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Number density

From Wikipedia, the free encyclopedia
Degree of concentration of countable objects
Not to be confused withNatural density.

Thenumber density (symbol:n orρN) is anintensive quantity used to describe the degree ofconcentration ofcountable objects (particles,molecules,phonons,cells,galaxies, etc.) in physical space:three-dimensionalvolumetric number density,two-dimensionalareal number density, orone-dimensionallinear number density.Population density is an example of areal number density. The termnumber concentration (symbol:lowercasen, orC, to avoid confusion withamount of substance indicated byuppercaseN) is sometimes used in chemistry for the same quantity, particularly when comparing with otherconcentrations.

Definition

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Volume number density is the number of specified objects per unitvolume:[1]n=NV,{\displaystyle n={\frac {N}{V}},}whereN is the total number of objects in a volumeV.

Here it is assumed[2] thatN is large enough thatrounding of the count to the nearestinteger does not introduce much of anerror, howeverV is chosen to be small enough that the resultingn does not depend much on thesize orshape of the volumeV because of large-scale features.

Area number density is the number of specified objects per unitarea,A:n=NA,{\displaystyle n'={\frac {N}{A}},}Similarly, linear number density is the number of specified objects per unitlength,L:n=NL,{\displaystyle n''={\frac {N}{L}},}

Column number density is a kind of areal density, the number or count of a substance per unit area, obtained integrating volumetric number density along a vertical path:nc=nds.{\displaystyle n'_{c}=\int n\,\mathrm {d} s.}It's related tocolumn mass density, with the volumetric number density replaced by the volume mass density.

Units

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InSI units, number density is measured in m−3, although cm−3 is often used. However, these units are not quite practical when dealing with atoms or molecules ofgases,liquids orsolids atroom temperature andatmospheric pressure, because the resulting numbers are extremely large (on the order of 1020). Using the number density of anideal gas at0°C and1atm as ayardstick:n0 = 1amg =2.6867774 × 1025 m−3 is often introduced to define arelative number density (adimensionless quantity), for any substances at any conditions (not necessarily limited to an ideal gas at0 °C and1 atm).[3]

Usage

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Using the number density as afunction ofspatial coordinates, the total number of objectsN in the entire volumeV can be calculated asN=Vn(x,y,z)dV,{\displaystyle N=\iiint _{V}n(x,\,y,\,z)\,\mathrm {d} V,}where dV = dx dy dz is a volume element. If each object possesses the samemassm0, the total massm of all the objects in the volumeV can be expressed asm=Vm0n(x,y,z)dV.{\displaystyle m=\iiint _{V}m_{0}n(x,\,y,\,z)\,\mathrm {d} V.}

Similar expressions are valid forelectric charge or any otherextensive quantity associated with countable objects. For example, replacingm withq (total charge) andm0 withq0 (charge of each object) in the above equation will lead to a correct expression for charge.

The number density ofsolute molecules in asolvent is sometimes calledconcentration, although usually concentration is expressed as a number ofmoles per unit volume (and thus calledmolar concentration).

Relation to other quantities

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Molar concentration

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For any substance, the number density can be expressed in terms of itsamount concentrationc (inmol/m3) asn=NAc{\displaystyle n=N_{\rm {A}}c}whereNA is theAvogadro constant. This is still true if thespatial dimension unit, metre, in bothn andc is consistently replaced by any other spatial dimension unit, e.g. ifn is in cm−3 andc is in mol/cm3, or ifn is inL−1 andc is in mol/L, etc.

Mass density

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Foratoms ormolecules of a well-definedmolar massM (inkg/mol), the number density can sometimes be expressed in terms of theirmass densityρm (in kg/m3) asn=NAMρm.{\displaystyle n={\frac {N_{\rm {A}}}{M}}\rho _{\mathrm {m} }.}Note that the ratioM/NA is the mass of a single atom or molecule in kg.

Examples

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The following table lists common examples of number densities at1 atm and20 °C, unless otherwise noted.

Molecular[4] number density and related parameters of some materials[citation needed]
MaterialNumber density,nAmount concentration,cMass density,ρmMolar mass,M
(1027 m−3 = 1021 cm−3)(amg)(103mol/m3 =mol/L)(103kg/m3 =g/cm3)(10−3kg/mol =g/mol)
Ideal gas0.025040.9320.0415841.58 × 10−6MM
Dry air0.025040.9320.041581.2041 × 10−328.9644
Water33.36791,241.9355.40860.9982018.01524
Diamond176.26,556292.53.51312.01

References and notes

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  1. ^IUPAC,Compendium of Chemical Terminology, 5th ed. (the "Gold Book") (2025). Online version: (2006–) "number concentration".doi:10.1351/goldbook.N04260
  2. ^Clayton T. Crowe; John D. Schwarzkopf; Martin Sommerfeld; Yutaka Tsuji (2011),Multiphase flows with droplets and particles: allelochemical interactions,CRC Press, p. 18,doi:10.1201/b11103,ISBN 9780429106392
  3. ^Joseph Kestin (1979),A Course in Thermodynamics, vol. 2, Taylor & Francis, p. 230,ISBN 0-89116-641-6
  4. ^Forelemental substances, atomic densities/concentrations are used
Solution
Concentration
and related quantities
Solubility
Solvent
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