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Oxalate chloride

From Wikipedia, the free encyclopedia
Class of chemical compounds

Anoxalate chloride oroxalato chloride is amixed anion compound contains bothoxalate andchlorideanions.

Related compounds includeoxalate fluorides[1] andoxalate bromides.[2]

Production

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Oxalate chlorides may be produced by treating an oxalate salt with concentrated hydrochloric acid, or with a metal oxide dissolved inoxalic acid andhydrochloric acid solutions that are evaporated.[3]

List

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nameformulacrystalspace groupcellvolumedensitycommentref
NovgorodovaiteCa2(C2O4)Cl2•2H2OmonoclinicI2/ma=6.936 b=7.382 c=7.443 β=94.3°loses water over 205°C; refract: α=1.500 β=1.545 γ=1.568 2V=71° (−)[4][5][6]
Ca2(C2O4)Cl2•7H2OtriclinicP1a = 7.3928b = 8.9925c = 10.484α = 84.070β = 70.95γ = 88.545°655.3looses water at 25°C to 2H2O; refract: α=1.571 β=1.648 γ=1.718 2V=87° (−)[4][7]
Ca4(C2O4)3Cl2•8H2Odubious[4]
octakis(ethyl(dimethyl)ammonium) dodecakis(μ-oxalato)-tetrachloro-tetra-chromium-tetra-manganese[NH(CH3)2(C2H5)]8[Mn4Cl4Cr4(C2O4)12]monoclinicP21a=13.8321b=17.1042c=20.4209β=91.874°[8]
octakis(diethyl(methyl)ammonium) dodecakis(μ-oxalato)-tetrachloro-tetra-chromium-tetra-manganese[NH(CH3)(C2H5)2]8[Mn4Cl4Cr4(C2O4)12]monoclinicP21a=14.1863b=17.3479c=20.4140β=91.937°[8]
DABCO=1,4-diazabicyclo[2.2.2]octane;(DABCO-H+)2(DABCO-2H2+)[MnII(CH3OH)(Cl−)CrIII(oxalate)3]2−2(CH3OH)triclinicP1a=8.093b=9.070c=19.574α=83.471°β=89.875°γ=86.765°[9]
tetrakis(methylammonium) tetrakis(μ-oxalato)-octachloro-tetra-iron(iii) pentahydrate(MeNH3)2[Fe2(ox)2Cl4]·2.5H2OmonoclinicP21/ca 10.7832b 13.913c 13.0578β 104.060°[10]
methylammonium (μ-hydroxo)-bis(μ-oxalato)-dichloro-di-iron(iii) trihydrateMeNH3[Fe2(OH)(ox)2Cl2]·2H2OmonoclinicCca=8.945b=14.936c=12.408β=108.531°[10]
methylammonium oxonium bis(μ-oxalato)-(μ-oxo)-dichloro-di-iron(iii) dihydrate(H3O)(MeNH3)[Fe2O(ox)2Cl2]·3H2OorthorhombicFdd2a=14.914b=23.507c=9.261[10]
DMF = dimethylformamideFe2(C2O4)Cl4(DMF)4triclinicP1a=8.3919b=8.7834c=11.2881α=70.248°β=71.993°γ=64.423°[11]
(dimim)2[Fe2Cl4(μ-ox)]ionic liquid[12]
L2=1,4-bis(imidazol-1-ylmethyl)benzene

bis(1,1'-(1,4-Phenylenebis(methylene))bis-1H-imidazol-3-ium) (μ2-oxalato)-tetrachloro-bis(oxalato)-di-iron(iii)

(H2-L2)2{Fe2(C2O4)3Cl4}triclinicP1a=10.6758b=10.7457c=10.8774α=113.219°β=109.138°γ=99.294° Z=11020.81.624emerald[13]
tetramelaminium trioxalatoferrate(III) chloride dihydrate(C3H7N6)4{Fe(C2O4)3}Cl·2H2OmonoclinicP21/ca=11.597b=22.299c=13.655β=94.344° Z=435211.698green[14]
methylammonium (μ-aqua)-tris(μ-chloro)-(μ-oxalato)-iron(iii)-potassiumK(MeNH3)[Fe(ox)Cl3(H2O)monoclinicP21/ma=8.725b=7.508c=9.026β=112.421°[10]
diethylmethylammonium[NH(CH3)(C2H5)2][FeCl2(C2O4)]monoclinicP21/ca=8.5125 b=10.775 c=14.9703β=104.798° Z=41327.61.516yellow; proton conductor[15]
bis(Tetramethylammonium) bis(μ2-oxalato)-tetrachloro-di-iron(iii)Me4N[FeIII(ox)Cl2]monoclinicP21/ca=7.9441b=8.6093c=17.8251β=91.869[16]
hexakis(Triethylammonium) hexakis(μ2-oxalato)-dodecachloro-hexa-iron(iii)Et3NH[FeIII(ox)Cl2]triclinicP1a=10.9609b=14.4602c=14.5780α=85.006°β=78.845°γ=83.0191[16]
Triethylammonium (μ2-oxalato)-dichloro-iron(iii)Et3NH[FeIII(ox)Cl2]orthorhombicFdd2a=13.5878b=37.972c=10.8210[16]
bis(Tetra-n-butylammonium) bis(μ2-oxalato)-tetrachloro-di-iron(iii)n-Bu4N[FeIII(ox)Cl2]monoclinicP21/ca=8.8836b=15.1939c=17.968β=91.556°[16]
[Fe(oxalato)Cl2]3(3,5-dimethylpyrazole)2(3,5- dimethylpyrazolium)2monoclinicC2/ca=19.527 b=11.867 c=19.429β=115.66° Z=44058.201.684green[17]
BETS = Bis(ethylenedithio)tetraselenafulvaleneκ-BETS2[FeIII(C2O4)Cl2]black; metallic;[18]
bis(2-(5,6-dihydro[1,3]dithiolo[4,5-b][1,4]dithiin-2-ylidene)-5,6-dihydro[1,3]dithiolo[4,5-b][1,4]dithiin-1-ium) bis(μ-oxalato)-tetrachloro-di-iron(iii)[BEDT-TTF][Fe(C2O4)Cl2]triclinicP1a=8.896b=11.401c=11.427α=112.062°β=103.775°γ=100.328°[19]
BEDT-TTF = Bis(ethylenedithio)tetrathiafulvalene(BEDT-TTF)[Fe(C2O4)Cl2](CH2Cl2)monoclinicP21/ca=8.858b=11.012c=14.932β=103.39°[20]
tris(ethylenediamine)cobalt(III)chloride oxalate trihydrate[Co(en)3]Cl(C2O4)·3H2OmonoclinicC2/ca = 19.932b = 9.3344c = 19.088β = 96.846°Z = 8[21]
dpyam=di-2-pyridylamine; (μ2-Oxalato)-bis(di-2-pyridylamine)-dichloro-di-copper(ii)Cu2(dpyam)2(μ-C2O4)(Cl)2triclinicP1a=7.4122b=8.6586c=9.8002α=87.900°β=72.022°γ=71.845°[22]
L = 3,5-dimethyl-1H-pyrazoleCu2(C2O4)(L)2Cl2(MeOH)2triclinicP1a=7.244b=8.039c=8.848α=92.16°β=92.73°γ=96.21°[23]
bpy=bipyridine[Fe(bpy)3]2[NbO(C2O4)3]Cl·11H2O[24]
[Fe(bpy)3]2[NbO(2O4)3]Cl·12H2OorthorhombicP212121a=14.975 b=21.708 c=22.351 Z=472661.530dark red[24]
[Co(bpy)3]2[NbO(C2O4)3]Cl·11H2OmonoclinicP21/ca=23.548 b=13.631 c=22.812β=101.0471871.536orange red[24]
[Co(bpy)3]2[NbO(C2O4)3]Cl·12H2OorthorhombicP212121a=15.103 b=22.075 c=22.386 Z=474631.495brown[24]
[Ni(bpy)3]2[NbO(C2O4)3]Cl·11H2OmonoclinicP21/ca=23.875 b=13.265 c=23.115β=101.69 Z=471691.539pink[24]
[Ni(bpy)3]2[NbO(C2O4)3]Cl·12H2OorthorhombicP21212115.058 b=22.039 c=22.398 Z=474331.500dark pink[24]
[Cu(bpy)3]2[NbO(C2O4)3]Cl·12H2OorthorhombicP212121a=15.035 b=22.267 c=22.538 Z=475451.487blue[24]
[Zn(bpy)3]2[NbO(C2O4)3]Cl·11H2OmonoclinicP21/c24.070 b=13.332 c=23.168 β=102.19 Z=472671.530pink[24]
[Zn(bpy)3]2[NbO(C2O4)3]Cl·12H2O[24]
tris(Tetraethylammonium) tetrakis(μ3-sulfido)-(oxalato-O,O')-trichloro-cyano-tri-iron-molybdenum(Et4N)5{[C2O4)MoFe3S4Cl2]2(μ-CN)(μ-S)}monoclinicP21/na=10.331b=22.580c=19.083β=91.97°double cubane structure[25]
(μ2-Oxalato)-dichloro-bis(η6-p-cymene)-di-ruthenium[Ru2(μ-η4-C2O4)Cl2(η6-p-PriC6H4Me)2]monoclinicP21/na=7.571b=8.998c=16.528β=95.52° Z=21120.73yellow[26]
chloro-(oxalato)-tris(pyridine)-rhodiummer-[Rh(C2O4)Cl(py)3]orthorhombicP212121a=9.9999b=12.0930c=14.9368 Z=41806.21.705yellow[27]
CHLOROPENTAAMMINECHROMIUM(III) BIS(OXALATO)PALLADATE[Cr(NH3)5Cl][Pd(C2O4)2]triclinica = 3.225b = 10.290c = 11.390 α = 116.5° β = 97.9° γ = 91.2°334.5[28]
C(NH2)3Cd(C2O4)Cl(H2O)·H2OtriclinicP1a=6.8136b=7.4890c=10.0515α=84.082°β=77.806°γ=88.813°band gap 3.76 eV[29]
SnC2O4Cl2[30]
SnC2O4Cl2 . CuBr2 1/4EtOHgreen[30]
SnC2O4Cl2 . CuCl2 . H2Ogreen[30]
SnC2O4Cl2 . CoBr2 1/8EtOHrose colour[30]
(Et4N)2C2O4 . SnCl2F2 . 2H2O:white[30]
(Me4N)2Sn(C2O4)Cl2white[30]
(Et4N)2Sn(C2O4)Cl2 .(Et4N)2C2O4(SnCl4)2 . EtOHwhite[30]
Sn(C2O4)2 . 2[SnCl4 . (Pyridine)2]white[30]
(Et4N)2SnCl6 . (Et4N)2C2O4 . 2SnC2O4(OH)2white[30]
(NH4)2Sb(C2O4)Cl3orthorhombicP212121a=8.6961 b=8.7844 c=13.5956 Z=41038.572.253[31]
K2Sb(C2O4)Cl3orthorhombicP212121a=8.3966 b=8.6023 c=13,6342 Z=4984.802.660[31]
Rb2Sb(C2O4)Cl3orthorhombicP212121a=8.6769 b=8.8485 c=13.8014 Z=41059.643.053birefringence 0.22@546 nm;NLO 2.1 × KH2PO4[31]
Ba2Mn2Cl2(C2O4)3·4H2OmonoclinicC2/ca=22.916b=8.248c=9.904β=99.53°[32]
Ba2Fe2Cl2(C2O4)3·4H2OmonoclinicC2/ca=22.798b=8.297c=9.849β=99.90°[32]
Ba2Co2Cl2(C2O4)3·4H2OmonoclinicC2/ca=22.675b=8.230c=9.757β=100.00°purple[33][32]
BaCd(C2O4)1.5Cl(H2O)2monoclinicC2/ca=23.101b=8.253c=10.040β 99.14°band gap 4.53 eV[29]
La(C2O4)ClmonoclinicP21/na=8.489b=16.19c=5.880β=104.14°[34][35]
La(C2O4)Cl·3H2O[36]
Ce(C2O4)Cl[1]
Ce(C2O4)Cl·3H2O[36]
Pr(C2O4)Cl·3H2Ostable to 163°C[36][1]
Nd(C2O4)Cl·3H2Ostable to 167°C; dec 510° to NdOCl[36][1][37]
Sm(C2O4)Cl·3H2Ostable to 174°C; dec at 347° to EuC2O4[36][1]
Eu(C2O4)Cl·3H2Ostable to 178°C[36][1]
Gd(C2O4)Cl·3H2O[36][38]
(Et4N)2Sn(C2O4)Cl2 . (Et4N)2C2O4(SnCl4)2 . EtOH[30]
[(Me4N)2C2O4SnCl4]2 . [(Me4N)2Sn(C2O4)2Cl2]2 . Sn(WO4)2[30]
[Pt(HC2O4)Cl3]2−[39]
[Pt(HC2O4)(C2O4)Cl]2−[39]
K2[Pt(C2O4)Cl2]·H2OtriclinicP1a=7.136 b=7.308 c=10.130 α=86.75° β=74.58° γ=54.28° Z=2457.73.27[40][39]
[Pt(NH3)5Cl][Cr(C2O4)3] · 4H2OorthorhombicPccna=38.901b=13.7267c=14.9141[41]
[Pt(NH3)5Cl][Fe(C2O4)3] · 4H2OorthorhombicPccna=39.0123b=13.7232c=14.8990[41]
[Pt(NH3)5Cl][Co(C2O4)3] · 2H2OmonoclinicP21a=8.5158b=12.6409c=8.5726β=105.000°[41]
lead chloride oxalatePb2Cl2(C2O4)monoclinicC2/ma=5.9411 b=5.8714 c=9.4212 β=95.232° Z=2327.265.82dec 350°C to Pb, Pb5O2Cl6 and Pb3O2Cl2[42]
Th4Cl4(C2O4)6•20H2O
Plutonium(III) oxalato chloride?Pu(C2O4)Cl·3H2Oblue; biaxial (−)[43]
Am(C2O4)Cl·3H2OmonoclinicP21/na=5.852b=15.823c=8.351β=104.243°[44]

References

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Salts and covalent derivatives of thechloride ion
HClHe
LiClBeCl2B4Cl4
B12Cl12
BCl3
B2Cl4
+BO3		C2Cl2
C2Cl4
C2Cl6
CCl4
+C
+CO3		NCl3
ClN3
+N
+NO3		ClxOy
Cl2O
Cl2O2
ClO
ClO2
Cl2O4
Cl2O6
Cl2O7
ClO4
+O		ClF
ClF3
ClF5		Ne
NaClMgCl2AlCl
AlCl3		Si5Cl12
Si2Cl6
SiCl4		P2Cl4
PCl3
PCl5
+P		S2Cl2
SCl2
SCl4
+SO4		Cl2Ar
KClCaCl
CaCl2		ScCl3TiCl2
TiCl3
TiCl4		VCl2
VCl3
VCl4
VCl5		CrCl2
CrCl3
CrCl4		MnCl2
MnCl3		FeCl2
FeCl3		CoCl2
CoCl3		NiCl2CuCl
CuCl2		ZnCl2GaCl
GaCl3		GeCl2
GeCl4		AsCl3
AsCl5
+As		Se2Cl2
SeCl2
SeCl4		BrClKr
RbClSrCl2YCl3ZrCl2
ZrCl3
ZrCl4		NbCl3
NbCl4
NbCl5		MoCl2
MoCl3
MoCl4
MoCl5
MoCl6		TcCl3
TcCl4		RuCl2
RuCl3
RuCl4		RhCl3PdCl2AgClCdCl2InCl
InCl2
InCl3		SnCl2
SnCl4		SbCl3
SbCl5		Te3Cl2
TeCl2
TeCl4		ICl
ICl3		XeCl
XeCl2
XeCl4
CsClBaCl2*LuCl3
177LuCl3		HfCl4TaCl3
TaCl4
TaCl5		WCl2
WCl3
WCl4
WCl5
WCl6		ReCl3
ReCl4
ReCl5
ReCl6		OsCl2
OsCl3
OsCl4
OsCl5		IrCl2
IrCl3
IrCl4		PtCl2
PtCl4
PtCl2−6		AuCl
(Au[AuCl4])2
AuCl3
AuCl−4		Hg2Cl2
HgCl2		TlCl
TlCl3		PbCl2
PbCl4		BiCl3PoCl2
PoCl4		AtClRn
FrClRaCl2**LrCl3RfCl4DbCl5SgO2Cl2BhO3ClHsMtDsRgCnNhFlMcLvTsOg
 
*LaCl3CeCl3PrCl3NdCl2
NdCl3		PmCl3SmCl2
SmCl3		EuCl2
EuCl3		GdCl3TbCl3DyCl2
DyCl3		HoCl3ErCl3TmCl2
TmCl3		YbCl2
YbCl3
**AcCl3ThCl3
ThCl4		PaCl4
PaCl5		UCl3
UCl4
UCl5
UCl6		NpCl3
NpCl4		PuCl3
PuCl4
PuCl2−6		AmCl2
AmCl3		CmCl3BkCl3CfCl3
CfCl2		EsCl2
EsCl3		FmCl2MdCl2NoCl2
Compounds of theoxalate ion
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