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N-Methylmorpholine

From Wikipedia, the free encyclopedia
N-Methylmorpholine
Names
IUPAC name
4-Methylmorpholine
Identifiers
3D model (JSmol)
AbbreviationsNMM
ChEMBL
ChemSpider
ECHA InfoCard100.003.310Edit this at Wikidata
EC Number
  • 203-640-0
UNII
UN number2535
  • InChI=1S/C5H11NO/c1-6-2-4-7-5-3-6/h2-5H2,1H3 ☒N
    Key: SJRJJKPEHAURKC-UHFFFAOYSA-N ☒N
  • InChI=1/C5H11NO/c1-6-2-4-7-5-3-6/h2-5H2,1H3
    Key: SJRJJKPEHAURKC-UHFFFAOYAK
  • O1CCN(C)CC1
Properties
C5H11NO
Molar mass101.149 g·mol−1
AppearanceLiquid
OdorStrongly unpleasant, fish-like
Density0.92 g/cm3
Melting point−66 °C (−87 °F; 207 K)
Boiling point115 to 116 °C (239 to 241 °F; 388 to 389 K)
Acidity (pKa)7.38 (for the conjugate acid) (H2O)[1]
Hazards
GHS labelling:
GHS02: FlammableGHS05: CorrosiveGHS07: Exclamation mark
Danger
H225,H302,H312,H314,H332
P210,P233,P240,P241,P242,P243,P260,P261,P264,P270,P271,P280,P301+P312,P301+P330+P331,P302+P352,P303+P361+P353,P304+P312,P304+P340,P305+P351+P338,P310,P312,P321,P322,P330,P363,P370+P378,P403+P235,P405,P501
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Chemical compound

N-Methylmorpholine is theorganic compound with the formula O(CH2CH2)2NCH3. It is a colorless liquid. It is a cyclictertiary amine. It is used as a base catalyst for generation ofpolyurethanes and other reactions. It is produced by the reaction ofmethylamine anddiethylene glycol as well as by the hydrogenolysis of N-formylmorpholine.[2] It is the precursor toN-methylmorpholineN-oxide, a commercially important oxidant.

References

[edit]
  1. ^David Evans Research GroupArchived 2012-01-21 at theWayback Machine
  2. ^Karsten Eller; Erhard Henkes; Roland Rossbacher; Hartmut Höke (2005). "Amines, Aliphatic".Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH.doi:10.1002/14356007.a02_001.ISBN 3-527-30673-0.
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