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Neodymium(III) perchlorate

From Wikipedia, the free encyclopedia
Neodymium(III) perchlorate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.033.459Edit this at Wikidata
EC Number
  • 236-821-8
  • InChI=1S/3ClHO4.Nd/c3*2-1(3,4)5;/h3*(H,2,3,4,5);/q;;;+3/p-3
    Key: HBKMAYJLXKBOER-UHFFFAOYSA-K
  • [O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[Nd+3]
Properties
Nd(ClO4)3
Molar mass442.5929 g/mol (anhydrate)
514.65402 g/mol (tetrahydrate)
523.66166 g/mol (4.5 hydrate)
550.68458 g/mol (hexahydrate)
Appearancelight purple crystals (anhydrous)[1]
Density3.33 g/cm³ (anhydrate)[1]
tan
Solubilitysoluble inhydrazine
Structure
Yb(ReO4)3, α = 90°, β = 90°, γ = 120°
a = 0.9341 nm,b = 0.9341 nm,c = 0.5835 nm
Hazards
GHS labelling:
GHS03: OxidizingGHS07: Exclamation mark[2]
Danger[2]
H271,H315,H319,H335
P210,P220,P221,P264,P271,P280,P302,P304,P305,P312,P313,P332,P338,P340,P351,P352,P362,P370,P378,P501
Related compounds
Othercations
Praseodymium(III) perchlorate
Samarium(III) perchlorate
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Neodymium(III) perchlorate is aninorganic compound. It is a salt ofneodymium andperchloric acid with thechemical formula ofNd(ClO4)3. It is soluble in water,[3] forming purple-pink,hydrated crystals.[2]

Properties

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Physical properties

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This sectionneeds expansion. You can help byadding to it.(May 2022)

Neodymium(III) perchlorate forms pale purple crystals when in its anhydrous form.[citation needed]

It is soluble in water.[3]

It forms crystals Nd(ClO4)3·nH2O, wheren = 4, 4.5 are purple-pink crystals,and n = 6 forms pale pink to lavender crystals.[2]

Alkaline salts

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This sectionneeds expansion. You can help byadding to it.(May 2022)

Nd(ClO4)3 can form alkaline salts, with the general formula of Nd(OH)x(ClO4)3 − x. The salt with x = 1.5 (saturated with 5 water atoms) is a light purple crystal with d = 2.88 g/cm³.[4]

Other compounds

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Nd(ClO4)3 can form compounds withhydrazine, such as Nd(ClO4)3·6N2H4·4H2O which is a small white crystal that is soluble inwater,methanol,ethanol andacetone, and insoluble intoluene, with density of 2,3271 g/cm³ at 20 °C.[5]

References

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  1. ^abHandbook… (Pierre Villars, Karin Cenzual, Roman Gladyshevskii; Walter de Gruyter GmbH & Co KG, 24 thg 7, 2017 - 1970 trang), trang 442. Truy cập 4 tháng 2 năm 2021.
  2. ^abcdNeodymium(III) Perchlorate Hexahydrate – American Elements ®. Truy cập 4 tháng 2 năm 2021.
  3. ^abBeeby, Andrew; Faulkner, Stephen (1997). "Luminescence from neodymium(III) in solution".Chemical Physics Letters.266 (1–2):116–122.doi:10.1016/S0009-2614(96)01520-5.
  4. ^Villars, Pierre; Cenzual, Karin; Gladyshevskii, Roman (24 July 2017).Handbook of Inorganic Substances 2017. Walter de Gruyter GmbH & Co KG. p. 3414.ISBN 978-3-11-043655-6.
  5. ^Izvestii︠a︡ vysshikh uchebnykh zavedeniĭ: Khimii︠a︡ i khimicheskai︠a︡ tekhnologii︠a︡, Tập 16, Số phát hành 1 (Ivanovskiĭ khimiko-tekhnologicheskiĭ in-t, 1973), trang 182. Truy cập 7 tháng 2 năm 2021.


Nd(II)
Nd(III)
Nd(IV)
Salts and covalent derivatives of theperchlorate ion
HClO4He
LiClO4Be(ClO4)2B(ClO4)4
B(ClO4)3
ROClO3N(ClO4)3
NH4ClO4
NOClO4
NO2ClO4
H3OClO4FClO4Ne
NaClO4Mg(ClO4)2Al(ClO4)3
Al(ClO4)4
Al(ClO4)2−5
Al(ClO4)3−6
SiPSClO4
ClOClO3
Cl2O7
Ar
KClO4Ca(ClO4)2Sc(ClO4)3Ti(ClO4)4VO(ClO4)3
VO2(ClO4)
Cr(ClO4)3Mn(ClO4)2Fe(ClO4)2
Fe(ClO4)3
Co(ClO4)2
Co(ClO4)3
Ni(ClO4)2Cu(ClO4)2Zn(ClO4)2Ga(ClO4)3GeAsSeBrOClO3Kr
RbClO4Sr(ClO4)2Y(ClO4)3Zr(ClO4)4Nb(ClO4)5MoO2(ClO4)2TcRuRh(ClO4)3Pd(ClO4)2AgClO4Cd(ClO4)2In(ClO4)3Sn(ClO4)4Sb(ClO4)3TeO(ClO4)2I(OClO3)3Xe(OClO3)2
CsClO4Ba(ClO4)2*Lu(ClO4)3Hf(ClO4)4Ta(ClO4)5
TaO(ClO4)3
TaO2ClO4
WO(ClO4)4ReO3ClO4OsIrPtAu(ClO4)4Hg2(ClO4)2
Hg(ClO4)2
Tl(ClO4)
Tl(ClO4)3
Pb(ClO4)2Bi(ClO4)3PoAtRn
FrClO4Ra**LrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg
 
*La(ClO4)3Ce(ClO4)xPr(ClO4)3Nd(ClO4)3PmSm(ClO4)3Eu(ClO4)3Gd(ClO4)3Tb(ClO4)3Dy(ClO4)3Ho(ClO4)3Er(ClO4)3Tm(ClO4)3Yb(ClO4)3
**AcTh(ClO4)4PaUO2(ClO4)2NpO2ClO4
NpO2(ClO4)2
PuO2(ClO4)2Am(ClO4)3Cm(ClO4)3BkCfEsFmMdNo
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