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Phosphide iodide

From Wikipedia, the free encyclopedia
Class of chemical compounds

Phosphide iodides oriodide phosphides are compounds containinganions composed ofiodide (I−) andphosphide (P3−). They can be considered asmixed anion compounds. They are in the category ofpnictidehalides. Related compounds include thephosphide chlorides,arsenide iodidesantimonide iodides andphosphide bromides.

Phosphorus can form clusters or chains in these compounds, so that some are 1-dimensional or fibrous.

Phosphide iodides are often metallic, black or dark red in colour.

List

[edit]
formulasystemspace groupunit cell Åvolumedensitycommentref
[Si40P6]I6.5cubicPm3na=10.1293 Z=11039.33.412clathrate[1]
K4P21IorthorhombicCcmma = 12.853;b = 21.795;c = 9.748 Z = 42730.72.271ruby red;sensitive to air[2]
Ca2PItrigonalR3ma=4.30 c=22.173.2yellow[3]
Ca3PI3cubicI4132a=12.31 Z=83.78colourless[3]
Cu2P3I2monoclinicP21ca = 15.343,b = 12.925,c = 15.260, β = 116.38°,Z = 16band gap 0.72 eV; Cu ion conductor[4][5][6]
Cu3P15I2monoclinicP21/na=9.667, b=19.475, c=9.886, β =108.75(2)°, Z=41762.4grey[5][7]
(CuI)3P12monoclinicP21a=12.846 b=13.857 c=9.651β=109.43 Z=41620.23.866shiny[5]
(CuI)2P14monoclinicP21/ca = 9.919, b = 9.718, c = 16.478, β = 105.71°, Z = 41529.03.539[8]
(CuI)5P16S[9]
(CuI)3P4S4hexagonalP63cma=19.082,c=6.691Z=62109.9[10]
(CuI)8P12monoclinicP121/c1a=15.343, b=12.925, c=15.26, β=116.384.64[11]
Ge38P8I8CubicP43na=10.507silvery[12]
(CuI)5P16Se[9]
(CuI)2P8Se3Pbcma=9.1348 b=12.351 c=13.873 Z=41565.23.673red; melt 408 °C; P8Se3 clusters[13]
(CuI)3P4Se4hexagonalP63cma = 19.601,c = 6.7196,Z = 6orange[14]
Zn3PI3cubicF42ma=5.9454.87dark grey; dec 300 °C[15]
(ZnI2)6ZnSP4S3[11]
(ZnI2)6ZnSeP4Se3cubicF43ca=19.5427463.14.325brown[11]
Rb4P21IorthorhombicCcmma = 13.281;b = 21.868;c = 9.771 Z=42838.12.619dark red[2]
Sr2P7IcubicP213a=10.25dark red; contains heptaphosphanortricyclane[16]
Zr6I14PorthorhombicCmca[17]
Ag2P3I2monoclinicAg ion conductor[4]
(AgI)2Ag3PS4hexagonalP63mca=7.395 c=12.224 Z=2579.1Ag ion conductor[18]
Cd2P3ImonoclinicC2/ca=8.255 b=9.304 c=7.514β =99.66[19]
Cd3PI3hexagonalP63mcband gap 2.44 eV[20]
Cd4P2I3orthorhombicPbcaa=12.890 b=12.725 c=12.654P24−[19]
SnIPsoft and flexible; double helix SnI+ and P−; band gap 1.9 eV[21][22]
Sn24P19.3I8cubicPm3na=10.9554[23]
Sn24P19.3BrxI8−xcubicPm3n[24]
Sn24P19.3(2)ClyI8−y (y ≤ 0.8)cubicPm3n[24]
Sn20Zn4P20.8I8cubicPm3na=10.883 Z=1[25]
Sn17Zn7P22I8cubicPm3na=10.8458 Z=1[25]
Sn14In10P22I8cubicPm3na=11.0450 Z=11347.45.535black[26]
Sn14In10P21.2I8P42/ma=24.745,c=11.067,Z=567765.521black[26]
[Ge30.5Sn7.7P7.75]I7.88cubicPm3na=10.721 Z=1[27]
Sn24AsxP19.3−xI8cubicPm3na = 10.9358—11.1495[28]
Cs0.35Zr6I14PorthorhombicCmcaa=15.934 b=14.287 c=12.939 Z=4black[17]
Ba2P7ImonoclinicP21/ma=6.3538 b=6.8990 c=12.0392β =95.515 Z=2524.933.912orange-yellow; water sensitive[29]
Ba3P3I2orthorhombicPnmaa = 17.195,b = 4.624,c = 14.272,Z = 4,[30]
Ba5P5I3monoclinicC2/ma = 42.664,b = 4.56.3,c = 9.431,β = 92.20,Z = 4[30]
La2PI2trigonalP3m1a=4.236 c=10.121 Z=1157.254.95[31]
Eu2PIR3ma = 4.445,c = 23.12.6,Z = 3[32]
Eu2P7IcubicP213dark red; contains heptaphosphanortricyclane; band gap 1.7 eV[16]
Au7P10ItrigonalP31ma=6.180 c=11.122 Z=1[33]
Hg9P5I6monoclinica=13.112 b=12.486 c=17.031β=119.90[34]
Hg4ZnPI4monoclinicP21a = 7.850, b = 12.719, c = 7.861, β = 119.52°, Z = 2like Millon phases[35]
Hg7Ag2P8I6monoclinicC12/m1a=13.146 b=11.037 c=8.336β=102.210 Z=21182.17.386black[36]
Hg12Ag41P88I41cubicFm3a=26.705 Z=4190455.147dark red; air stable; P113− clusters[37]
HgAg6P20I2monoclinicP21/ma = 6.718,b = 27.701,c = 7.383,β = 113.98°,Z = 2[38]

References

[edit]
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Binary phosphides
Ternary phosphides
Quaternary phosphides
Quinary phosphides
See also
Salts and covalent derivatives of theiodide ion
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