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Neodymium(II) bromide

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(July 2022)
Neodymium(II) bromide
Names
IUPAC name
Neodymium(II) bromide
Other names
  • Neodymium dibromide
  • Neodymium bromide
Identifiers
3D model (JSmol)
  • InChI=1S/2BrH.Nd/h2*1H;/q;;+2/p-2
    Key: SNPAAONOVANSBU-UHFFFAOYSA-L
  • [Br-].[Br-].[Nd+2]
Properties
NdBr2
Molar mass304.05 g/mol
AppearanceGreen solid
Melting point725 °C (1,337 °F; 998 K)
Related compounds
Otheranions
Neodymium(II) fluoride,Neodymium(II) chloride,Neodymium(II) iodide
Othercations
Praseodymium(II) bromide,Cerium(II) bromide,Samarium(II) bromide
Related compounds
Lead(II) chloride,Neodymium(III) bromide
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Neodymium(II) bromide is aninorganic compound ofneodymium andbromide.

Preparation

[edit]

Neodymium(II) bromide can be obtained via the reduction ofneodymium(III) bromide with neodymium in avacuum at 800 to 900 °C.[1]

Nd + 2 NdBr3 → 3 NdBr2

Properties

[edit]

Neodymium(II) bromide is a dark green solid. The compound is extremelyhygroscopic and can only be stored and handled under carefully dried inert gas or under a high vacuum. In air or on contact with water, it converts tohydrates by absorbing moisture, but these are unstable and more or less rapidly transform into oxybromides with evolution ofhydrogen. The compound has the samecrystal structure aslead(II) chloride type.[1]

References

[edit]
  1. ^abGeorg Brauer (Hrsg.), unter Mitarbeit vonMarianne Baudler u. a.:Handbuch der Präparativen Anorganischen Chemie. 3., umgearbeitete Auflage. Band I, Ferdinand Enke, Stuttgart 1975, ISBN 3-432-02328-6, S. 1081.
Nd(II)
Nd(III)
Nd(IV)
Salts and covalent derivatives of thebromide ion
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