3−). They can be considered asmixed anion compounds. They are distinct from thephosphidosilicates, which have the phosphorus bonded to the silicon. Related compounds include thephosphide carbides,germanide phosphides,nitride silicides, andantimonide silicides.

One preparation method is to heat a metal phosphide with silicon in a silica tube. Phosphorus must be prevented from evaporating. Another method is to use a liquid tin flux.

Phosphide silicides may be present as minerals. They are under investigation as photovoltaic materials.[1]

List

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formulasystemspace groupunit cell Åvolumedensitycommentref
Li10.68Si5PorthorhombicPnmaa = 10.2434, b = 4.2788, c = 23.9767 Z=41050.891.52grey metallic; Si5 rings[2]
Fe5PSihexagonalP63cma=6.766 c=12.456 Z=6493.836.82[3]
Fe5(P,Si)3[4]
Fe7(P,Si)3[5]
(Fe,Ni)8(P,Si)3Perryite[6]
Ni2PSiorthorhombicPbcaa=4.985 b=5.871 c=13.667399.955.86[7]
ZrCuSiPP4/nmma=3.5671c=9.4460metallic[8]
La4(P1−xSix)3-zcubicI43d[9]
Ce4(P1−xSix)3-zcubicI43d[9]
Ce4P1.77Si1.23cubicI43da=8.9359 Z=4713.536.0474black[9]
Pr4(P1−xSix)3-zcubicI43d[9]
Nd4(P1−xSix)3-zcubicI43d[9]
Gd4Co13(Si, P)9P6m2a = 10.419,c = 37.27[10]
Sm4Co13(Si, P)9P6m2[10]
Tb4Co13(Si, P)9P6m2[10]
Dy4Co13(Si, P)9P6m2[10]
Ho4Co13(Si, P)9P6m2[10]
Er4Co13(Si, P)9P6m2[10]
Hf27Si6P10Immma = 3.5739, b = 18.623, c = 23.081, Z = 211.443P2 groups[11]

References

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  1. ^Martinez, Aaron D.; Ortiz, Brenden R.; Johnson, Nicole E.; Baranowski, Lauryn L.; Krishna, Lakshmi; Choi, Sukgeun; Dippo, Patricia C.; To, Bobby; Norman, Andrew G.; Stradins, Paul; Stevanovic, Vladan (January 2015)."Development of ZnSiP$_{\mathbf 2}$ for Si-Based Tandem Solar Cells".IEEE Journal of Photovoltaics.5 (1):17–21.doi:10.1109/JPHOTOV.2014.2362305.ISSN 2156-3381.S2CID 6853210.
  2. ^Fässler, Thomas Friedrich; Eickhoff, Henrik; Toffoletti, Lorenzo; Klein, Wilhelm; Raudaschl-Sieber, Gabi (2022-01-20)."Planar Si5 and Ge5 Pentagons beside Isolated Phosphide Anions in Lithium Phosphide Tetrelides Li10+xSi5P and Li10+xGe5P".Zeitschrift für anorganische und allgemeine Chemie.648 (10) zaac.202100376.Bibcode:2022ZAACh.648E0376E.doi:10.1002/zaac.202100376.ISSN 0044-2313.S2CID 246183043.
  3. ^Ellner, M.; El-Boragy, M. (June 1992)."Über die eisenhaltigen vertreter des strukturtyps Pd5Sb2".Journal of Alloys and Compounds (in German).184 (1):131–138.doi:10.1016/0925-8388(92)90461-H.
  4. ^"Unnamed (Fe Phosphide-Silicide II)".www.mindat.org. Retrieved2021-09-22.
  5. ^"Unnamed (Fe Phosphide-Silicide I)".www.mindat.org. Retrieved2021-09-22.
  6. ^Dambaev, V. A.; Ulyanov, A. A. (March 1998)."Opaque Minerals in Enstatite Chondrites: Perryite - Silicophosphide NI and Fe in PCA 91085 and Conditions of Its Formation".Lunar and Planetary Science Conference.29 (1282): 1282.Bibcode:1998LPI....29.1282D.
  7. ^None Available (2017),Materials Data on SiNi2P by Materials Project, The Materials Project, LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States),doi:10.17188/1262921, retrieved2021-09-22
  8. ^Abe, Hideki; Yoshii, Kenji (May 2002)."Structure and Electrical Transport Property of a Silicopnictide ZrCuSiP".Journal of Solid State Chemistry.165 (2):372–374.Bibcode:2002JSSCh.165..372A.doi:10.1006/jssc.2002.9553.
  9. ^abcdeChizhov, Pavel S.; Khasanova, Nellie R.; Baitinger, Michael; Schnelle, Walter; Prots, Yuri; Burkhardt, Ulrich; Antipov, Evgeny V.; Grin, Yuri (2006-09-01)."Ce 4 (P 1- x Si x ) 3- z: A First Example for the Stabilization of the Anti-Th 3 P 4 Type Structure by Substitution in the Non-Metal Substructure".Inorganic Chemistry.45 (18):7210–7216.doi:10.1021/ic060726h.ISSN 0020-1669.PMID 16933921.
  10. ^abcdefJeitschko, Wolfgang; Jakubowski-Ripke, Ursula; Albering, Jörg (June 2011)."Crystal Structure of the Silicide Phosphide Gd4Co13(Si, P)9, the Isotypic Lanthanoid Cobalt Silicide Phosphides Ln4Co13(Si, P)9 (Ln = Sm, Tb, Dy, Ho, Er), and the Uranium Iron Phosphide U4Fe13P9".Zeitschrift für anorganische und allgemeine Chemie.637 (7–8):895–900.Bibcode:2011ZAACh.637..895J.doi:10.1002/zaac.201000404.
  11. ^Huang, Chang-Cang; Neuhausen, Jörg; Tremel, Wolfgang (2000)."Hf27Si6P10, a novel metal-rich compound with P2 groups".Chemical Communications (1):17–18.doi:10.1039/a906873b.
Binary phosphides
Ternary phosphides
Quaternary phosphides
Quinary phosphides
See also
Salts and covalent derivatives of thesilicide ion
SiH4
+H		He
LiSiBe2SiSiB3
SiB6
+B		SiC
+C		Si3N4
-N
+N		SiO2SiF4Ne
NaSiMg2SiAlSi4−SiP, SiP2
-P
+P		SiS2
-S		SiCl4Ar
KSiCaSi
CaSi2		ScSi Sc5Si3 Sc2Si3 Sc5Si4TiSi
TiSi2		V3Si V5Si3, V6Si5, VSi2, V6Si5Cr3Si Cr5Si3, CrSi, CrSi2MnSi,MnSi2, Mn9Si2, Mn3Si,Mn5Si3, Mn11Si9FeSi2
FeSi
Fe5Si3
Fe2Si
Fe3Si		CoSi,CoSi2,Co2Si, Co3SiNiSi,more…Cu17Si3, Cu56Si11, Cu5Si, Cu33Si7, Cu4Si, Cu19Si6, Cu3Si, Cu87Si13ZnGaGeSi
+Ge		SiAs, SiAs2
-As
+As		SiSe2 SiSeSiBr4Kr
RbSiSrSi2YSi Y5Si3, Y5Si4, Y3Si5, YSi1.4ZrSi Zr5Si3, Zr5Si4,ZrSi2, Zr3Si2, Zr2Si, Zr3SiNb4Si Nb5Si3MoSi2
Mo3Si Mo5Si3		TcRuSi Ru2Si, Ru4Si3, Ru2Si3RhSi Rh2Si, Rh5Si3, Rh3Si2, Rh20Si13PdSi Pd5Si, Pd9Si2, Pd3Si, Pd2SiAgCdInSnSbTeSi2 Te2Si3SiI4Xe
CsSiBa2Si BaSi2, Ba5Si3 Ba3Si4*Lu5Si3HfSi Hf2Si, Hf3Si2, Hf5Si4, HfSi2Ta9Si2, Ta3Si, Ta5Si3WSi2 W5Si3ReSi Re2Si, ReSi1.8 Re5Si3OsSiIrSiPtSiAuHgTlPbBiPoAtRn
FrRa**LrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg
 
*LaSi2 La5Si3, La3Si2, La5Si4, LaSiCeSi2 Ce5Si3, Ce3Si2, Ce5Si4,CeSi, Ce3Si5PrSi2 Pr5Si3, Pr3Si2, Pr5Si4, PrSiNdSi Nd5Si3, Nd5Si4, Nd5Si3, Nd3Si4, Nd2Si3, NdSixPmSmSi2 Sm5Si4, Sm5Si3, SmSi, Sm3Si5Eu?GdSi2 Gd5Si3, Gd5Si4, GdSiTbSi2 SiTb, Si4Tb5, Si3Tb5DySi2 DySiHoSi2 Ho5Si3, Ho5Si4, HoSi, Ho4Si5ErSi2 Er5Si3, Er5Si4, ErSiTm?YbSi Si1.8Yb, Si5Yb3, Si4Yb3, Si4Yb5, Si3Yb5
**AcThSiPaSiUSi2NpSi2PuSiAmCmBkCfEsFmMdNo
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